1993 Fiscal Year Annual Research Report

不活性小分子の活性化

Research Project

Project/Area Number	04241104
Research Institution	The University of Tokyo
Principal Investigator	干鯛眞信東京大学, 工学部, 教授 (60011011)
Co-Investigator(Kenkyū-buntansha)	岩澤康裕理学部, 教授 (40018015) 齋藤太郎理学部, 教授 (90011006) 藤元薫工学部, 教授 (30011026) 村井真二大阪大学, 工学部, 教授 (00029050) 長倉三郎総合研究大学院大学, 学長 (30013444)
Keywords	不活性小分子 / 窒素分子 / メタン / 二酸化炭素 / 金属クラスター / 固体表面
Research Abstract	本研究は平成4年度より発足した重点領域研究「不活性小分子の活性化」の総括班の平成5年度計画研究に関するもので、本領域における研究計画の円滑な推進と各研究班間の情報・意見交換、ならびに研究成果の他分野および社会への広報・還元を計ることを目的としている。平成5年度は当初の研究計画に基づき2回の公開シンポジウム(第3回ならびに第4回公開シンポジウム)を開催した。第3回公開シンポジウムは平成5年6月28、29日に東京で開催し、104名の出席者があった。講演は各研究班から2名ずつ計10名の研究者により行われ、研究結果の詳しい説明がなされ活発な質疑、討論が行われた。また、これにあわせて総括班会議、各班会議、全体会議が行われ、研究成果に関する討論、研究計画に関連する連絡があり、1995年環太平洋国際化学会議における小分子活性化に関するシンポジウム開催の計画、およびEuropean Research Network on“Small Molecules:Selective Process and Catalyses"との研究協力の提案がなされた。第4回公開シンポジウムは12月17、18日に大阪で開催し、77名の出席者があった。講演は各研究班から1〜4名ずつ計12名の研究者により行われ、研究結果の詳しい説明と質疑、討論が行われた。またシンポジウムとあわせて総括班会議、各班会議、全体会議が開かれ、研究成果についての討論と研究計画に関する連絡が行われた。研究成果のとりまとめと広報活動に関しては、2回の公開シンポジウムでの講演要旨集ならびに領域全研究者による平成5年度研究成果報告書を作成して各研究者に配布した。尚、本総括班では研究の効果的進展を計るため、備品として本年度に元素分析装置(東京大学工学部)、リサイクル分取HPLC(大阪大学工学部)、カメラ用X線結晶構造解析装置(東京大学理学部)、フーリエ変換赤外分光光度計(東京大学理学部)を購入設置し、班員の協同利用を開始している。

Research Products

(23 results)

All Other

All Publications (23 results)

