1996 Fiscal Year Final Research Report Summary
REACTION FIELD CREATED BY METAL COMPLEXES
| Project/Area Number |
07305039
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 総合 |
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| Research Field |
Synthetic chemistry
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| Research Institution | TOKYO INSTITUTE OF TECHNOLOGY |
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Principal Investigator |
SUZUKI Hiroharu Tokyo Institute of Technology, Professor, 工学部, 教授 (30106629)
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| Co-Investigator(Kenkyū-buntansha) |
KOMIYA Sanshiro Tokyo University of Agriculture and Technology, Professor, 工学部, 教授 (00111667)
TATSUMI Kazuyuki Nagoya University, Professor, 理学部, 教授 (10155096)
SAKAKI Shigeyoshi Kumamoto University, Professor, 工学部, 教授 (20094013)
ISOBE Kiyoshi Osaka City University, Professor, 理学部, 教授 (70101285)
ITO Takashi Yokohama National University, Professor, 工学部, 教授 (50016721)
KOGA Nobuaki Nagoya University, Associate Professor (80186650)
WAKATSUKI Yosuo The Institute of Physial and Chemical Research, Research Manager (20087513)
TAKAHASHI Tamotsu Hokkaido University, Professor (30163273)
OSAKADA Kohtaro Tokyo Institute of Technology, Associate Professor (00152455)
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| Project Period (FY) |
1995 – 1996
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| Keywords | Reaction Field / Polyhydride Complex / Dinuclear Complex / Trinuclear Complex / Metal Cluster / Coordinative Unsaturation |
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| Research Abstract |
This research project was intended to establish the methodology for the construction and modification of the reaction field of metal complex. The reaction field created on the metal complex can be modified by appropriately changing ligands. Ten researchers working in a variety of fields have been divided into the following four groups.
1. Creation of Highly Functioned Mononuclear Active Species
Takashi ito, Kohtaro Osakada, and Sanshiro Komiya
2. Construction of Sterically and Electronically Controlled Multimetallic Reaction Field
Hiroharu Suzuki, Kiyashi Isobe, and Kazuyuki Tatsumi
3. Conversion of Organic Substrates in the Highly Controlled Metal Complex Reaction Field
Tamotu Takahashi and Yasuo Wakatsuki
4.Theoretical Approach directed toward Control of Reaction Field
Nobuaki Koga and Shigeyoshi Sakaki
The first group achieved activation of CO_2, Si-C bond, and N-H bond by using coordinatively unsaturated transition metal complexes. The second group developed systematic synthetic method of metal cluster complexes. Di- and trinuclear polyhydride complexes of ruthenium could activate a variety of organic substrates including alkanes and unprecedented type of selective C-H and C-C bonds cleavage was performed. A new class of clusters with Rh-S-W framework were systematically synthesized. A novel organic transformation involving zirconacyclopentene as synthetic intermediate and redox reaction of NO on hexanuclear carbonyl clusters were performed by the third group. Ab initio MO studies of several transition metal complex-catalyzed reactions such as olefin polymerization and hydrosilation were done by the fourth group.
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[Publications] Makoto Minato, Hiroyuki Sakai, Zu-Gan Weng, Da-Yang Zhou, Susumu Kurishima, Takashi Ito, Mikio Yamasaki, Motoo Shiro, Masako Tanaka and Kohtaro Osakada: "Syntheses, Ctructures, and Reactions of eta^2-N-Acylamido-N,O Hydrido Complexes of Molybdenum (II) and Tungsten" Organometallics. 15(22). 4863-4871 (1996)
Description
「研究成果報告書概要(欧文)」より
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