1992 Fiscal Year Annual Research Report

不活性小分子の活性化

Research Project

Project/Area Number	04241104
Research Institution	The University of Tokyo
Principal Investigator	干鯛眞信東京大学, 工学部, 教授 (60011011)
Co-Investigator(Kenkyū-buntansha)	岩澤康裕東京大学, 理学部, 教授 (40018015) 齋藤太郎東京大学, 理学部, 教授 (90011006) 藤元薫東京大学, 工学部, 教授 (30011026) 村井真二大阪大学, 工学部, 教授 (00029050) 長倉三郎総合研究大学院大学, 学長 (30013444)
Keywords	不活性小分子 / 窒素分子 / メタン / 二酸化炭素 / 金属クラスター / 固体表面
Research Abstract	本研究は平成4年度より発足した重点領域研究「不活性小分子の活性化」の総括班の計画研究に関するもので、本領域における研究計画の円滑な推進と各研究班間の情報・意見交換、ならびに研究成果の他分野および社会への広報・還元を計ることを目的としている。平成4年度は当初の研究計画に基づき2回の公開シンポジウムを開催した。第1回公開シンポジウムは平成4年7月10、11日に東京で開催し、101名の出席者があった。講演内容は領域研究者全員(51名)の研究計画概要であり、活発な質疑が行われた。また、シンポジウムとあわせて総括班会議、各班会議、全体会議が行われ、第3班班長交替(生越久靖京都大学教授から藤元薫東京大学教授へ)などの研究計画遂行上必要な議題が検討された。第2回公開シンポジウムは12月11,12日に大阪で開催し、81名の出席者があった。講演は各研究班から2名ずつ、計10名の研究者により行われ、研究結果の詳しい説明がされるとともに活発な質疑、討論が行われた。またシンポジウムとあわせて総括班会議、各班会議、全体会議が開かれ、研究成果についての討論と研究計画に関する連絡が行われた。また研究成果のとりまとめと広報活動に関しては、2回の公開シンポジウムでの講演要旨集ならびに領域全研究者による平成4年度研究成果報告書を作成して各研究者に配布したほか、班員相互の連絡を緊密にし、また研究成果の社会への広報を促進する目的で、広報No1、No2を作成配布した。尚、本総括班では研究の効果的進展を計るため、備品として本年度に単結晶自動X線構造解析装置、270MHz超伝導核磁気共鳴装置、およびクライオストリームクーラーを購入して東京大学工学部に設置し、班員の協同利用を開始している。

Research Products

(23 results)

All Other

All Publications (23 results)

