1993 Fiscal Year Annual Research Report

有機電気化学の新展開

Research Project

Project/Area Number	05235101
Research Institution	Tohoku University
Principal Investigator	長哲郎東北大学, 薬学部, 教授 (10010753)
Co-Investigator(Kenkyū-buntansha)	内本喜一朗京都大学, 工学部, 教授 (90025958) 鳥居滋岡山大学, 工学部, 教授 (70032927) 野中勉東京工業大学, 大学院・総合理工学研究科, 教授 (00016528)
Keywords	有機電気化学 / 生物電気化学
Research Abstract	本研究は重点領域研究「有機電気化学の新展開」の総括班として機能し、評価グループ(6名)は高い学識から本領域研究に対する評価を行うとともに運営についての適切な助言を与えた。実施グループ(研究代表者、4班の各班長、生物電気化学の有機電気化学への展開を計るための担当者の計6名から構成)は評価グループの助言に対処するとともに研究班相互の連携を緊密化し、研究計画全体の効果的実現を計った。 1.会議の開催平成5年7月2〜3日熊本市において(第15回エレクトロオーガニックケミストリー討論会終了後)まず全体会議を持ち、代表者、各班長による本重点領域研究の目的、計画等の説明、評価班員による挨拶があり、引き続き班会議において計画・公募班員の研究説明、研究目標等について議論がなされた。第2回全体会議(松永是、小久見善八、仁木克己、土田英俊の研究発表)と第1回公開シンポジウム(藤島昭、大森秀信、佐々木和夫、大辻吉男の他、部外の本多健一、西山明徳の講演)が12月6〜7日仙台市で開催され、同時に総括班会議、班会議が行われた。 2.印刷物の発行ニュースレター3回および班員名簿を班員を主な対象として配布した。また全体会議および公開シンポジウムの要旨集を配布した。 3.研究成果の早期公開など全班員の本年度成果の和文および英文報告書を年度末までに配布し、自他の研究計画等の評価、他班の班員との研究協力などへの利用、第三者への早期公開への利用に供した。

Research Products

(32 results)

All Other

All Publications (32 results)

