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1993 Fiscal Year Final Research Report Summary

Study of development of selective determination and separation method for trace element

Research Project

Project/Area Number 04303004
Research Category

Grant-in-Aid for Co-operative Research (A)

Allocation TypeSingle-year Grants
Research Field 分析・地球化学
Research InstitutionHokkaido University

Principal Investigator

TAGA Mitsuhiko  Hokkaido University, Dep.of Chem., Professor, 理学部, 名誉教授 (90000778)

Co-Investigator(Kenkyū-buntansha) YOSHIMURA Kazuhisa  Kyushu University, College of General Education, Professor, 教養部, 教授 (80112291)
KUMAMARU Takahiro  Hiroshima University, Faculty of Sci., Professor, 理学部, 教授 (50033816)
MOTOMIZU Shoji  Okayama University, Faculty of Sci., Professor, 理学部, 教授 (50032826)
OGUMA Koichi  Chiba University, Faculty of Engineering, Professor, 工学部, 教授 (60009529)
NAKAMURA Hroshi  Hokkaido University, Graduate School of Environ.Earth Sci., Professor, 大学院・地球環境科学研究科, 教授 (00117194)
Project Period (FY) 1992 – 1993
KeywordsComplexing ability / Adduct formation / Synthetic reference material / Humic acid / Metal furnace / Fluorescent reagent / Flow injection analysis / Ion-interaction chromatography
Research Abstract

The new determination methods having high sensitivity and selectivity were studied in this project for the speciation and charactarization of trace elements in environmental and biological samples and new materials.
1. The development of speciation methods for trace elements in ebvironmental and biological samples. The complexing ability of humic acid was evaluated exactly by anodic stripping voltammetry using the effect of sodium dodecyl sulfate(SDS). The pre-concentration methods of trace elements in polystylene film or PCTFE resin were developed and applied to analyzes of seawater and river water. A synthetic multi-element reference materials with a pseudo-biological composition was prepared and the usefulness as a atandard material was demonatrated.
2. The high selective separation and determination methods based on new viewpoint. The excellent separation of metal and rare earth metal ions was achieved by introducing adduct formation and masking effect to mobile phase system of HPLC … More and ion-interaction chromatography. The possibility of titania microparticles as a promising matrix for HPLC was investigated.
3. The development of analytical reagent having new function. A new fluorescent reagent which has two anthracene moieties at both terminals on linear polyether was synthesized. The fluorescent spectrum of the reagent changed from that of monomer to dimer at the complexation with metal ions. From extraction behavior of beta-diketone, the chelate ring rigidity was found to be a parameter governing the ion size recognition. Novel cationic triphenylmethane dyes were synthesized and their characteristics were investigated to evaluate them as an ion association reagent.
4. On-line system for the rapid and sensitive determination and separation. Flow injection methods by catalysis of oxidative coupling reaction, ion-exchange phase absorptiometry and ICP method using metal furnace vaporization via in situ solid phase reaction were developed for the determination of trace elements in environmental samples. Less

  • Research Products

    (52 results)

All Other

All Publications (52 results)