[Publications] Y.Ishii: "¨Novel Arylation of Molecular Nitrogen via Bimetallic Activation:Reaction of Coordinated Dinitrogen with Coordinated Haloarene¨" J.Am.Chem.Soc.114. 5429-5430 (1992)
[Publications] H.Oshita: ""Novel Disilyation of a Dinitrogen Ligand in cis-[W(N_2)_2(PMe_2Ph)_4].Synthesis and Reactivity of mer-[WI_2(NNSiMe_2Ch_2CH_2Sime_2)(PMe_2Ph)_3]"" Organometallics. 11. 4116-4123 (1992)
[Publications] Y.Ishii: "¨Alkenyldiazenido Complexes of Molybdenum and Tungsten Derived from Dinitrogen Complexes:Their Synthesis,Characterization and Novel Reactivities¨" J.Am.Chem.Soc.114. 9890-9898 (1992)
[Publications] T.Aoshima: ""Preparation and Properties of Molybdenum and Tungsten Dinitrogen Complexes XXXV.Synthesis of Diazoalkane and Hydrazido(2-) Complexes of Tungsten Containing a π-Acceptor Ligand"" J.Organomet.Chem.435. 85-99 (1992)
[Publications] T.Aoshima: ""A Novel Dinuclear Tetracarbonyl Complex Containing a Bridging Alkyldiazenido Ligand [WC1(CO)_2(PMe_2Ph)_2(N=NCMe_2CMe_2N=N)WC1(CO)_2(PMe_2Ph)_2] Formed via a Cationic Carbonyldiazoalkane Complex [WC1(CO)(NN=CMe_2)(PMe_2Ph)_3][ZnC1_3(thf)]"" J.Chem.Soc.,Chem.Commun.586-588 (1992)
[Publications] S.Ikeda: "¨Regioselective Incorporation of CO into Enamines by Rhodium-Catalyzed Reaction with a Hydrosilane and CO¨" J.Org.Chem.57. 2-4 (1992)
[Publications] S.Ikeda: "¨Rhodium-Catalyzed Reaction of N,N-Acetals with a Hydrosilane and Carbon Monoxide¨" Organometallics. 11. 3494-3495 (1992)
[Publications] N.Chatani: "¨Conversion of Alkenes to Enol Silyl Ethers of Acylsilanes by Inidium-Catalyzed Reaction with a Hydrosilane and Carbon Monoxide¨" J.Am.Chem.Soc.114. 9710-9711 (1992)
[Publications] K.Omata: "¨Methane Partial Oxidation to Methanol-Solid Initiated Homogeneous Methane Oxidation¨" Catal.Lett.12. 227-230 (1992)
[Publications] R.Philipp: "¨On the Active Site of MgO/CaO Mixed Oxide for Oxidative Coupling of Methane¨" J.Catal.134. 422-433 (1992)
[Publications] T.Nozaki: "¨Selective Oxidative Coupling of Methane with Membrane Reactor¨" Chem.Eng.Sci.47. 2945-2950 (1992)
[Publications] T.Nozaki: "¨Oxidative Coupling of Methane by Using Membrane Reactor Modified by Molten Salts¨" J.Chem.Soc.,Chem.Commun.1248 (1992)
[Publications] K.Fujimoto: "¨Selective Synthesis of Liquid Hydrocarbons from Carbon Dioxide and Methane¨" Energy Conversion and Management. 33. 529-536 (1992)
[Publications] O.Yamazaki: "¨Reduction of Carbon Dioxide by Methane with Ni-on-MgO-CaO Containing Catalyst¨" Chem.Lett.1953-1956 (1992)
[Publications] K.Tsuge: ""Synthesis of an Equilateral TrianGular Molybdenum Cluster Complex[Mo_4(μ_3-S)_2(μ-S)_3(PMe_3)_6]with Eight Cluster Valence Electrons"" J.Am.Chem.Soc.114. 7910-7912 (1992)
[Publications] K.Tsuge: ""Synthesis of[Mo_4S_6(SH)_2(PMe_3)_6]and[Mo_6S_<10>(SH)_2(PEt_3)_6]Consisting of Fused Mo_3(μ_3-S)Cluster Units"" Inorg.Chem.23. 4715-4716 (1992)
[Publications] Y.Izumi: "¨Methylruthenium Carbidocarbonyl Clusters Supported on Inorganic Oxides: Characterization and Selective Acetaldehyde Formation¨" J.Chem.Soc.,Dalton Trans.2287-2297 (1992)
[Publications] M.Shirai: ""Asymmetric Structure Determination of Copper Oxide on α-Quarts(0001) Surface by Polarized Total-Reflection Fluorescence Extended X-Ray Absorption Fine Structure Spectroscopy"" Chem.Lett.1037-1040 (1992)
[Publications] K.Asakura: ""Reversible Structure Transformation of ZrO_2 on Pd Black"" J.Phys.Chem.96. 7386-7389 (1992)
[Publications] T.Aruga: "¨Ordered Oxygen on Mo(112):Modification of Surface Electronic Structure and Control of Reaction Path¨" J.An.Chem.Soc.114. 4911-4912 (1992)
[Publications] H.Yoshitake: ""Active Sites and Reaction Mechanisms for Deuteration of Acrolein on TiO_2-,Y_2O_3-,ZrO_2-,CeO_2-,and Na/SiO_2-supported Platinum"" J.Chem.Soc.,Faraday Trans.88. 503-510 (1992)
[Publications] T.Liu: ""Structures and Catalytic Activity of Pt-Mo Bimetallic Ensenbles Derived from a New Planar [PtMo_6O_<24>]^<8-> Heteropolyanion Supported on Al_2O_3 and SiO_2"" J.Catal.135. 367-385 (1992)
[Publications] T.Aruga: "Ordering at Surfaces and Interfaces" Eds.A.Yoshimori,T.Shinjo,H.Watanabe, 553 (1992)

1992 Fiscal Year Annual Research Report

不活性小分子の活性化

Principal Investigator

干鯛 眞信 東京大学, 工学部, 教授 (60011011)

Research Products

[Publications] Y.Ishii: "¨Novel Arylation of Molecular Nitrogen via Bimetallic Activation:Reaction of Coordinated Dinitrogen with Coordinated Haloarene¨" J.Am.Chem.Soc.114. 5429-5430 (1992)

[Publications] H.Oshita: ""Novel Disilyation of a Dinitrogen Ligand in cis-[W(N_2)_2(PMe_2Ph)_4].Synthesis and Reactivity of mer-[WI_2(NNSiMe_2Ch_2CH_2Sime_2)(PMe_2Ph)_3]"" Organometallics. 11. 4116-4123 (1992)