[Publications] Yoshitomo Kashiwagi: "Electrocatalytic Oxidative Coupling Reaction of Naphthols and Naphthol Ethers" Chemistry Letters. 81-84 (1993)
[Publications] Yoshitomo Kashiwagi: "Electrocatalytic Oxidative Coupling of Methylquinolines on TEMPO-Modified Graphite Felt Electrode" Chemistry Letters. 257-260 (1993)
[Publications] Yoshitomo Kashiwagi: "Electrocatalytic Oxidation of NADH on Thin Poly(acrylic acid)Film Coated Graphite Felt Electrode Coimmobilizing Ferrocene and Diaphorase" Chemistry Letters. 677-680 (1993)
[Publications] Iwao Suzuki: "Electrochemical Conversion of Alcohols into Aldehydes Mediated by Lipophilic γ-Cyclodextrin Bearing a Ferrocene Moiety" Chemistry Letters. 1719-1722 (1993)
[Publications] 長哲郎: "高分子修飾電極を用いる電解合成" 化学工業. 45. 121-126 (1994)
[Publications] Tetsuo Osa: "Electroenzymatic Oxidation of Alcohols on a Poly(acrylic acid)-coated Graphite Felt Electrode Terimmobilizing Ferrocene,Diaphorase and Alcohol Dehydrogenase" Chemistry Letters. 367-370 (1994)
[Publications] M.Umezawa: "Electroreductive Polymerization of Dichlorocarbosilanes" Electrochimica Acta. 38. 529-533 (1993)
[Publications] Po-Chung Cheng: "Electroreduction of Methyl Cinnamate Using a Rotating Cylinder Electrode" Denki Kagaku. 61. 218-223 (1993)
[Publications] Shu-Yong Guo: "Maximum in Oxidizing Power of Anodically-Generated Br-Cl Composite Reagents" Denki Kagaku. 61. 245-246 (1993)
[Publications] Po-Chung Cheng: "Electron-Transfer Process in Emulsion Electrolysis" Denki Kagaku. 61. 886-887 (1993)
[Publications] Yoshihito Kunugi: "Electroorganic Reactions on Organic Electrodes.Part18" Journal of Electroanalytical Chemistry. 353. 209-215 (1993)
[Publications] Yoshihito Kunugi: "Preparation of Hydrophobic Zinc and Lead Electrodes and Their Application to Electroreduction of Organic Compounds" Journal of Electroanalytical Chemistry. 356. 163-169 (1993)
[Publications] Yoshihito Kunugi: "Electrolysis of Emulsion of Organic Compounds" Denki Kagaku. 140. 2833-2836 (1993)
[Publications] 野中勉: "電極電子化学" 電気学会誌. 113. 727-731 (1993)
[Publications] 野中勉: "有機電解用電極材料の新展開" 表面. 31. 737-745 (1993)
[Publications] 野中勉: "疎水性電極による有機電解" 化学工業. 45. 127-130 (1994)
[Publications] Hideo Tanaka: "2-Substituted Penems,New Candidates for Cephalosporinase Inhibitors" Bioorganic & Medicinal Chemistry Letter. 3. 2253-2254 (1993)
[Publications] Hideo Tanaka: "Mg/PbBr_2 Bimetal Redox-Promoted Stannation of Propargyl,Allyl,Vinyl,and Aryl Halides" Synlett. 835-836 (1993)
[Publications] Tsutomu Inokuchi: "Electrochemical Wacker Type Reaction with a Double Mediatory System Consisting of Palladium Complex and Tri(4-bromophenyl)amine" Chemistry Letters. 121-124 (1994)
[Publications] Sigeru Torii: "Electroreduction of 5-Chloro-7-nitrobenzofuran Derivative,a Facile Access to a Key Intermediate for ACTA Inhibitors" Synlett. 68 (1994)
[Publications] Sigeru Torii: "Electrochemical Generation of C-N-C 1,3-Dipole Leading to Pyrrolidine Skeleton" Synlett. 印刷中. (1994)
[Publications] Ryohei Yamaguchi: "A Highly Effective One-Pot Bicycloannulation Methodology for the Synthesis of Berban and Yohimban Systems Based on Organotin-Mediated Three-Componennt Coupling(N-Acylative Pentadienylation of C=N Bonds)" Journal of Organic Chemistry. 58. 1136-1143 (1993)
[Publications] Hiroshi Shinokubo: "tert-Butyldimethylsilyldichloromethyllithium as a Dichloromethylene Dianion Synthon 1,3-Rearrangement of Silyl Group from Carbon to Oxide" Tetrahedron Letters. 34. 1951-1954 (1993)
[Publications] Hiroshi Shinokubo: "Rearrangement of β-t-Butyldimethylsiloxy Carbenoids.Regio-and Stereoselective Synthesis of (Z)-1-Halo-2-tert-butyldimethylsiloxy-1-alkenes" Tetrahedron Letters. 34. 4985-4988 (1993)
[Publications] Masahiko Taniguchi: "Triethylborane Induced Intermolecular Hydrogermylation of Homoallylic Alcohols and Homopropargylic Alcohols" Chemistry Letters. 1751-1754 (1993)
[Publications] Kozo Matsumoto: "Lithium Carbenoids Induced Ring Enlargement of Silacyclobutane into 2-Halo-1-silacyclopentane and its Use in Organic Synthesis" Tetrahedron. 49. 8487-8502 (1993)
[Publications] 内本喜一朗: "有機金属化合物を用いる高選択的有機反応" 有機化学合成協会誌. 51. 1064-1073 (1993)
[Publications] Masahiko Taniguchi: "Stereoselective Reduction of 2-Methyl-3-oxo Ethers(or Amides)with Sodium Borohydride Catalyzed By Manganese(II)Chloride or Tetrabutylammonium Borohydride.A Practical Preparation of erythro and threo-3-Hydroxy-2-methyl Esters(or Amides)" Tetrahedron. 49. 11169-11182 (1993)
[Publications] Kazuhiko Takai: "A Dramatic Effect of a Catalytic Amount of Lead on the Simmons-Smith Reaction and Formation of Alkylzinc Compounds from Iodo Alkanes.Reactivity of Zinc Metal:Activation and Deactivation" Journal of Organic Chemistry. (印刷中). (1994)
[Publications] Seijiro Matsubara: "Lanthanoid Triflate Catalyzed Conjugate Addition of Amines to α,β-Unsaturated Esters.A Facile Route to Optically Active β-Lactam" Chemistry Letters. (印刷中). (1994)
[Publications] Seijiro Matsubara: "Diastereoselective Addition of Organometallic Reagents to Imines or Hydrazones Containing 1,3-Oxathiane as a Chiral Template" Chemistry Letters. (印刷中). (1994)
[Publications] Tsutomu Nonaka: "New Functionality Materials,Vol.C(ed by M.Doyama)" Elsevier Sci.Pub.B.V., 6 (1993)

