1996 Fiscal Year Annual Research Report

微細組織・界面機能の制御設計に関する総合的研究

Research Project

Project/Area Number	07305034
Research Institution	KYOTO UNIVERSITY
Principal Investigator	原田誠京都大学, エネルギー理工学研究所, 教授 (90027128)
Co-Investigator(Kenkyū-buntansha)	東谷公京都大学, 工学研究科, 教授 (10039133) 岡崎守男京都大学, 工学研究科, 教授 (90025916) 三宅義和関西大学, 工学部, 教授 (70111995) 上岡龍一熊本工業大学, 工学部, 教授 (70099076) 中塩文行九州大学, 工学部, 教授 (70037729)
Keywords	微細構造形成 / 分子集合体 / 微粒子 / 高分子 / 複合材料 / 自己組織化 / 界面機能 / 材料プロセス
Research Abstract	研究の最終年度として、各分担者(18名)が行っている微細構造形成過程とその機能の研究を深化させると共に、この多様な研究の共通事項を抽出して、微細構造制御設計と機能の共通基盤になる方法論について考察を加えた。 1.各個分担者の研究:(1)界面活性剤から形成される分子集合体と機能;界面活性剤・酵素複合体調整の一般的方法論、分子集合体のナノ材料創製のための鋳型機能、人工細胞膜の各種反応機能とモデル解析手法、分子集合体を用いた超微粒子の調整法とその濃縮法などを解明した。(2)高分子等における秩序形成過程と機能;高分子共重合体の分相・反応誘起型構造形成過程、高分子の微粒子形成過程、非平衡反応における高分子ゲル過程と構造制御、高分子膜の微細構造と機能との関係などを明らかにした。(3)複合材料構造形成過程と機能:超伝導材料におけるクラスター生成過程と臨界挙動との関連、原子間力顕微鏡(AFM)による鍍金過程の結晶成長機構、タンパク質・糖類複合体における糖類アモルファス化過程などを解明した。(4)微粒子系秩序化;微粒子系構造形成の基礎となる粒子間相互作用の起源と実験的決定、流れ場における粒子クラスターの分散機構、電場誘起粒子構造形成、マイクロカプセル構造制御と機能化等に関して多くの知見をえた。 2.共通基盤事項の抽出:自己組織化による構造形成の現象論、構造形成におけるナノ領域の分子挙動、構造形成過程と機能評価における計算機手法の有用性など、横断的方法論について検討した。また、これに関連して、シンポジウム「拘束場をもつ物質系の構成と機能」を開催した。さらに、本研究の将来展開として、重点領域研究申請の可能性を探った。

Research Products
(27 results)

All Other

All Publications (27 results)

