• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

1994 Fiscal Year Final Research Report Summary

Systems for Collection, Management and Utilization of Solvent Extraction Data

Research Project

Project/Area Number 05554024
Research Category

Grant-in-Aid for Developmental Scientific Research (B)

Allocation TypeSingle-year Grants
Research Field 分離・精製・検出法
Research InstitutionTohoku University

Principal Investigator

AKIBA Kenichi  Tohoku Univ.Inst.Advanced Materials Processing Prof., 素材工学研究所, 教授 (00006040)

Co-Investigator(Kenkyū-buntansha) HASEGAWA Yuko  Sci.Univ.Tokyo, Faculty of Sci.Prof., 理学部, 教授 (20084303)
KATO Masanao  Toyohashi Univ.Technol.Associate Prof., 分析計測センター, 助教授 (90144211)
SUZUKI Nobuo  東北大学, 名誉教授
TSUKAHARA Satoshi  Tohoku Univ.Faculty of Sci.Res.Associate Emeritus Prof., 理学部, 助手 (50207338)
SAITOH Koichi  Tohoku Univ.Faculty of Sci.Associate Prof., 理学部, 助教授 (90004457)
Project Period (FY) 1993 – 1994
KeywordsSolvent Extraction / Database / Extractant / Chelate Extraction / Ion Pair Extraction / Extraction Constant / Extraction Equilibrium / Organic Solvent
Research Abstract

Extraction separation has been widely used in a tracer level to industrial scale under severe conditions such as high salt concentration. In addition to fundamental equilibrium constants, a great number of numerical data are significantly important for selection of extraction and separation conditions. The systems for collection of solvent extraction data and their utilization were developed. Solvent extraction database, SEDATA-II,consists of following data tables. (1) Extraction Data (EXTN) : extracting conditions, extraction reaction, equilibrium constants and relevant information ; (2) Name of Compound Data (NACOM) : name of reagents, solvents ; (3) Reference Data (LISED) : information about the data sources. The data tables, EXTN,NACOM and LISED can be mutually used for retrieval of related subjects. SEDATA-II is available for the evaluation of extraction processes as follows : (1) the extraction percentage (%E) or distribution ratio (D) is retrieved for the extraction of desired elements with a given extractant ; (2) the variation of %E or D is depicted against variables such as pH ; (3) extraction behavior of different elements can be graphically illustrated for comparison ; (4) the equilibrium constants for related reactions are retrieved ; (5) optimum conditions are selected for extraction and separation of metals ; (6) all information on the data sheet can be displayd ; (7) reference of certain data is readily surveyed. A database for the extraction of actinoids with amide extractants was newly constructed by Japan Atomic Research Institute on the basis of the common data tables. These database systems were presented in Symposium on Solvent Extraction 1994 and demonstrated with a personal computer.

  • Research Products

    (36 results)

All Other

All Publications (36 results)

  • [Publications] S.Nakamura: "Application of Europium (III) Extraction with Organophosphinic Acid to Liquid Membrane Transport" J.Radioanal.Nucl.Chem.178. 63-71 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Akiba: "Extraction Separation of Yttrium from Ferric Iron with Di (2-ethylhexyl)-Phosphoric acid" Solvent Extr.Res.Develop.,Jpn.1. 137-145 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Fu: "Extraction of Platinum (IV) with Trioctylamine and Its Application to Liquid Membrane Transport" Sep.Sci.Technol.30. 609-619 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Nakamura: "Separation of Yttrium from Lanthanoid Elements by Centrifugal Partition Chromatography" J.Liq.Chromatogr.

