1995 Fiscal Year Annual Research Report

有機電気化学の新展開

Research Project

Project/Area Number	05235101
Research Institution	Tohoku University
Principal Investigator	長哲郎東北大学, 薬学部, 教授 (10010753)
Co-Investigator(Kenkyū-buntansha)	松岡英明東京農工大学, 工学部, 教授 (10143653) 内本喜一朗京都大学, 工学部, 教授 (90025958) 鳥居滋岡山大学, 工学部, 教授 (70032927) 野中勉東京工業大学, 大学院・総合理工学研究科, 教授 (00016528)
Keywords	有機電気化学 / 電極界面 / 超活性反応種 / メディエーター反応 / 錯体電子移動反応
Research Abstract	本重点領域研究の最終年度の総括班の役割を果たし、評価グループ6名と実施グループ5名から構成された。計画班員29名、公募班員91名の組織からなり、反応場としての電極界面の新しい概念の確立と超反応活性種の創成による有機電気化学の格段の飛躍をめざして各研究班内はもちろん研究班相互の連携を緊密化し、研究計画全体の効率的進展を計った。 1.会議の開催京大会館において平成7年6月29日第5回全体会議(各班より2名発表)、6月30日第4回公開シンポジウム(各班より1名と外部から生越久靖氏の講演)と39名のポスター発表、班会議、総括班会議を開催した。また、12月2〜4日セミナープラザすずかけ台において第6回全体会議(各班より4名発表)、第5回公開シンポジウム(各班より1名と外部から徳田耕一氏の講演)と48名のポスター発表、班会議、総括班会議を実施した。 2.印刷物の発行ニュースレター4回、全体会議および公開シンポジウムの要旨集2回、全班員の研究概要、全班員名簿を印刷し、班員等に配付した。また平成7年度の研究成果報告書(全班員和文、英文各2ページ)を作成した。 3.研究班相互の研究協力と関連した討論会への共催班長会議を2回開き、班組織を越えた横断的研究の推進に努めた。たとえば、第18回エレクトロオ-ガニックケミストリー討論会、第2回日韓電気化学セミナーを共催し、電極界面、メディエーター反応、錯体電子移動反応の主題を設け、またその機会に参加者のロビ-討論を行い横断的研究の実を計った。研究目標は順調に達成でき、総括班は円滑に機能した。

Research Products
(19 results)

All Other

All Publications (19 results)

[Publications] Tomonori Hoshi: "Controlled Deposition of Glucose Oxidase on Platinum Electrode Based on an Avidin/Biotin for the Regulation ofOutput Current of Glucose Sensors" Analytical Chemistry. 67. 770-774 (1995)
[Publications] Tomonori Hoshi: "Use of Electrodeposited Avidin Film for the Preparation of Lactate and Choline Sensors" Analytical Sciences. 11. 311-312 (1995)
[Publications] Naotaka Sato: "Electroatalytic Activity of Poly(tetrafluoroaniline)Film-Coated Electrode for Fe^<3+/2+> Redox Response" Denki Kagaku. 63. 437-439 (1995)
[Publications] Po-Chang Chen: "InFluemces of Electroytic Conditions on Emulsion Electrolysis:n-Octanol Oxidation" Denki Kagaku. 63. 395-399 (1995)
[Publications] Mahito Atobe: "Ultrasonic Effects on Electroorganic Processes.Electroreduction of Bezaldehydes on Ultrasoundvibrating Electrodes" Chemistry Letters. 669-670 (1995)
[Publications] Naotake Sato: "Electopolymerization of o-Mercaptoniline Monolayer Self-assembled on an Au Electrode" Chemistry Letters. 805-806 (1995)
[Publications] Katsuhiko Tsunashima: "Product-Selectivity Control in an Electroorganic Process by Temperature.Electroreduction of Acetophenone" Chemistry Letters. 862-862 (1995)
[Publications] Hideko Tanaka: "Synthesis of 2-exo-Methylenepenam by Reductive 1,2-Elimination and S-S Bond Fission in a PbBr_2/Al Bimetal System" Chemistry Letters. 709-710 (1995)
[Publications] Tsutomu Inokuchi: "One-pot Conversion of Primary Alcohols to α-Oxygenated Alkanals with TEMPO in Combination with Moleculaar Oxygen and Ruthenium Complex" Tetrahedron Letters. 36. 3223-3226 (1995)
[Publications] Sigeru Torii: "A Novel Ru(VII)/Ru(IV)Mediarory System for Electrooxidation of Primary and Seondary Alcohols,Leading to Aldehydes and Ketones" Chemistry Letters. 369-370 (1995)
[Publications] Sigeru Torii: "Electrochemical Deamination of Aromatic Amines" Synlett. 439-440 (1995)
[Publications] Sigeru Torii: "Electrochemical Os-Catalyzed Asymmetric Dihydrixylation of Olefins with Sharpless Ligand" Chemistry Letters. 319-320 (1995)
[Publications] Kazuhiko Takai: "Selective Cyclotrimerization of Acetylenes via Tantalum-Alkyne Complexes" Chemistry Letters. 851-852 (1995)
[Publications] Kiitiro Utimoto: "Diastereoselective 1,4-Addition of Organocopper-Lanthanoid Reagents to α,β-Unsaturated Ketones Containing 1,3-Oxathiane as a Chiral Auxiliary" Synlett. 501-502 (1995)
[Publications] Seijiro Matsubara: "Alkylidenation of Ketones By gem-Dibromoalkane,SmI_2,and Sm in the Presence of Catalytic Amount of CrCl_3" Chemistry Letters. 259-260 (1995)
[Publications] Kiitiro Utimoto: "A Preparation of β-Oxoester Enolate Equivalents from SmI_2 and a-Bromoalkanoates" Chemistry Letters. 197-198 (1995)
[Publications] Hideaki Matsuoka: "Combined Effect of Amphoterricin B and Flucytosine on Hyphal Growth of Canadida Albicans Estimated at a Single Hypha Level" Journal of Medical and Veterinary Mycology. 33. 191-195 (1995)
[Publications] Hyeong-Cheol Yang: "Application of a Microscopic Fluoresdence Indicator to the Determination of Antimycotic Activity" Journal of Antibacterial Antifungal Agent. 23. 3-7 (1995)
[Publications] 戸田不二雄: "シクロデキストリン(5・4シクロデキストリンと電気化学)" 産業図書, 348 (1995)