[Publications] H.Seino: "“Conjugate Additions of Organocuprates to α,β-Unsaturated Diazoalkane Complexes of Molybdenum and Tungsten"" Organometallics. 13. 364-369 (1994)
[Publications] H.Oshita: "“Silylation and Germylation of a Coordinated Dinitrogen in cis-〔M(N_2)_2(PMe_2Ph)_4〕(M = Mo,W)using R_3ECl/NaI and R_3ECl/Na mixtures(E = Si,Ge)." J.Organometal.Chem.456. 213-220 (1993)
[Publications] H.Oshita: "“Preparation and Characterization of W(V)Diazoalkane Complexes mer,mer-〔WX_3-(NN=CMeR)(PMe_2Ph)_2 and Hydrazido(2-)Complex〔WI_3(NNH_2)(PMe_2Ph)_2〕." J.Organomet.Chem.461. 43-49 (1993)
[Publications] K.Ohe: "“Palladium-Catalyzed Reaction of 5-Methylene-1,3-dioxolan-2-ones.A New Access to and Reactivity of Oxatrimethylenemethane-Palladium"" J.Org.Chem.58. 1173-1177 (1993)
[Publications] Y.Fukumoto: "“Rhodium-Catalyzed Ring Opening Silylformylation of Epoxides Leading to β-Siloxyaldehydes"" J.Org.Chem.58. 4187-4188 (1993)
[Publications] H.Kakiuchi: "“Completely Selective Synthesis of(E)-β-(Triethylsilyl)styrenes by Vinylsilanes by Fe_3(CO)_<12>-Catalyzed Reaction of Styrene with Triethylsilane"" J.Organomet.Chem.456. 45-47 (1993)
[Publications] S.Murai: "“Efficient Catalytic Addition of Aromatic Carbon-Hydrogen Bonds to Olefins"" Nature. 366. 529-531 (1993)
[Publications] N.Chatani: "“Ruthenium-Catalyzed Reaction of 1,6-Diynes with Hydrosilanes and Carbon Monoxide:A Third Way of Incorporating CO"" J.Am.Chem.Soc.115. 11614-11615 (1993)
[Publications] F.Kakiuchi: "“Dehydrogenative Silylation of 1,5-Dienes with Hydrosilanes Catalyzed by RhCl(PPh_3)_3"" Organometallics. 12. 4748-4750 (1993)
[Publications] T.Nozaki: "“Oxidative Coupling of Methane with Membrane Reactors Containing Lead Oxide"" Ind.Eng.Chem.32. 1174-1179 (1993)
[Publications] T.Nozaki: "“Utilization of Oxide Ion Transportation for Oxidative Coupling of Methane with Membrane Reactors"" Studies in Surf.Sci.Catal.77. 377-380 (1993)
[Publications] T.Nozaki: "“Gas-Phase Oxidative Coupling of Methane in the Presence of Promoters"" Energy and Fuels. 7. 432-433 (1993)
[Publications] K.Omata: "“Methane Partial Oxidation to Methanol.1.Effects of Reaction Conditions and Additives"" Ind.and Eng.Chem.Res.(in press).
[Publications] M.Shirai: "“Polarized Total-Reflection Fluorescence EXAFS Study of Anisotropic Structure Analysis for Co Oxides on α-Al_2O_3(0001)as Model Surfaces for Active Oxidation Catalysts"" J.Catal.145. 159-165 (1994)
[Publications] Y.Iwasawa: "“Chemical Design and Characterization of Catalysts and Catalysis:An Approach to Dynamic Catalyst Design"" Catal.Today.18. 21-72 (1993)
[Publications] N.Ichikuni: "“Structures and Catalysis of New Nb Dimers on SiO_2"" Catal.Today.16. 427-434 (1993)
[Publications] J.Inukai: "“Reversible Activity Enhancement of SiO_2-Supported Group VIII Metal Catalysts by Pretreatment Temperature"" J.Catal.143. 22-31 (1993)
[Publications] M.Shirai: "“Polarized Total-Reflection Fluorescence EXAFS Studies on Asymmetric Surface Structures of Catalysts"" Jpn.J.Apply.Phys.32. 413-415 (1993)
[Publications] K.Asakura: "“Asymmetric Structure Analysis of Active Surface Sites by in situ Polarized Total-Reflection Fluorescence EXAFS"" Catal.Lett.20. 117-124 (1993)
[Publications] N.Ichikuni: "“In situ d Electron Density of Pt Particles on Supports by XANES"" Catal.Lett.20. 87-95 (1993)
[Publications] Y.Iwasawa: "New Frontiers in Catalysis" L.Guczi,F.Solymosi,P.Tetenyi Eds., (1993)
[Publications] Y.Iwasawa: "Elementary Reaction Steps in Heterogeneous Catalysis" R.W.Joyner,R.A.van Santen Eds., (1993)
[Publications] Y.Iwasawa: "“Catalysis by Structurally Designed Surfaces"" K.Tamaru Ed., (1993)

1993 Fiscal Year Annual Research Report

不活性小分子の活性化

Principal Investigator

干鯛 眞信 東京大学, 工学部, 教授 (60011011)

Research Products

[Publications] H.Seino: "“Conjugate Additions of Organocuprates to α,β-Unsaturated Diazoalkane Complexes of Molybdenum and Tungsten"" Organometallics. 13. 364-369 (1994)

[Publications] H.Oshita: "“Silylation and Germylation of a Coordinated Dinitrogen in cis-〔M(N_2)_2(PMe_2Ph)_4〕(M = Mo,W)using R_3ECl/NaI and R_3ECl/Na mixtures(E = Si,Ge)." J.Organometal.Chem.456. 213-220 (1993)

[Publications] H.Oshita: "“Preparation and Characterization of W(V)Diazoalkane Complexes mer,mer-〔WX_3-(NN=CMeR)(PMe_2Ph)_2 and Hydrazido(2-)Complex〔WI_3(NNH_2)(PMe_2Ph)_2〕." J.Organomet.Chem.461. 43-49 (1993)

