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1996 Fiscal Year Final Research Report Summary

Reactive Organometallics

Research Project

Project/Area Number 05236105
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Research InstitutionOsaka University

Principal Investigator

MURAHASHI Shun-ichi  Osaka University, Graduate School of Engineering Science, Professor, 基礎工学部, 教授 (60029436)

Co-Investigator(Kenkyū-buntansha) YAMAMOTO Yoshinori  Graduate School of Science, Tohoku University, Professor, 大学院・理学研究科, 教授 (60029519)
OKAZAKI Renji  Graduate School of Science, The University of Tokyo, Professor, 大学院・理学系研究科, 教授 (70011567)
MORO-OKA Yoshihiko  Tokyo Institute of Technology, Research Laboratory of Resources Utilization, Pro, 資源化学研究所, 教授 (70016731)
YAMAMOTO Akio  Waseda University, School of Science and Engineering, Professor, 理工学部, 教授 (30016711)
NAGAKURA Saburo  Kanagawa Academy of Science and Technology, President, 理事長 (30013444)
Project Period (FY) 1993 – 1996
KeywordsReactive Organometallics / Reactive Organometallics of Transition Metals / Reactive Organometallics of Non-transition Metals / Organometallics of Organic Active Intermediates / Catalysis of Reactive Organometallics / Molecular Recognition of Reactive Organometallics
Research Abstract

Aiming to acquire innovative method of chemical transformation for the future, the present research project designed and produced reactive organometallics that suit appropriate purposes, and placed emphasis on clarifying their function of catalysis and molecular recognition and examining their possibility of working as functional materials. The following research groups were set up depending on the research theme :
A) Reactive Organometallics of Transition Metals (S.-I.Murahashi)
B) Reactive Organometallics of Non-transition Metals (R.Okazaki)
C) Organometallics of organic Active Intermediates (Y.Yamamoto)
D) Catalysis of Reactive Organometallics (A.Yamamoto)
E) Molecular Recognition of Reactive Organometallics (Y.Moro-oka)
110 researchers in total engaged in this project and in consequence, fruitful results that are original enough to promoto the introduction of the leading technology were obtained in the field of organometallic chemistry, organic synthesis, catalysis, and functional materials.
The meetings of head of research group and evaluation group were held twice a year (seven in total) to promote and to generalize the project. Open symposiums were held 7 times to exchange lively and meaningful opinions between researchers, and about 200 people including researchers and those from private enterprises from outside took part in every symposium. The gist of the symposium was published each time and was distributed to all concerned. In addition, we issued public relations bulletins 8 times and also filed a report on our three-year research "Reactive organometallics-Synthesis and Function- " in English and distributed it to the Ministry of Education, Science, Culture and Sports, and researchers at large to make our results widely known at home as well as abroad.

  • Research Products

    (10 results)

All Other

All Publications (10 results)

  • [Publications] S.-I.Murahashi: "Ruthenium-Catalyzed Oxidation of Phenols with Alkyl Hydroperoxides.A Novel,Facile Route to 2-Substituted" J.Am.Chem.Soc.118. 2509-2510 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.Okazaki: "The First Rotational Isomers of Stable Selenoaldehydes and Their 1-Tungsten Complex" Angew.Chem.,Int.Ed.Engl.35. 660-662 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Yamamoto: "A New Palladium Catalyzed Benzannulation of Conjugated Enynes" J.Am.Chem.Soc.118. 3970-3971 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A.Yamamoto: "Activation of C-O and C-N Bonds in Allylic Alcohols and Amines by Palladium Complexes Promoted by CO_2" Bull.Chem.Soc.Jpn.69. 1065-1078 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Moro-oka: "Deoxygenative Reduction of Diruthenium Carbonyl Complexes(^5-C_5H_4R)_2Ru_2(-CH_2)_n(-CO)_<2-n>(CO)_2(n=1,2;R=H,Me)" Organometallics. 15. 2548-2553 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.-I.Murahashi, T.Naota, N.Miyaguchi, S.Noda: "Ruthenium-Catalyzed Oxidation of Phenols with Alkyl Hydroperoxides. A Novel Facile Route to 2-Substituted Quinones" J.Am.Chem.Soc.118. 2509-2510 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N.Takeda, N.Tokitoh, R.Okazaki: "The First Rotational Isomers of Stable Selenoaldehydes and Their 1-Tungsten Complex" Angew.Chem., Int.Ed.Engl.35. 660-662 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Saito, M.M.Salter, V.Gevorgyan, N.Tsuboya, K.Tando, Y.Yamamoto: "A New Palladium Catalyzed Benzannulation of Conjugated Enynes" J.Am.Chem.Soc.118. 3970-3971 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Sakamoto, I.Shimizu, A.Yamamoto: "Activation of C-O and C-N Bonds in Allylic Alcohols and Amines by Palladium Complexes Promoted by CO_2. Synthetic Application to Allylation of Nucleophiles, Carbonylation, and Allylamine Disproportionation" Bull.Chem.Soc.Jpn.69. 1065-1078 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Akita, R.Hua, T.Oku, Y.Moro-oka: "Deoxygenative Reduction of Diruthenium Carbonyl Complexes (eta^5-C_5H_4R)_2-Ru_2 (mu-CO) (CO)_2 with Hydrosilanes Leading to Bridging Methylene Complexes (eta^5-C_5H_4R)_2Ru_2 (mu-CH_2)_n (mu-CO)_<2-n> (CO)_2 (n=1,2 ; R=H,CH_3)" Organometallics. 15. 2548-2553 (1996)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-03-09  

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