1995 Fiscal Year Annual Research Report

有機電気化学の新展開

Principal Investigator

長 哲郎 東北大学, 薬学部, 教授 (10010753)

Research Products

[Publications] Tomonori Hoshi: "Controlled Deposition of Glucose Oxidase on Platinum Electrode Based on an Avidin/Biotin for the Regulation ofOutput Current of Glucose Sensors" Analytical Chemistry. 67. 770-774 (1995)

[Publications] Tomonori Hoshi: "Use of Electrodeposited Avidin Film for the Preparation of Lactate and Choline Sensors" Analytical Sciences. 11. 311-312 (1995)

[Publications] Naotaka Sato: "Electroatalytic Activity of Poly(tetrafluoroaniline)Film-Coated Electrode for Fe^<3+/2+> Redox Response" Denki Kagaku. 63. 437-439 (1995)

[Publications] Po-Chang Chen: "InFluemces of Electroytic Conditions on Emulsion Electrolysis:n-Octanol Oxidation" Denki Kagaku. 63. 395-399 (1995)

[Publications] Mahito Atobe: "Ultrasonic Effects on Electroorganic Processes.Electroreduction of Bezaldehydes on Ultrasoundvibrating Electrodes" Chemistry Letters. 669-670 (1995)

[Publications] Naotake Sato: "Electopolymerization of o-Mercaptoniline Monolayer Self-assembled on an Au Electrode" Chemistry Letters. 805-806 (1995)

[Publications] Katsuhiko Tsunashima: "Product-Selectivity Control in an Electroorganic Process by Temperature.Electroreduction of Acetophenone" Chemistry Letters. 862-862 (1995)

[Publications] Hideko Tanaka: "Synthesis of 2-exo-Methylenepenam by Reductive 1,2-Elimination and S-S Bond Fission in a PbBr_2/Al Bimetal System" Chemistry Letters. 709-710 (1995)

[Publications] Tsutomu Inokuchi: "One-pot Conversion of Primary Alcohols to α-Oxygenated Alkanals with TEMPO in Combination with Moleculaar Oxygen and Ruthenium Complex" Tetrahedron Letters. 36. 3223-3226 (1995)

[Publications] Sigeru Torii: "A Novel Ru(VII)/Ru(IV)Mediarory System for Electrooxidation of Primary and Seondary Alcohols,Leading to Aldehydes and Ketones" Chemistry Letters. 369-370 (1995)

[Publications] Sigeru Torii: "Electrochemical Deamination of Aromatic Amines" Synlett. 439-440 (1995)

[Publications] Sigeru Torii: "Electrochemical Os-Catalyzed Asymmetric Dihydrixylation of Olefins with Sharpless Ligand" Chemistry Letters. 319-320 (1995)

[Publications] Kazuhiko Takai: "Selective Cyclotrimerization of Acetylenes via Tantalum-Alkyne Complexes" Chemistry Letters. 851-852 (1995)

[Publications] Kiitiro Utimoto: "Diastereoselective 1,4-Addition of Organocopper-Lanthanoid Reagents to α,β-Unsaturated Ketones Containing 1,3-Oxathiane as a Chiral Auxiliary" Synlett. 501-502 (1995)

[Publications] Seijiro Matsubara: "Alkylidenation of Ketones By gem-Dibromoalkane,SmI_2,and Sm in the Presence of Catalytic Amount of CrCl_3" Chemistry Letters. 259-260 (1995)

[Publications] Kiitiro Utimoto: "A Preparation of β-Oxoester Enolate Equivalents from SmI_2 and a-Bromoalkanoates" Chemistry Letters. 197-198 (1995)

[Publications] Hideaki Matsuoka: "Combined Effect of Amphoterricin B and Flucytosine on Hyphal Growth of Canadida Albicans Estimated at a Single Hypha Level" Journal of Medical and Veterinary Mycology. 33. 191-195 (1995)

[Publications] Hyeong-Cheol Yang: "Application of a Microscopic Fluoresdence Indicator to the Determination of Antimycotic Activity" Journal of Antibacterial Antifungal Agent. 23. 3-7 (1995)

[Publications] 戸田不二雄: "シクロデキストリン(5・4シクロデキストリンと電気化学)" 産業図書, 348 (1995)

長哲郎東北大学, 薬学部, 教授 (10010753)