1993 Fiscal Year Annual Research Report

有機電気化学の新展開

Principal Investigator

長 哲郎 東北大学, 薬学部, 教授 (10010753)

Research Products

[Publications] Yoshitomo Kashiwagi: "Electrocatalytic Oxidative Coupling Reaction of Naphthols and Naphthol Ethers" Chemistry Letters. 81-84 (1993)

[Publications] Yoshitomo Kashiwagi: "Electrocatalytic Oxidative Coupling of Methylquinolines on TEMPO-Modified Graphite Felt Electrode" Chemistry Letters. 257-260 (1993)

[Publications] Yoshitomo Kashiwagi: "Electrocatalytic Oxidation of NADH on Thin Poly(acrylic acid)Film Coated Graphite Felt Electrode Coimmobilizing Ferrocene and Diaphorase" Chemistry Letters. 677-680 (1993)

[Publications] Iwao Suzuki: "Electrochemical Conversion of Alcohols into Aldehydes Mediated by Lipophilic γ-Cyclodextrin Bearing a Ferrocene Moiety" Chemistry Letters. 1719-1722 (1993)

[Publications] 長 哲郎: "高分子修飾電極を用いる電解合成" 化学工業. 45. 121-126 (1994)

[Publications] Tetsuo Osa: "Electroenzymatic Oxidation of Alcohols on a Poly(acrylic acid)-coated Graphite Felt Electrode Terimmobilizing Ferrocene,Diaphorase and Alcohol Dehydrogenase" Chemistry Letters. 367-370 (1994)

[Publications] M.Umezawa: "Electroreductive Polymerization of Dichlorocarbosilanes" Electrochimica Acta. 38. 529-533 (1993)

[Publications] Po-Chung Cheng: "Electroreduction of Methyl Cinnamate Using a Rotating Cylinder Electrode" Denki Kagaku. 61. 218-223 (1993)

[Publications] Shu-Yong Guo: "Maximum in Oxidizing Power of Anodically-Generated Br-Cl Composite Reagents" Denki Kagaku. 61. 245-246 (1993)

[Publications] Po-Chung Cheng: "Electron-Transfer Process in Emulsion Electrolysis" Denki Kagaku. 61. 886-887 (1993)

[Publications] Yoshihito Kunugi: "Electroorganic Reactions on Organic Electrodes.Part18" Journal of Electroanalytical Chemistry. 353. 209-215 (1993)

[Publications] Yoshihito Kunugi: "Preparation of Hydrophobic Zinc and Lead Electrodes and Their Application to Electroreduction of Organic Compounds" Journal of Electroanalytical Chemistry. 356. 163-169 (1993)

[Publications] Yoshihito Kunugi: "Electrolysis of Emulsion of Organic Compounds" Denki Kagaku. 140. 2833-2836 (1993)

[Publications] 野中 勉: "電極電子化学" 電気学会誌. 113. 727-731 (1993)

[Publications] 野中 勉: "有機電解用電極材料の新展開" 表面. 31. 737-745 (1993)

[Publications] 野中 勉: "疎水性電極による有機電解" 化学工業. 45. 127-130 (1994)

