1994 Fiscal Year Annual Research Report

不活性小分子の活性化

Research Project

Project/Area Number	04241104
Research Institution	The University of Tokyo
Principal Investigator	干鯛眞信東京大学, 工学部, 教授 (60011011)
Co-Investigator(Kenkyū-buntansha)	岩澤康裕東京大学, 理学部, 教授 (40018015) 齋藤太郎東京大学, 理学部, 教授 (90011006) 藤元薫東京大学, 工学部, 教授 (30011026) 村井真二大阪大学, 工学部, 教授 (00029050) 長倉三郎総合研究大学院大学, 学長 (30013444)
Keywords	不活性小分子 / 窒素分子 / メタン / 二酸化炭素 / 金属クラスター / 固体表面
Research Abstract	本研究は平成4年度より発足した重点領域研究「不活性小分子の活性化」の総括班の平成6年度計画研究に関するもので、本領域における研究計画の円滑な推進と各研究班間の情報・意見交換、ならびに研究成果の他分野および社会への広報・還元を計ることを目的としている。平成6年度は当初の研究計画に基づき2回の公開シンポジウム(第5回ならびに第6回公開シンポジウム)を開催した。第5回公開シンポジウムは平成6年7月8、9日に京都で開催し、81名の出席者があった。講演は各研究班から2〜4名ずつ計13名の研究者により行われ、研究結果の詳しい説明がなされて活発な質疑、討論が行われた。また、これにあわせて総括班会議、各班会議、全体会議が行われ、研究成果に関する討論、研究計画に関連する連絡が行われた。第6回公開シンポジウムは12月12、13日に東京で開催し、107名の出席者があった。講演は各研究班から1/5名ずつ計13名の研究者により行われ、研究結果の詳しい説明と質疑、討論が行われるとともに、シンポジウムとあわせて総括班会議、各班会議、全体会議が開かれた。さらに11月7日に京都で合同班会議を開き、研究の進捗状況について討論を行った。さらに、班間にまたがる6件の共同研究に対して、総括班より研究費の助成を行った。この他、9月14日〜16日にフランス Rennes 大学において European Research Network on "Small Molecules: Selective Process and Catalyses" との協同シンポジウムを行い、日本からは本重点領域の班員を中心に17名が参加した。なお、研究成果のとりまとめと広報活動に関しては、上記2回の公開シンポジウムでの講演要旨集ならびに領域全研究者による平成6年度研究成果報告書を作成して各研究者に配布した。

Research Products

(18 results)

All Other

All Publications (18 results)

[Publications] Y.Harada: "Conjugate Additions of Organocuprates to α,β-Unsaturated Diazoalkane Complexes of Molybdenum and Tungsten" Chem.Lett.13. 364-369 (1994)
[Publications] H.Seino: "1-Pyrrolylimido Complexes of Molybdenum and Tungsten: Synthesis of Pyrrole from Mloecular Dinitrogen and Unusual β-Regioselective Substitution Reactions of the Pyrrole Ring on a Metal Complex" J.Am.Chem.Soc.116. 7433-7434 (1994)
[Publications] Y.Mizobe: "Preparation of Heterobimetallic Complexes with a Bridging Dinitrogen Ligand,[WX(PMe_2Ph)_4(μ-N_2)MCp_2Cl], and X-ray Structure of [WI(PMe_2Ph)_3(py)(μ-N_2)ZrCp_2Cl]" Organometallics. 13. 3764-3766 (1994)
[Publications] Y.Ishii: "Bimetallic Arylation of Molecular Nitrogen" Organometallics. 13. 5062-5071 (1994)
[Publications] A.Orita: "Reactions via Carbonyl Anions.[4+1] Cyclocoupling of the Azadienyllithium with Carbon Monoxide" J.Org.Chem.59. 477-481 (1994)
[Publications] A.Orita: "Reaction of Lithium Silylamides with Carbon Monoxide Leading to Carbamoylsilanes" Organometallics. 13. 1533-1536 (1994)
[Publications] T.Nozaki: "Oxide Ion Transport for Selective Oxidative Coupling of Methane with New Membrane Reactor" AIChE Journal. 40. 870-877 (1994)
[Publications] K.Omata: "Methane Partial Oxidation to Methanol. 1.Effects of Reaction Conditions and Additives" Ind.Eng.Chem.Res.33. 784-789 (1994)
[Publications] X.Li: "Low Temperature Oxidative Coupling of Methane by Perovskite Oxide" Chem.Lett.1581-1584 (1994)
[Publications] K.Omata: "Oxidative Coupling of Methane on an ABO3 Type Oxide with Mixed Conductivity" J.Chem.Soc.,Chem.Commun.1647-1648 (1994)
[Publications] K.Fujimoto: "New Uses of Methane" Stud.Surf.Sci.Catal.81. 73-84 (1994)
[Publications] O.Yamazaki: "Selective Oxidation of Methane to C_2 Hydrocarbons with Molten Metal Oxide" Stud.Surf.Sci.Catal.81. 277-279 (1994)
[Publications] J.Mizutani: "Synthesis and Structure of a Pyridine Complex of Trinuclear Molybdenum Cluster [Mo_3S_4Cl_4(py)_5]" Chem.Lett.2117-2118 (1994)
[Publications] Y.Izumi: "CO-Breathing Structure Change and Catalysis for Oxygenate Synthesis form CO/H_2 on Supported [Ru_6C] Clusters: Structural and Chemical Controls by Interstitial Carbido Carbon" J.Phys.Chem.98. 594-602 (1994)
[Publications] K.Tomishige: "Design and Characterization by EXAFS, FTIR, and TEM of Rh-Sn/SiO_2 Catalysts Active for NO-H_2 Reaction" J.Catal.149. 70-80 (1994)
[Publications] N.Ichikuni: "Observation of the Structural Change in the Nb Sites During Ethanol Dehydration on a SiO_2-Attached Nb Diner Catalyst by EXAFS" J.Phys.Chem. 98. 11576-11581 (1994)
[Publications] M.Shirai: "Polarized total-Reflection Fluorescence EXAFS Study of Anisotropic Structure Analysis for Co Oxides on α-Al_2O_3(0001) as Model Surfaces for Active Oxidation Catalysts" J.Catal.145. 159-165 (1994)
[Publications] K.Tomishige: "In-situ EXAFS Observation of the Molecular Reaction Intermediate for NO-H_2 Reaction on Highly Active Rh-Sn/SiO_2 Catalysts" Chem.Lett.235-238 (1994)