  • [Publications] M.Fukushima: "Effect of sodium dodecyl sulfate on measurement of labile copper(II)species in the presence of humuc acid by anodic stripping voltammetry" Anal.Chim.Acta. 270. 153-159 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Fukushima: "Interaction between humic acids and copper(II)oxinate" Anal.Chim.Acta. (in press). (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Kakizawa: "Syntheses and complexing behavior of new fluorescent reagents for alkaline earth metal ions" Chem.Lett.1671-1674 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Nakamura: "Time resolved electron spin resonance spectra of linked radical pairs on laser excitation of zinc tetraphenylporphyrin-viologen systems" J.Phys.Chem.97. 534-536 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Iwata: "Preparation of thin support film for PIXE and its application to trace analysis of biological materials" Intern.J.PIXE. 2. 381 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Nakamura: "Synergistic extraction of tervalent lanthanoids with 2-thenoyltrifluoro-acetone and ethylenediamine as a neutral bidentate ligand," Anal.Chim.Acta. 270. 95 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Yasud: "Solvent Extraction of Divalent Metals as Dihydrobis(1-pyrazolyl)borate Chelates" Bull.Chem.Soc. 65. 781 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Ogura: "Voltammetric Study on the Transfer of Alkali and Alkaline Earth Metal Ions at the Aqueous/Organic Interface Facilitated by Phosphine Oxides" Bull.Chem.Soc.Jpn.,. 66. 1971 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Motomizu: "Spectrophotometric determination of cationic and anionic surfactants with anionic dyes in the presence of nonionic surfactants,Part I:general aspect" Microchim.Acta. 106. 57 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Hagiwara: "Equilibrium and kinetic studies on the formation of triphenylmethanols from triphenylmethane dyes" Bull.Chem.Soc.Jpn.,. 67(in press). (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] E.Iwamoto: "Graphite furnace atomic absorption spectrometry with graphite cloth ribbon and its application to determination of arsenic in mussel" Anal.Sci.,. 8. 389 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Fujiwara: "Automated method for the selective determination of gold by on-line solvent extraction and reversed micellar mediated luminol chemiluminescence detection" Microchem.J.,. (in press.).

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] U.Hase: "Determination of trace amounts of iron in highly purified water by ion-exchanger phase absorptiometry combined with flow analysis" Talanta. 39. 1019 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] U.Hase: "Determination of silicic acid in highly purified water by improved gel-phase absorptiometry" Anal.Sci.,. 9. 111 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Nakano: "Flow injection determination of chromium(III)by pyrogallol chemiluminescence" Talanta. 40. 75-80 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Teshima: "Effect of ligands on the iron(III)/iron(II)system and its novel application to simultaneous flow injection determination of vanadium(IV)and vanadium(V)" Anal.Sci.,. 10. 207-212 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Tsunoda: "Characteristics of Potasium Ion Doped Slab Optical Waveguide as Absorption Cell and its Application to Spectrophotometric Determination of Methylene Blue" Anal.Chim.Acta. 276. 133-139 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Kawamoto: "Labitity of Soluble Copper(II)Complex in River Waters in the Uban Area" Bull.Chem.Soc.Jpn.,. 66. 2104-2105 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Kuroda: "Ion interaction chromatography of nitrilotriacetatocomplexes of the rare earth elements with post-column reaction detection" Talanta. 40. 237 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Kuroda: "Selective determination of yttrium in geological materials by ion-interaction chromatography" Mikrochim.Acta. 110. 47 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Ikeguchi: "Flow Injection-Acid Hydrolysis Technique for Determination of Organic Phosphates" Anal.Sci.,. 9. 397 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Murayama: "Preparation and Evaluation of Octadecyl Titania as Column Packing Material for High Performance Liquid Chromatography" Microchem.J.,. in press.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Katsura: "Enhancement effect of palladium and Albumin on the sensitivities of group IIIB-VIB elements in graphite furnace atomic absorption spectrometry" Anal.Sci.,. 8. 97 (1992)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Matsumoto: "Palladium as a matrix modifier in graphite-furnace atomic absorption spectrometry of group IIIB-VIB elements" Anal.Sci.,. 9. 447 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Billah: "Preconcentration and determination of a trace amount of manganese as its thenoyltrifluor acetone complex with dibenzo-18-crown-6 by means of synergistic extraction" Anal.Sci.,. 9. 251 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] L.Zhang: "Spectrophotometric determination of cobalt(II)in water after preconcentration by sorption of its nitroso R complex with poly(chlorotrifluoroethylene)resin" Anal.Sci.,. 10(in press). (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Fukushima: "Effect of sodium dodecyl sulfate on measurement of labile copper(II) species in the presence of humic acid by apdoc striping voltammetry" Anal.Chim.Acta. 270. 153-159 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Fukushima: "Interaction between humic acids and Copper(II) oxinate" Anal.Chim.Acta. (in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Kakizawa: "Syntheses and complexing behavior of new fluorescent reagents for alkaline earth metal ions" Chem.Lett.1671 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Nakamura: "Time resolved electron spin resonance spectra of linked radical pairs on laser excitation of zinc tetraphenylporphyrin-viologen systems" J.Phys.Chem.97. 554 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Iwata: "Preparation of thin support film for PIXE and its application to trace analysis of biological materials" Intern.J.PIXE. 2. 361 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Nakamura: "Synergic extraction of tervalent lanthanoids with 2-thenoyltrifluoroacetone and ethylenediamine as a neutral bidentate ligand" Anal.Chim.Acta. 270. 95 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Nakano: "Flow injection determination of chromium(III) by pyrogallol chemiluminescence" Talanta. 40. 75 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N.Teshima: "Effect of ligands on the iron(III)/iron(II) system and its novel application to simultaneous flow injection determination of vanadium(IV) and vanadium(V)" Anal.Sci.10. 207 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Tsunoda: "Charactaristics of Potasium Ion Doped Slab Optical Waveguide as Absorption Cell and its Application to Spectrophotometric Determination of Methylene Blue" Anal.Chim.Acta. 276. 133 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Kawamoto: "Labitity of Soluble Copper(II) Complex in River Waters in the Uban Area" Bull.Chem.Soc.Jpn.66. 2104 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.Kuroda: "Ion interaction chromatography of nitrilotriacetatocomplexes of the rare earth elements with post-column reaction detection" Talanta. 40. 237 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.Kuroda: "Selective determination of yttrium in geological materials by ion-interaction chromatography" Mikrochim.Acta. 110. 47 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Ikeguchi: "Flow Injection - Acid Hydrolysis Technique for Determination of Organic Phosphates" Anal.Sci.9. 397 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Murayama: "Preparation and Evaluation of Octadecyl Titania as Column Packing Material for High Performance Liquid Chromatography" Microchem.J.(in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.katsura: "Enhancement effect of palladium and Albumin on the sensitivities of group IIIB-VIB elements in graphite furnace atomic absorption spectrometry" Anal.Sci.6. 97 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Matsumoto: "Palladium as a matrix modifier in graphite-furnace atomic absorption spectrometry of group IIIB-VIB elements" Anal.Sci.9. 447 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Billah: "Preconcentration and determination of a trace amount of manganese as it acetone comlex with dibenzo-18-crown-6 by means of synergistic extraction" Anal.Sci.9. 251 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] L.Zhang: "Spectrophotometric determination of cobalt(II) in water after preconcentration by sorption of its nitroso R complex with poly(chlorotrifluoroethylene) resin" Anal.Sci.10, (in press). (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N.Yasud: "Solvent Extraction of Divalent Metals as Dihydrobis(1-pyrazolyl) borate Chelates" Bull.Chem.Soc.Jpa. 65. 761 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Ogura: "Voltammetric Study on the Transfer of Alkali and Alkaline Earth Metal Ions at the Aqueous/Organic Interface Facilitated by Phosphine Oxides" Bull.Chem.Soc.Jpn.66. 1971 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Motomizu: "spectrophotometric determination of cationic and anionic surfactants with anionic dyes in the presence of nonionic surfactants, Part I : general aspect" Microchim.Acta. 106. 57 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Hagiwara: "Equilibrium and kinetic studies on the formation of triphenylmethanols from triphenylmethane dyes" Bull.Chem.Soc.Jpn.67, (in press). (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] E.Iwamoto: "Graphite furnace atomic absorption spectrometry with graphite cloth ribbon and its application to determination of arsenic in mussel" Anal.Sci.8. 389 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T.Fujiwara: "Automated method for the selective determination of gold by on-line solvent extraction and reversed micellar madiated luminol chemiluminescence detection" Microchem.J.(in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] U.Hase: "Determination of trace amounts of iron in highly purified water by ion-exchanger phase absorptiometry combined with flow analysis" Talanta. 39. 1019 (1992)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] U.Hase: "Determination of silicic acid in highly purified water by improved gel-phase absorptiometry" Anal.Sci.9. 111 (1993)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1995-03-27  

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