[Publications] Hideo Tanaka: "2-Substituted Penems,New Candidates for Cephalosporinase Inhibitors" Bioorganic & Medicinal Chemistry Letter. 3. 2253-2254 (1993)

[Publications] Hideo Tanaka: "Mg/PbBr_2 Bimetal Redox-Promoted Stannation of Propargyl,Allyl,Vinyl,and Aryl Halides" Synlett. 835-836 (1993)

[Publications] Tsutomu Inokuchi: "Electrochemical Wacker Type Reaction with a Double Mediatory System Consisting of Palladium Complex and Tri(4-bromophenyl)amine" Chemistry Letters. 121-124 (1994)

[Publications] Sigeru Torii: "Electroreduction of 5-Chloro-7-nitrobenzofuran Derivative,a Facile Access to a Key Intermediate for ACTA Inhibitors" Synlett. 68 (1994)

[Publications] Sigeru Torii: "Electrochemical Generation of C-N-C 1,3-Dipole Leading to Pyrrolidine Skeleton" Synlett. 印刷中. (1994)

[Publications] Ryohei Yamaguchi: "A Highly Effective One-Pot Bicycloannulation Methodology for the Synthesis of Berban and Yohimban Systems Based on Organotin-Mediated Three-Componennt Coupling(N-Acylative Pentadienylation of C=N Bonds)" Journal of Organic Chemistry. 58. 1136-1143 (1993)

[Publications] Hiroshi Shinokubo: "tert-Butyldimethylsilyldichloromethyllithium as a Dichloromethylene Dianion Synthon 1,3-Rearrangement of Silyl Group from Carbon to Oxide" Tetrahedron Letters. 34. 1951-1954 (1993)

[Publications] Hiroshi Shinokubo: "Rearrangement of β-t-Butyldimethylsiloxy Carbenoids.Regio-and Stereoselective Synthesis of (Z)-1-Halo-2-tert-butyldimethylsiloxy-1-alkenes" Tetrahedron Letters. 34. 4985-4988 (1993)

[Publications] Masahiko Taniguchi: "Triethylborane Induced Intermolecular Hydrogermylation of Homoallylic Alcohols and Homopropargylic Alcohols" Chemistry Letters. 1751-1754 (1993)

[Publications] Kozo Matsumoto: "Lithium Carbenoids Induced Ring Enlargement of Silacyclobutane into 2-Halo-1-silacyclopentane and its Use in Organic Synthesis" Tetrahedron. 49. 8487-8502 (1993)

[Publications] 内本喜一朗: "有機金属化合物を用いる高選択的有機反応" 有機化学合成協会誌. 51. 1064-1073 (1993)

[Publications] Kazuhiko Takai: "A Dramatic Effect of a Catalytic Amount of Lead on the Simmons-Smith Reaction and Formation of Alkylzinc Compounds from Iodo Alkanes.Reactivity of Zinc Metal:Activation and Deactivation" Journal of Organic Chemistry. (印刷中). (1994)

[Publications] Seijiro Matsubara: "Lanthanoid Triflate Catalyzed Conjugate Addition of Amines to α,β-Unsaturated Esters.A Facile Route to Optically Active β-Lactam" Chemistry Letters. (印刷中). (1994)

[Publications] Seijiro Matsubara: "Diastereoselective Addition of Organometallic Reagents to Imines or Hydrazones Containing 1,3-Oxathiane as a Chiral Template" Chemistry Letters. (印刷中). (1994)

[Publications] Tsutomu Nonaka: "New Functionality Materials,Vol.C(ed by M.Doyama)" Elsevier Sci.Pub.B.V., 6 (1993)

長哲郎東北大学, 薬学部, 教授 (10010753)

[Publications] 長哲郎: "高分子修飾電極を用いる電解合成" 化学工業. 45. 121-126 (1994)

[Publications] 野中勉: "電極電子化学" 電気学会誌. 113. 727-731 (1993)

[Publications] 野中勉: "有機電解用電極材料の新展開" 表面. 31. 737-745 (1993)

[Publications] 野中勉: "疎水性電極による有機電解" 化学工業. 45. 127-130 (1994)