[Publications] Y.Ishii: "¨Alkenyldiazenido Complexes of Molybdenum and Tungsten Derived from Dinitrogen Complexes:Their Synthesis,Characterization and Novel Reactivities¨" J.Am.Chem.Soc.114. 9890-9898 (1992)

[Publications] T.Aoshima: ""Preparation and Properties of Molybdenum and Tungsten Dinitrogen Complexes XXXV.Synthesis of Diazoalkane and Hydrazido(2-) Complexes of Tungsten Containing a π-Acceptor Ligand"" J.Organomet.Chem.435. 85-99 (1992)

[Publications] S.Ikeda: "¨Regioselective Incorporation of CO into Enamines by Rhodium-Catalyzed Reaction with a Hydrosilane and CO¨" J.Org.Chem.57. 2-4 (1992)

[Publications] S.Ikeda: "¨Rhodium-Catalyzed Reaction of N,N-Acetals with a Hydrosilane and Carbon Monoxide¨" Organometallics. 11. 3494-3495 (1992)

[Publications] N.Chatani: "¨Conversion of Alkenes to Enol Silyl Ethers of Acylsilanes by Inidium-Catalyzed Reaction with a Hydrosilane and Carbon Monoxide¨" J.Am.Chem.Soc.114. 9710-9711 (1992)

[Publications] K.Omata: "¨Methane Partial Oxidation to Methanol-Solid Initiated Homogeneous Methane Oxidation¨" Catal.Lett.12. 227-230 (1992)

[Publications] R.Philipp: "¨On the Active Site of MgO/CaO Mixed Oxide for Oxidative Coupling of Methane¨" J.Catal.134. 422-433 (1992)

[Publications] T.Nozaki: "¨Selective Oxidative Coupling of Methane with Membrane Reactor¨" Chem.Eng.Sci.47. 2945-2950 (1992)

[Publications] T.Nozaki: "¨Oxidative Coupling of Methane by Using Membrane Reactor Modified by Molten Salts¨" J.Chem.Soc.,Chem.Commun.1248 (1992)

[Publications] K.Fujimoto: "¨Selective Synthesis of Liquid Hydrocarbons from Carbon Dioxide and Methane¨" Energy Conversion and Management. 33. 529-536 (1992)

[Publications] O.Yamazaki: "¨Reduction of Carbon Dioxide by Methane with Ni-on-MgO-CaO Containing Catalyst¨" Chem.Lett.1953-1956 (1992)

[Publications] K.Tsuge: ""Synthesis of an Equilateral TrianGular Molybdenum Cluster Complex[Mo_4(μ_3-S)_2(μ-S)_3(PMe_3)_6]with Eight Cluster Valence Electrons"" J.Am.Chem.Soc.114. 7910-7912 (1992)

[Publications] K.Tsuge: ""Synthesis of[Mo_4S_6(SH)_2(PMe_3)_6]and[Mo_6S_<10>(SH)_2(PEt_3)_6]Consisting of Fused Mo_3(μ_3-S)Cluster Units"" Inorg.Chem.23. 4715-4716 (1992)

[Publications] Y.Izumi: "¨Methylruthenium Carbidocarbonyl Clusters Supported on Inorganic Oxides: Characterization and Selective Acetaldehyde Formation¨" J.Chem.Soc.,Dalton Trans.2287-2297 (1992)

[Publications] M.Shirai: ""Asymmetric Structure Determination of Copper Oxide on α-Quarts(0001) Surface by Polarized Total-Reflection Fluorescence Extended X-Ray Absorption Fine Structure Spectroscopy"" Chem.Lett.1037-1040 (1992)

[Publications] K.Asakura: ""Reversible Structure Transformation of ZrO_2 on Pd Black"" J.Phys.Chem.96. 7386-7389 (1992)

[Publications] T.Aruga: "¨Ordered Oxygen on Mo(112):Modification of Surface Electronic Structure and Control of Reaction Path¨" J.An.Chem.Soc.114. 4911-4912 (1992)

[Publications] H.Yoshitake: ""Active Sites and Reaction Mechanisms for Deuteration of Acrolein on TiO_2-,Y_2O_3-,ZrO_2-,CeO_2-,and Na/SiO_2-supported Platinum"" J.Chem.Soc.,Faraday Trans.88. 503-510 (1992)

[Publications] T.Liu: ""Structures and Catalytic Activity of Pt-Mo Bimetallic Ensenbles Derived from a New Planar [PtMo_6O_<24>]^<8-> Heteropolyanion Supported on Al_2O_3 and SiO_2"" J.Catal.135. 367-385 (1992)

[Publications] T.Aruga: "Ordering at Surfaces and Interfaces" Eds.A.Yoshimori,T.Shinjo,H.Watanabe, 553 (1992)

干鯛眞信東京大学, 工学部, 教授 (60011011)