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1993 Fiscal Year Final Research Report Summary

Optoelectronic Materials Based on Physical Chemistry

Research Project

Project/Area Number 03303008
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 工業物理化学・複合材料
Research InstitutionThe University of Tokyo

Principal Investigator

FUJISHIMA Akira  Faculty of Engineering, University of Tokyo : Profesor, 工学部, 教授 (30078307)

Co-Investigator(Kenkyū-buntansha) YANAGIDA Shozo  Faculty of Engineering, Osaka University : Professor, 工学部, 教授 (10029126)
IIZAWA Masuo  Faculty of Bioscience and Biotechnology, Tokyo Inst. of Technology : Professor, 生命理工学部, 教授 (00016742)
IRIE Masahiro  Inst. Advancd Material Study, Kyushu University : Professor, 機能物質科学研究所, 教授 (30001986)
YAMAZAKI Iwao  Faculty of Engineering, Hokkaido University : Professor, 工学部, 教授 (80002111)
UOSAKI Kohei  Faculty of Science, Hokkaido Univeersity : Professor, 理学部, 教授 (20133697)
Project Period (FY) 1991 – 1993
Keywordsindustrial physical chiemistry / opto-electonics / photo-functinal molecule / molecular desigh / optical information strage / biosensor / control of interfacial function / photochemical process
Research Abstract

Anticipating for the coming changes in the 21st century, a century predicted to be the "ge of light", all members of our group have been interested light-related chemical phenomena. We have accomplished a variety of pioneering tasks in this field. Currently, we are engaged in basic and applied studies on the phenomena specifically occurring at the interface between a solid(a semiconductor or metal)and a solution or a gas, upon the application of light energy to the interface. We are expliring system shows characteristics distinctly different from those of any one phase, which at times have given us the delight of observing an unexpected phenomenon. Some of our recent results are summarized as follows.
Nanometer order chemical research with STM and AFM, these "atom-watching"mictoscopes prove their high research potential with their mechanisms, functions and pronciples. In a study performed in this area, an STM is used to directly observe the interface between a layred compound, exhibiting charge density waves and an electrolyte. Efforts in the development of information recording materials which uses these microscopes to write and erase are under way.
Metallization by(phto)chemical reactions of semiconductor thin films, concerns the metallization of various insulating substrates. As we see typically in the metallization of printed circuit boards, thes is one of the important processes in modern technology. We have recently developed a new metallization technique that uses(photo)chemical reactions of a certain of semiconductor thin films.

  • Research Products

    (24 results)

All Other

All Publications (24 results)

  • [Publications] T.Amemiya: "Faradaic Charge Transfer with Double-Layer Charging and/or Adsorption-Related Chartging at Polymer-Modified Electrodes as Observed by Color Impedance Spectroscopy" J.Phys.Chem.97. 9736-9740 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Morigaki: "In-Situ Electrochemical Actinometry Using an Azo Monolayer Film" Ber.Bunsenges.Phys.Chem.97. 860-864 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] L.A.Nagahara: "Scanning Probe and Transmission Electron Microscopy Observations of Cobalt Naphthalocyanine Molecules Deposited onto a NaCl Substrate" J.Vac.Sci.Technol.A. 11. 781-785 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] L.A.Nagahara: "Effects of HF Solution in the Electroless Deposition Process on Silicon Surfaces" J.Vac.Sci.Technol.A. 11. 763-767 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Baba: "Characterization of the Molecular Orientation in LB Films of Rhodamine B Derivatives by the Optical Second Harmonic Generation Coherent Interferometry" Denki Kagaku. 61. 1030-1031 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Morigaki: "Electrochemical Counting of Photon Number Using the Assembled Monolayer Film of Azo Compound" Sensors and Actuators B. 13-14. 226-229 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] O.Sato: "Self-Ordered Film of Hamicyanine Derivative Characterized by Phase-Sensitive Optical Second-Harmonic Generation" Jpn.J.Appl.Phys.32. 1201-1203 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-storing Materials.Part II.Copper-Modified Palladium Electrode" J.Electroanal.Chem.348. 459-464 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Amemiya: "Dynamics of Faradaic Processed in Polypyrrole/Poly-styrenesulfonate Composite Films in the Presence and Absence a of Redox Species in Aqueous Solutions" J.Phys.Chem.97. 4192-4195 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Amemiya: "Frequency-Resolved Faradaic Processes in Polypyrrole Films Observed by Electromodilation Techniques:Electrochemical Impedance and Color Impedance Spectroscopies" J.Phys.Chem.97. 4187-4191 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Z.F.Liu: "Direct Observation of the Secondary Structure of Unfolded Pseudomonas-Cytochrome C_<551> by Scanning Tunneling Microscopy" Surf.Sci.Lett.284. L411-L415 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-storing Materials.Part I.The Effect of Hydrogen Absorption on the Electrochemical Behavior on Palladium Electrodes" J.Electroaanal.Chem.345. 445-456 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ameriya: "Faradaic Charge Transfer with Double-Layr Charging and/or Adsorption-Related Chartging at Polymer-Modified Electrodes as Observed by Color Impedance Spectroscopy" J.Phys.Chem. 97(38). 9736-9740 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Morigaki: "In-Situ Electrochemical Actinometry Using an Azo Monolayr Film" Ber.Bunsenges.Phys.Chem. 97(7). 860-864

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] L.A.Nagahara: "Scanning Probe and Transmission Electron Microscopy Observations of Cobalt Naphthalocyanine Molecules Deposited onto a NaCl Substrate" J.Vac.Sci.Technol.A. 11(4). 781-785 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] L.A.Nagahara: "Effects of HF Solution in the Electroless Deposition Process on Silicon Surfaces" J.Vac.Sci.Technol.A. 11(4). 763-767 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.Baba: "Characterization of the Molecular Orientation in LB Films of Rhodamine B Derivatives by the Optical Second Harmonic Generation Coberent Interferometry" Denki Kagaku. 61(8). 1030-1031 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Morigaki: "Electrochemical Counting of Photon Number Using the Assembled Monolayr Film of Azo Compound" Sensors and Actuators B. 13-14. 226-229 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] O.Sato: "Self-Ordered Film of Hamicyanine Derivative Characterized by Phase-Sensitive Optical Second-Harmonic Generation" Jpn.J.Appl.Phys. 32(1), 3A. 1201-1203 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrorgen-storing Materials. Part II.Copper-Modified Palladium Electrode" J.Electroanal.Chem. 348. 459-464 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Ameriya: "Dynamics of Faradaic Processed in Polypyrrole/Polystirenesulfonate Composite Films in the Presence and Absence of a Redox Species in Aqueous Solutions" J.Phys Chem. 97(16). 4192-4195 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Ameriya: "Frequency-Resolved Faradaiv Processes in Polypyrrole Films Obseved by Electromodilation Techniques : Electrochemical impedance and Color Impedance Spestoscopies" J.Phys Chem. 97(16). 4187-4191 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Z.F.Liu: "Direct Observation of the Secondary Structure of Unfolded Pseudomonas-Cytochrome C_<551> by Scanning Tunneling Micoscopy" Surf.Sci.Lett. 284. l411-l415 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Ohkawa: "Electrochemical Reduction of Carbon Dioxide on Hydrogen-storing Materials.Part I.The Effect of Hydrogen absorptiion on the Electrochemical Behavior on Palladium Electrodes" J.Electroaanal. Chem. 345. 445-456 (1993)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1995-03-27  

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