1994 Fiscal Year Annual Research Report

不活性小分子の活性化

Principal Investigator

干鯛 眞信 東京大学, 工学部, 教授 (60011011)

Research Products

[Publications] Y.Harada: "Conjugate Additions of Organocuprates to α,β-Unsaturated Diazoalkane Complexes of Molybdenum and Tungsten" Chem.Lett.13. 364-369 (1994)

[Publications] H.Seino: "1-Pyrrolylimido Complexes of Molybdenum and Tungsten: Synthesis of Pyrrole from Mloecular Dinitrogen and Unusual β-Regioselective Substitution Reactions of the Pyrrole Ring on a Metal Complex" J.Am.Chem.Soc.116. 7433-7434 (1994)

[Publications] Y.Mizobe: "Preparation of Heterobimetallic Complexes with a Bridging Dinitrogen Ligand,[WX(PMe_2Ph)_4(μ-N_2)MCp_2Cl], and X-ray Structure of [WI(PMe_2Ph)_3(py)(μ-N_2)ZrCp_2Cl]" Organometallics. 13. 3764-3766 (1994)

[Publications] Y.Ishii: "Bimetallic Arylation of Molecular Nitrogen" Organometallics. 13. 5062-5071 (1994)

[Publications] A.Orita: "Reactions via Carbonyl Anions.[4+1] Cyclocoupling of the Azadienyllithium with Carbon Monoxide" J.Org.Chem.59. 477-481 (1994)

[Publications] A.Orita: "Reaction of Lithium Silylamides with Carbon Monoxide Leading to Carbamoylsilanes" Organometallics. 13. 1533-1536 (1994)

[Publications] T.Nozaki: "Oxide Ion Transport for Selective Oxidative Coupling of Methane with New Membrane Reactor" AIChE Journal. 40. 870-877 (1994)

[Publications] K.Omata: "Methane Partial Oxidation to Methanol. 1.Effects of Reaction Conditions and Additives" Ind.Eng.Chem.Res.33. 784-789 (1994)

[Publications] X.Li: "Low Temperature Oxidative Coupling of Methane by Perovskite Oxide" Chem.Lett.1581-1584 (1994)

[Publications] K.Omata: "Oxidative Coupling of Methane on an ABO3 Type Oxide with Mixed Conductivity" J.Chem.Soc.,Chem.Commun.1647-1648 (1994)

[Publications] K.Fujimoto: "New Uses of Methane" Stud.Surf.Sci.Catal.81. 73-84 (1994)

[Publications] O.Yamazaki: "Selective Oxidation of Methane to C_2 Hydrocarbons with Molten Metal Oxide" Stud.Surf.Sci.Catal.81. 277-279 (1994)

[Publications] J.Mizutani: "Synthesis and Structure of a Pyridine Complex of Trinuclear Molybdenum Cluster [Mo_3S_4Cl_4(py)_5]" Chem.Lett.2117-2118 (1994)

[Publications] Y.Izumi: "CO-Breathing Structure Change and Catalysis for Oxygenate Synthesis form CO/H_2 on Supported [Ru_6C] Clusters: Structural and Chemical Controls by Interstitial Carbido Carbon" J.Phys.Chem.98. 594-602 (1994)

[Publications] K.Tomishige: "Design and Characterization by EXAFS, FTIR, and TEM of Rh-Sn/SiO_2 Catalysts Active for NO-H_2 Reaction" J.Catal.149. 70-80 (1994)

[Publications] N.Ichikuni: "Observation of the Structural Change in the Nb Sites During Ethanol Dehydration on a SiO_2-Attached Nb Diner Catalyst by EXAFS" J.Phys.Chem. 98. 11576-11581 (1994)

[Publications] M.Shirai: "Polarized total-Reflection Fluorescence EXAFS Study of Anisotropic Structure Analysis for Co Oxides on α-Al_2O_3(0001) as Model Surfaces for Active Oxidation Catalysts" J.Catal.145. 159-165 (1994)

[Publications] K.Tomishige: "In-situ EXAFS Observation of the Molecular Reaction Intermediate for NO-H_2 Reaction on Highly Active Rh-Sn/SiO_2 Catalysts" Chem.Lett.235-238 (1994)

干鯛眞信東京大学, 工学部, 教授 (60011011)