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1996 Fiscal Year Final Research Report Summary

Dynamics of solid-molecules and the structure-function relationship

Research Project

Project/Area Number 07304074
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section総合
Research Field Physical chemistry
Research InstitutionTokyo Institute of Technology

Principal Investigator

OHASHI Yuji  Tokyo Institute of Technology Chemistry Professor, 理学部, 教授 (40016118)

Co-Investigator(Kenkyū-buntansha) IWASAKI Fujiko  Electro-Commun.Professor, 電気通信学部, 教授 (10017329)
INABE Tamotsu  Hokkaido Univ.Chemistry Professor, 大学院・理学研究科, 教授 (20168412)
ISHII Kikujirou  Gakushuuin Univ.Chemistry Professor, 理学部, 教授 (30013543)
IKEDA Susumu  KEK Professor, 教授 (80132679)
ATAKE Tohru  Tokyo Inst.Tech.Inst.Ceramics Professor, 応用セラミックス研究所, 教授 (30028229)
Project Period (FY) 1995 – 1996
KeywordsMolecular motion in solid / Dynamics / Phase transition / Proton transfer / Amorphous phase / Liquid crystal / X-ray analysis / Analysis of heat capacity
Research Abstract

The following six research projects have been studied, keeping in contact with each other. (1) Proton transfer in solid. The relation between the p-electron system and the proton transfer in charge transfer complexes. The proton transfer in KH2P04 and ice theoretically and compared the calculation with the experiment of neutron diffraction. The proton transfer in cobaloxime complexes by single crystal neutron diffraction when they were irradiated with the xenon lamp. The mechanism of ferroelectricity. (2) Phase transition. The analysis of the heat capacity of the fullerren compounds. The heat capacity of p-polyphenyl mixed crystals. The structural change of organic radicals. Phase transition of one dimensional halogen-bridged metal complexes. Phase transition of water. (3) Molecular dynamics and reactivity. Complex formation between surfactants and aromatic compounds in a mortar and their structures. Radiation polymerization of DSP.(4) Anharmonic thermal vibration and hindered rotation. Relationship between molecular orbital and anharmonic vibration observed by X-ray analysis. Theoretical aspect of the hindered rotation of organic molecules. (5) Structure and function of liquid crystal and membrane. Analysis of molecular motion in liquid crystals by NMR.(6) Structure and molecular motion in amorphous materials. Analysis of structure of amorphous benzene an its relaxation by spectroscopy.

  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] Hiroki Amano et al.: "β-α Photoisomerization of Cobaloxiue Complexes in the Solid Stcte.5 Reactim Rate Reduced by a Hydnega Bncd." Bull.Chem.Soc.Jpn.69. 3107-3114 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Yoshiki Ohgo et al.: "Crysfalline-State Reaction of Cobaloxine Coyslizes,19. A New Mode of Raceainzation of the 1 Cyauethil Group." Bull.Chem.Soc.Jpn.69. 2425-2443 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Keiji Sawada et al.: "Four Polywinphs of a Cobaloxiue Complix with Different Solid-Sfete Photoisomerization rates" Acfx Cryst allogrpbhica. B52. 303-313 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Kazuya Saito et al.: "Phonou and the Infranitluilaymction in Crysfalliue Tramscstilbeue" Physica. B219-220. 417-419 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Iwasaki et al.: "Crysfal and Molecular Sfnicfariss of Novel Metal Carbeue Complies II. Inteuslty Meagoirement using Rapid-X-cay Diffracfoaetess" Bull.Chem.Soc.Jpn.69. 2749-2757 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Inabe et al.: "Dimansimality Control of Phthalofancine Based Conductors" Mol.Cryst.Liq.Cryst.285. 107-112 (1996)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Hiroki Amano et al.: "b-a Photoisomerization of Cobaloxime Comolexes in the Solid State.5. Reaction Rate Deduced by a Hydrogen Bond" Bull.Chem.Soc.Jpn.69. 3107-3114 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Yoshiki Ohgo et al.: "Crystalline State Reaction of Cobaloxime Complexes. 19.A New Mode of Racemization of the 1-Cyanoethyl Group" Bull.Chem.Soc.Jpn.69. 2425-2443 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Keiju Sawada et al.: "Four Polymorphs of a Cobaloxime Complex with different Solid-state Photoisomerization Rates" Acta Crystallogr.B52. 303-313 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Kazuya Saito et al.: "Phonon and the Intramolecular Motion in Crystalline trans-Stilbene" Physica. B219-220. 417-419 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Fujiko Iwasaki et al.: "Crystal and molecular Structures of Novel Metal Carbene Complexes.II." Bull.Chem.Soc.Jpn. 69. 2749-2759 (1996)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Tamotsu Inabe et al: "Dimensionality Control of Phthalocyanine Based Conductors" Mol.Cryst.Liq.Cryst.285. 107-112 (1996)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 1999-03-09  

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