[Publications] A.Shioi: "X-ray and Light Scattering from Oil-Rich Microemulsions Containing Sodium Bis(2-ethylhexyl)Phosphate" Langmuir. 12・13. 3201-3205 (1996)
[Publications] K.Kurumada: "Dynamical Behavior and Structure of Concentrated Water-in-Oil Miaoenulsions in the Sodium Bis(2ethylhexyl)Sulfosuccimate syste" J.Phys.Chem.100・3. 1020-1026 (1996)
[Publications] M.Goto: "Enzymatic Resolution of Racemic Ibuprofen by Surfactant-Coated Lipases in Organic Media" Biotechnol.Letters. 18・7. 839-844 (1996)
[Publications] T.Ono: "Extraction Behavior of Hemoglobin Using Reversed Micelles by Dioleyl Phosphoric acid" Biotechnol.Prog.12・6. 793-800 (1996)
[Publications] M.Kinoshita: "Interaction between macroparticles in a simple model system of a nonpdar liquid containing trace a mount of water" J.Chem.Phys.105・16. 7184-7191 (1996)
[Publications] M.Kinoshita: "Interaction between macroparticles in aqueous electrolytes" J.Chem.Phys.105・6. 2487-2499 (1996)
[Publications] H.Sato: "Mechanism of Foruration of Metal Sulfide Ultrafine Particles in Reverse Micelles Usiug a Gas Injection Metho" Ind.Eng.Chem.Res.36・1. 92-100 (1997)
[Publications] H.Tobita: "Kinetics of Free-Radical Polymerization with Chain-Length-Dependent Bimolecular Termination Under Unstatio Conditions" Macro molecules. 29・9. 3073-3080 (1996)
[Publications] H.Tobita: "Random Degradation of Branched Polymers.2.Multiple Branches" Macromolecules. 29・8. 3010-3021 (1996)
[Publications] K.Kondo: "AFM Study on Morphology Evaluation of Zinc Electrodeposits" ISIJ International. 37・2. 140-145 (1997)
[Publications] F.Cerwinski: "Atomic Force Microscopy Study of Surface Morphology of Zinc-Iron Electrodeposits" J.Electrochem.Soc.144・2. 481-484 (1997)
[Publications] K.Mishima: "Prediction of Polyethylene Glycol Microcapsules of Flaronoids Using the Rapid Expansion of Super Critical CO_2" 2nd-International Conf.on Solvothermal Reactions. 69-70 (1996)
[Publications] K.Higashitani: "Evaluation of Interaction Forces between Surfaces in Electrolyte Solutions by Atomic Force Microscope" J.Chem.Eng.Japan. 30・1. 52-58 (1997)
[Publications] K.Yoshida: "The Electric Properties of Sintered Cermet as a Continuum Percolation Medium" Fractals. 4. 175-180 (1996)
[Publications] K.Yoshida: "Effects of Quenching on the Grain Boundary in Sintereal Ag-BPSCCO" Physica Status Solidi. (a)153. K5-K7 (1996)
[Publications] K.Okamoto: "Selective Permeation of Carbon Dioxide through Aminer Modified Polyimide Membrance" Chem.Lett.613-614 (1996)
[Publications] K.Tanaka: "Permeation and Seperation Properties of Polyimide Membranes to Olefins and Paraffins" J.Membrane Sci.121. 197-207 (1996)
[Publications] H.Sato: "Mechanism of Formation of Silver Halides Ultrafine Particles in Reversed Micellar Systems" J.Chem.Eng.Japan. 29・3. 501-507 (1996)
[Publications] K.Kato: "Water Permealility through the Lipid Membrane of a Giant Vesicle Prepared by a Two-Step Emulsification Technique" Solv.Extra.Res.Dev.,Japan. 3. 62-73 (1996)
[Publications] K.Kato: "Preparation of a hybrid-type Nesicle Moclified by concanavalin A for a drug delivery system" Chem.Eng.Symposium. 57. 71-75 (1997)
[Publications] 森康雄: "粒子分散系電気粘性流体における構造形成" 化学工学シンポジウムシリーズ. 54. 161-168 (1995)
[Publications] K.Mishima: "Effect of Vinyl Alcohol+Sodium Acrylate Copolymer Gel on the Vapor-Liquid Equilibrium of 1・Propanol+Water" J.Chem.Enh.Data. 41・5. 953-955 (1996)
[Publications] K.Abe: "Peptide Synthesis by Surfactant-Chymotrpsin Complexes in Organic Media" Biotechnol.Techniques. 11・1. 25-29 (1997)
[Publications] H.Kita: "Carbon Molecular Sieve Membrane Prepared from Phenolic Resin" Chem.Lett.179-180 (1997)
[Publications] A.W.Marczewski: "Modeling and analysis of experimental atomic force microscope images of hard colloidal particle" Computers Chem.(印刷中). (1997)
[Publications] T.Ono: "Effect of Organic Solvent Behavior of Cytochrom C Using Reversed Micellar Solutions" Solv.Extr.Res.Dev.Japan. 3. 1-9 (1996)
[Publications] 東谷公: "化学工学の進歩30微粒子制御(化学工学会編)槙書店" 微粒子の表面ミクロ構造のin-situ 評価法と安定性, 13 (1996)

1996 Fiscal Year Annual Research Report

微細組織・界面機能の制御設計に関する総合的研究

Principal Investigator

原田 誠 京都大学, エネルギー理工学研究所, 教授 (90027128)

Research Products

[Publications] A.Shioi: "X-ray and Light Scattering from Oil-Rich Microemulsions Containing Sodium Bis(2-ethylhexyl)Phosphate" Langmuir. 12・13. 3201-3205 (1996)

[Publications] K.Kurumada: "Dynamical Behavior and Structure of Concentrated Water-in-Oil Miaoenulsions in the Sodium Bis(2ethylhexyl)Sulfosuccimate syste" J.Phys.Chem.100・3. 1020-1026 (1996)

[Publications] M.Goto: "Enzymatic Resolution of Racemic Ibuprofen by Surfactant-Coated Lipases in Organic Media" Biotechnol.Letters. 18・7. 839-844 (1996)

[Publications] T.Ono: "Extraction Behavior of Hemoglobin Using Reversed Micelles by Dioleyl Phosphoric acid" Biotechnol.Prog.12・6. 793-800 (1996)

[Publications] M.Kinoshita: "Interaction between macroparticles in a simple model system of a nonpdar liquid containing trace a mount of water" J.Chem.Phys.105・16. 7184-7191 (1996)