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Tsukahara: "Liquid-Liquid Partition Coefficients of Tris (β-diketonato) chromium (III) and Bis (β-diketonato) palladium (II) in the Dodecane/(Acetonitrile-Water) System." Anal.Sci.9. 65-70 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Suzuki: "Synergic Extraction of Lanthanoids (III) with Thenoyltrifluoroacetone and Terpyridine." J.Radioanal.Nucl.Chem.172. 239-248 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Matsunaga: "Extraction Characteristics of Metal Ions with Reagent Impregnated Polymer Resins" Solvent Extraction in the Process Industries (ISEC'93). 1. 615-620 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Tachimori: "Simulation Study on Behavior of Technetium and Its Controlled Strip at the Codecontamination Process of the Fuel Reprocessing" J.Nucl.Sci.Technol.31. 456-462 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Rais: "Extraction Separation of Tervalent Am and Lanthanides in the Presence of Some Soft and Hard Donors and Dicarbollide" Sep.Sci.Technol.29. 1347-1365 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] J.Rais: "Extraction of Europium and Americium by a Mixture of CMPO and Dicarbollide" J.Radioanal.Nucl.Chem.Lett.188. 157-162 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Hasegawa: "Separation Factors in the Extraction of Thiocyanatolanthanoids (III) with Trioctylphosphine Oxide in Hexane and in Chloroform" Anal.Sci.10. 167-170 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Hasegawa: "Trend of Stabilities of Adducts of 4,4,4-Trifluoro-1-(2-thienyl)-1,3-butanedionates with Phenylpyridines over Lanthanoid Series" Anal.Sci.11. 59-62 (1995)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Satake: "Synergic Extraction of Rare Earths (III) with 2-Thenoyltrifluoroacetone and Phosphoryl-Type Bidentate Ligand as Tetraphenyldiphosphine Dioxide or Bis (diphenylphosphinyl) methane." Anal.Chim.Acta. 282. 215-220 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Katsuta: "Solvent Extraction of 8-Quinolinolato-iron (III) with the Aid of Various Phenols as Hydrogen-bonding Donors." Talanta. 40. 231-235 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Saitoh: "Separatiion of chlorophyll-cl and- c2 by micellar electrokinetic capillary chromatography" J.Chromatogr.A. 687. 149-153 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Tsukahara: "Synergic Extraction Equilibrium and Substoichiometric Extraction of Iron (II) with 2-Thenoyltrifluoroacetone and Trioctylphosphine Oxide" Radiochim.Acta. 65. 245-248 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Satake: "Synergic Extraction of Lanthanoids (III) with 2-Thenoyltrifluoroacetone and Nitrogen-Containing Polydentate Ligands" CYRIC Annual Report. 81-86 (1993)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Kato: "Adsorption Equilibria of Copper (II) Ion on Octadecyl-bonded Silica Gels in the Presence of β-Diketones" Bull.Chem.Soc.Jpn.67. 3231-3235 (1994)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Nakamura: "Application of Europium (III) Extraction with Organophosphinic Acid to Liquid Membrane Transport" J.Radioanal.Nucl.Chem.178. 63-71 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Akiba: "Extraction Separation of Yttrium from Ferric Iron with Di (2-ethylhexyl) phosphoric acid" Solvent Extr.Res.Develop., Jpn.1. 137-145 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Fu: "Extraction of Platinum (IV) with Trioctylamine and Its Application to Liquid Membrane Transport" Sep.Sci.Technol.30. 609-619 (1995)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Nakamura: "Separation of Yttrium from Lanthanoid Elements by Centrifugal Partition Chromatography" J.Liq.Chromatogr.(in press).

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Tsukahara: "Liquid-Liquid Partition Coefficients of Tris (beta-diketonato) -chromium (III) and Bis (beta-diketonato) palladium (II) in the Dodecane (Acetonitrile-Water) System" Anal.Sci.9. 65-70 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N.Suzuki: "Synergic Extraction of Lanthanoids (III) with Thenoyltrifluoroacetone and Terpyridine" J.Radioanal.Nucl.Chem.172. 239-248 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Satake: "Synergic Extraction of Rate Earths (III) with 2-Thenoyl-trifluoroacetone and Phosphoryl-Type Bidentate Ligand as Tetraphenyldiphosphine Dioxide or Bis (diphenylphosphinyl) methane" Anal.Chem.Acta. 282. 215-220 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Katsuta: "Solvent Extraction of 8-Quinolinolato-iron (III) with the Aid of Various Phenols as Hydrogen-bonding Donors" Talanta. 40. 231-235 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K.Saito: "Separatiion of chlorophyll-c1 and -c2 by micellar electrokinetic capillary chromatography" J.Chromatogr.A. 687. 149-153 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Tsukahara: "Synergic Extraction Equilibrium and Substoichiometric Extraction of Iron (II) with 2-Thenoyl-trifluoroacetone and Trioctylphosphine Oxide" Radiochem.Acta. 65. 245-248 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Satake: "Synergic Extraction Lanthanoids (III) with 2-Thenoyltrifluoroacetone and Nitrogen-Containing Polydentate Ligands" CYRIC Annual Report. 81-86 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M.Kato: "Adsorption Equilibria of Copper (II) Ion on Octadecyl-bonded Silica Gels in the Presence of b-Diketones" Bull.Chem.Soc.Jpn.67. 3231-3235 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H.Matsunaga: "Extraction Characteristics of Metal Ions with Reagent Impregnated Polymer Resins" Solvent Extraction in the Process Industries (ISEC'93). 1. 615-620 (1993)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S.Tachimori: "Simulation Study on Behavior of Technetium and Its Controlled Strip at the Codecontamination Process of the Fuel Reprocessing" J.Nucl.Sci.Technol.31. 456-462 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Rais: "Extraction Separation of Tervalent Am and Lanthanides in the Presence of Some Soft and Hard Donors and Dicarbollide" Sep.Sci.Technol.29. 1347-1365 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] J.Rais: "Extraction of Europium and Americium by a Mixture of CMPO and Dicarbollide" J.Radioanal.Nucl.Chem.Lett.188. 157-162 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Hasegawa: "Separation Factors in the Extraction of Thiocyanatolanthanoids (III) with Trioctylphosphine Oxide in Hexane and Chloroform" Anal.Sci.10. 167-170 (1994)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y.Hasegawa: "Trend of Stabilities of Adducts of 4,4,4-Trifluoro-1- (2-thienyl) -1,3-butanedionates with Phenylpyridines over Lanthanoid Series" Anal.Sci.11. 59-62 (1995)

    • Description
      「研究成果報告書概要(欧文)」より

URL: 

Published: 1999-03-09  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi