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1996 Fiscal Year Final Research Report Summary

New Development of Organic Electrochemistry

Research Project

Project/Area Number 05235101
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionTohoku University

Principal Investigator

OSA Tetsuo  Tohoku University, Emeritus Professor, 名誉教授 (10010753)

Co-Investigator(Kenkyū-buntansha) MASTUOKA Hideaki  Tokyo University of Agriculture and Technology, Faculty of Engineering, Professo, 工学部, 教授 (10143653)
UTIMOTO Kiitiro  Kyoto University, Faculty of Engineering, Professor, 工学部, 教授 (90025958)
TORII Sigeru  Okayama University, Faculty of Engineering, Professor, 工学郡, 教授 (70032927)
NONAKA Tsutomu  Tokyo Institute of Technology, Inter-disciplinary Graduate School of Science and, 大学院・総合理工学研究科, 教授 (00016528)
Project Period (FY) 1993 – 1995
KeywordsOrganic Electrochemistry / Electron-transfer Field / Electrogenerated Unusual Active Species / Mediator Reaction / Electron Transfer System in Coordination Compounds / Asymmetric Electrolysis / Enantioselective Electrolysis / Biochemistry
Research Abstract

Investigation of this group {X00} playd a function of managemet group for this rescarch project. The group consisted of 6 advisory and 5 executive members exerted an effective propulsion of the research project in close cooperation of four research groups (A01-A04) , getting advice by advisory members.
1.Research Subjects and Ressults The project was set up by four research subjects : 1) Design and Control of Electron-transfer Reaction Fields (A01), 2) Electrogenerated Unusual Active Species (A02), 3) Development of Mediator Reactions (A03), and 4) New Development of Electron Transfer in Coordination Compounds (A04). The project was pursued by 29 project members and 91 public-applicant members for 1995. In October, 1996, we evaluated a fruitful success in all the subjects which developed not only organic electrochemistry remarkably but also contributed to build many organic reaction systems being unable to perform by conventional organic chemistry methods. Furthermore, the results was c … More ontributed to build interdisciplinary areas with coordination chemistry and biochemistry. Its shoul be mentioned that asymmetric or enantioselective electrolysis was achieeved over our intial proposal which would become to a new tool in organic chemistry.
2.Opening of Whole Members' Meeting and Open Symposia Six whole members' meetings and 5 open symposia were connectively opened as well as many times of meetings for management group and each research subject groups. It is noticed that the group leaders arranged actively to maintain informal four cooperative research systems concerning reactive metal surface electrode, electrode reaction by physical method, biofunctionality throughelectron transfer and chiral synthesis.
3.Printing Meterials Research reports composed of each 2 pages in Japanese and English versions by all the members were published in the end of each years and a collective research report by 4 English pages of every member was done in December, 1996. Abstracts at the whole members' meetings and open symposia were not only distributed to the members and other participants every time, but 12 times of news letters relating the research were also distributed to the members. An English book "New Challenges in Organic Electrochemistry" which was applied a support to Monbusho is being prepared to publish in February, 1998. Less

  • Research Products

    (27 results)

All Other

All Publications (27 results)

  • [Publications] Tetsuo Osa: "Preparative,Electroenzymatic Reduction of NAD^+ to NADH on a Thin Poly(Acrylic Acid)Layer-Coaated Graphite Felt Electrode Coimmobilizing Ion-Paired Methylviologen-Cation Exchange Polymer and Diaphorase" Chemistry Letter. 1093-1094 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Tetsuo Osa: "Enantioselective,Electrocatalytic Oxidation of Racemic Alcohols on a TEMPO-modified Graphite Felt Electrode by Use of Chiral Base(TEMPO=2,2,6,6-tetramethylpiperidin-1-yloxyl)" Chemical Communications. 2745-2746 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Tetsiuo Osa: "Enantioselective,Electrocatalytic Lactonization of Methyl-substituted Diols on a TEMPO-modified Graphite Felt Electrode in the Presence of(-)-Sparteine" Chemistry Letter. 1043-1044 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Tsutomu Nonaka: "Product-Selectivity Control in an Electroorganic Process by Temperature.Electroreduction of Acetophenone" Chemistry Letter. 862-862 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Tsutomu Nonaka: "Ultrasonic Effects on Electroorganic Processes.Part4.Theeoretical and Experimental Studies on Product-selectivity in Electroreduction of Benzaldehyde and Benzoic Acid" Electroanalysis. (印刷中). (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Tsutomu Nonaka: "Ultrasonic Effects on Electroorganic Processes.Part5.Current Efficiency and Product Selectivity in Electroreduction of Alkyl Halides to Alkyl Stannanes at a Reactive Tin Cathode" Electrochimica Acta. (印刷中). (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Sigeru Torii: "Chemical and Electrochemical Asymmetric Dihydroxylation of Olefins in I_2-K_2CO_3-K_2OsO_2(OH)_4 and I_2-K_3PO_4/K_2HPO_3-K_2OsO_2(OH)_3 Systems with Sharpless' Ligand" Journal of Organic Chemistry. 61. 3055-3061 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Sigeru Torii: "Sythesis of 3-Chloro-Δ^3-cephem-4-carboxylate by Addition/Cyclization of Allen-carboxylate.Copper(II)-Promoted Aerobic Oxidation of Arensulfinic Acids" Bulletin of the Chemical Society of Japan. (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Sigeru Torii: "Electrogeneration of Triphenyltin Radical,Anion and Cation.Electrochemical Initiation of Tin Hydride-Promoted Radical Chain Reactions" Journal of Organic Chemistry. 61. 9402-9408 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Kiitiro Uchimoto: "Selective Cyclotrimerization of Acetylenes via Tantalum-Alkyne Complexes" Chemistry Letter. 851-852 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Kiitiro Uchimoto: "Samarium-Mediated Highly Stereoselective Reaction of 1,1-Dihaloalkanes with Aldehydes.Generation of Chiral a-Iodoethyl Building Block from Aciral 1,1-Diiodoethane" Angewandte Chemie,International Edition in English. (印刷中). (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hideaki Matsuoka: "Application of Multifuncitional Microelectrode to the in vivo Analysis of the K^+ Response to CO_2 Stress" Bioelectrochemistry and Bioenergetcs. 39. 115-118 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hideaki Matsuoka: "Microinjection of Fluorescence Dye in a Plant Cell and Its Intercellular Translocation with a Multi-channel Microelectrode System" Biochimica Biophysica Acta. 1289. 1-4 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Sigeru Torii: "Novel Trends in Electroorganic Synthesis" Kodansha Ltd., 374 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Tsetsuo Osa: "Enantioselective, Electrocatalytic Lactonization of Methyl-substitute Diols on a TEMPO modified Graphite Felt Electrode in the Presence of (-) -Sparteine" Chemistry Letters. 1996. 1043-1044