[Publications] M.Kinoshita: "Interaction between macroparticles in aqueous electrolytes" J.Chem.Phys.105・6. 2487-2499 (1996)

[Publications] H.Sato: "Mechanism of Foruration of Metal Sulfide Ultrafine Particles in Reverse Micelles Usiug a Gas Injection Metho" Ind.Eng.Chem.Res.36・1. 92-100 (1997)

[Publications] H.Tobita: "Kinetics of Free-Radical Polymerization with Chain-Length-Dependent Bimolecular Termination Under Unstatio Conditions" Macro molecules. 29・9. 3073-3080 (1996)

[Publications] H.Tobita: "Random Degradation of Branched Polymers.2.Multiple Branches" Macromolecules. 29・8. 3010-3021 (1996)

[Publications] K.Kondo: "AFM Study on Morphology Evaluation of Zinc Electrodeposits" ISIJ International. 37・2. 140-145 (1997)

[Publications] F.Cerwinski: "Atomic Force Microscopy Study of Surface Morphology of Zinc-Iron Electrodeposits" J.Electrochem.Soc.144・2. 481-484 (1997)

[Publications] K.Mishima: "Prediction of Polyethylene Glycol Microcapsules of Flaronoids Using the Rapid Expansion of Super Critical CO_2" 2nd-International Conf.on Solvothermal Reactions. 69-70 (1996)

[Publications] K.Higashitani: "Evaluation of Interaction Forces between Surfaces in Electrolyte Solutions by Atomic Force Microscope" J.Chem.Eng.Japan. 30・1. 52-58 (1997)

[Publications] K.Yoshida: "The Electric Properties of Sintered Cermet as a Continuum Percolation Medium" Fractals. 4. 175-180 (1996)

[Publications] K.Yoshida: "Effects of Quenching on the Grain Boundary in Sintereal Ag-BPSCCO" Physica Status Solidi. (a)153. K5-K7 (1996)

[Publications] K.Okamoto: "Selective Permeation of Carbon Dioxide through Aminer Modified Polyimide Membrance" Chem.Lett.613-614 (1996)

[Publications] K.Tanaka: "Permeation and Seperation Properties of Polyimide Membranes to Olefins and Paraffins" J.Membrane Sci.121. 197-207 (1996)

[Publications] H.Sato: "Mechanism of Formation of Silver Halides Ultrafine Particles in Reversed Micellar Systems" J.Chem.Eng.Japan. 29・3. 501-507 (1996)

[Publications] K.Kato: "Water Permealility through the Lipid Membrane of a Giant Vesicle Prepared by a Two-Step Emulsification Technique" Solv.Extra.Res.Dev.,Japan. 3. 62-73 (1996)

[Publications] K.Kato: "Preparation of a hybrid-type Nesicle Moclified by concanavalin A for a drug delivery system" Chem.Eng.Symposium. 57. 71-75 (1997)

[Publications] 森 康雄: "粒子分散系電気粘性流体における構造形成" 化学工学シンポジウムシリーズ. 54. 161-168 (1995)

[Publications] K.Mishima: "Effect of Vinyl Alcohol+Sodium Acrylate Copolymer Gel on the Vapor-Liquid Equilibrium of 1・Propanol+Water" J.Chem.Enh.Data. 41・5. 953-955 (1996)

[Publications] K.Abe: "Peptide Synthesis by Surfactant-Chymotrpsin Complexes in Organic Media" Biotechnol.Techniques. 11・1. 25-29 (1997)

[Publications] H.Kita: "Carbon Molecular Sieve Membrane Prepared from Phenolic Resin" Chem.Lett.179-180 (1997)

[Publications] A.W.Marczewski: "Modeling and analysis of experimental atomic force microscope images of hard colloidal particle" Computers Chem.(印刷中). (1997)

[Publications] T.Ono: "Effect of Organic Solvent Behavior of Cytochrom C Using Reversed Micellar Solutions" Solv.Extr.Res.Dev.Japan. 3. 1-9 (1996)

[Publications] 東谷 公: "化学工学の進歩30微粒子制御(化学工学会編)槙書店" 微粒子の表面ミクロ構造のin-situ 評価法と安定性, 13 (1996)

原田誠京都大学, エネルギー理工学研究所, 教授 (90027128)

[Publications] 森康雄: "粒子分散系電気粘性流体における構造形成" 化学工学シンポジウムシリーズ. 54. 161-168 (1995)

[Publications] 東谷公: "化学工学の進歩30微粒子制御(化学工学会編)槙書店" 微粒子の表面ミクロ構造のin-situ 評価法と安定性, 13 (1996)