[Publications] K.Ohe: "“Palladium-Catalyzed Reaction of 5-Methylene-1,3-dioxolan-2-ones.A New Access to and Reactivity of Oxatrimethylenemethane-Palladium"" J.Org.Chem.58. 1173-1177 (1993)

[Publications] Y.Fukumoto: "“Rhodium-Catalyzed Ring Opening Silylformylation of Epoxides Leading to β-Siloxyaldehydes"" J.Org.Chem.58. 4187-4188 (1993)

[Publications] H.Kakiuchi: "“Completely Selective Synthesis of(E)-β-(Triethylsilyl)styrenes by Vinylsilanes by Fe_3(CO)_<12>-Catalyzed Reaction of Styrene with Triethylsilane"" J.Organomet.Chem.456. 45-47 (1993)

[Publications] S.Murai: "“Efficient Catalytic Addition of Aromatic Carbon-Hydrogen Bonds to Olefins"" Nature. 366. 529-531 (1993)

[Publications] N.Chatani: "“Ruthenium-Catalyzed Reaction of 1,6-Diynes with Hydrosilanes and Carbon Monoxide:A Third Way of Incorporating CO"" J.Am.Chem.Soc.115. 11614-11615 (1993)

[Publications] F.Kakiuchi: "“Dehydrogenative Silylation of 1,5-Dienes with Hydrosilanes Catalyzed by RhCl(PPh_3)_3"" Organometallics. 12. 4748-4750 (1993)

[Publications] T.Nozaki: "“Oxidative Coupling of Methane with Membrane Reactors Containing Lead Oxide"" Ind.Eng.Chem.32. 1174-1179 (1993)

[Publications] T.Nozaki: "“Utilization of Oxide Ion Transportation for Oxidative Coupling of Methane with Membrane Reactors"" Studies in Surf.Sci.Catal.77. 377-380 (1993)

[Publications] T.Nozaki: "“Gas-Phase Oxidative Coupling of Methane in the Presence of Promoters"" Energy and Fuels. 7. 432-433 (1993)

[Publications] K.Omata: "“Methane Partial Oxidation to Methanol.1.Effects of Reaction Conditions and Additives"" Ind.and Eng.Chem.Res.(in press).

[Publications] M.Shirai: "“Polarized Total-Reflection Fluorescence EXAFS Study of Anisotropic Structure Analysis for Co Oxides on α-Al_2O_3(0001)as Model Surfaces for Active Oxidation Catalysts"" J.Catal.145. 159-165 (1994)

[Publications] Y.Iwasawa: "“Chemical Design and Characterization of Catalysts and Catalysis:An Approach to Dynamic Catalyst Design"" Catal.Today.18. 21-72 (1993)

[Publications] N.Ichikuni: "“Structures and Catalysis of New Nb Dimers on SiO_2"" Catal.Today.16. 427-434 (1993)

[Publications] J.Inukai: "“Reversible Activity Enhancement of SiO_2-Supported Group VIII Metal Catalysts by Pretreatment Temperature"" J.Catal.143. 22-31 (1993)

[Publications] M.Shirai: "“Polarized Total-Reflection Fluorescence EXAFS Studies on Asymmetric Surface Structures of Catalysts"" Jpn.J.Apply.Phys.32. 413-415 (1993)

[Publications] K.Asakura: "“Asymmetric Structure Analysis of Active Surface Sites by in situ Polarized Total-Reflection Fluorescence EXAFS"" Catal.Lett.20. 117-124 (1993)

[Publications] N.Ichikuni: "“In situ d Electron Density of Pt Particles on Supports by XANES"" Catal.Lett.20. 87-95 (1993)

[Publications] Y.Iwasawa: "New Frontiers in Catalysis" L.Guczi,F.Solymosi,P.Tetenyi Eds., (1993)

[Publications] Y.Iwasawa: "Elementary Reaction Steps in Heterogeneous Catalysis" R.W.Joyner,R.A.van Santen Eds., (1993)

[Publications] Y.Iwasawa: "“Catalysis by Structurally Designed Surfaces"" K.Tamaru Ed., (1993)

干鯛眞信東京大学, 工学部, 教授 (60011011)