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Tetsuo Osa: "Preparative, Electroenzymatic Reduction of NAD^+ to NADH on a Thin Poly (Acrylic Acid) Layr-Coated Graphite Felt Electrode Coimmobilizing Ion-paired Methyl Viologen-Cation-Exchange Polymer and Diaphorase" Chemistry Letters. 1996. 1093-1094

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Tetsuo Osa: "Enantioselective, Electrocatalytic Oxidation of Racemic Alcohols on TEMPO modified Graphite Felt Electrode by Use of Chiral Base (TEMPO=2,2,6,6-trtramethylpiperidin-1-yloxyl)" Chemical Communications. 1996. 2745-2746

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Tsutomu Nonaka: "Product-Selectivity Control in an Electroorganic Process by Tempreture. Electroreduction of Acetophenone" Chemistry Letters. 1995. 862-862

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Tsutomu Nonaka: "Ultrasonic Effects on Electroorganic Processes. Part4. Theeoretical and Experimental Studies on Product-selectivity in Electroreduction of Benzaldehyde and Benzoic Acid" Electroanalysis. (in press). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Tssutomu Nonaka: "Ultrasonic Effects on Electroorganic Processes. Part5. Current Efficiency and Product Selectivity in Electroreduction of Alkyl Halides to Alkyl Stannanes at a Reactive Tin Cathode" Electrochimica Acta. (in press). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Sigeru Torii: "Chemical and Electrochemical Asymmetric Dihydroxylation of Olefins in I_2-K_2CO_3-K_2OsO_2(OH)_4 and I_2-K_3PO_4/K_2HPO_3-K_2OsO_2(OH)_3 Systems with Sharpless' Ligand" Journal of Organic Chemistry. 1994. 953-954

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Sigeru Torii: "Sythesis of 3-Chloro-DELTA^3-cephem-4-carboxylate by Addition/Cyclization of Allen-carboxylate. Copper (II)-Promoted Aerobic Oxidatio of Arensulfinic Acids" Bulletin of the Chemical Society of Japan. 69. 1391-1396 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Sigeru Torii: "Electrogeneration of Triphenyltin Radical, Anion and Cation. Electrochemical Initiation of Tin Hydride-Promoted Radical Chain Reactions" Journal of Organic Chemistry. 61. 9402-9408 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Kiitiro Utimoto: "Selective Cyclotrimerization of Acetylenes via Tantalum-Alkyne Complexes" Chemistry Letters. 1995. 851-852

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Kiitiro Utimoto: "Samarium-Mediated Highly Stereoselective Reaction of 1,1-Dihaloalkanes with Aldehydes. Generation of Chiral a-Iodoethyl Building Block from Aciral 1,1-Diiodoethane" Angewandte Chemie, International Edition in English. (in press). (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hideaki Matsuoka: "Application of Multifunctional Microelectrode to the in vivo Analysis of the K^+ Response to CO^2 Stress" Bioelectrochemistry and Bioenergetcs. 39. 115-118 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Hideaki Mastuoka: "Microinjection of Fluorescence Dye in a Plant Cell and Its Intercellular Translocation with a Multi-channel Microelectrode System" Biochemica Biophysica Acta. 1289. 1-4 (1996)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-03-09  

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