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1997 Fiscal Year Final Research Report Summary

Syntheses and Functionarities of Metallomesogens

Research Project

Project/Area Number 08304039
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 機能・物性・材料
Research InstitutionTohoku University

Principal Investigator

KOBAYASHI Nagao  Tohoku Univ.Graduate School of Science, Professor, 大学院・理学研究科, 教授 (60124575)

Co-Investigator(Kenkyū-buntansha) OHTA Kazuchika  Shinshu Univ.Faculty of Textile Sci.& Tech., Assoc.Professor, 繊維学部, 助教授 (70160497)
WAKITA Hisanobu  Fukuoka Univ.Faculty of Scinence, Professor, 理学部, 教授 (50078581)
SHIRAISHI Shinsaku  Tokyo Univ.Inst.of Industrial Science, Professor, 生産技術研究所, 教授 (30013163)
NAKAMURA Naotake  Ritsumeikan Univ.Faculty of Sci.& Eng., Professor, 理工学部, 教授 (10066722)
MORI Akira  Kyushu Univ.Inst.of Adv.Material Study, Professor, 機能物質科学研究所, 教授 (70038602)
Project Period (FY) 1996 – 1997
KeywordsMetal Complex / liquid crystal / metallomesogen / synthesis / function
Research Abstract

It is well known that liquid crystals have been very actively investigated only as imaging materials. Since the application for liquid crystal display (LCD) is too outstandingly useful, the other possibilities based on the liquid crystalline state itself may be neglected.
In this research group, we have stood on the viewpoint which is totally different from the conventional thinking method as "liquid crystals=application to LCD." Hence, we have studied not on the conventional liquid crystals for LCD but on novel liquid cryatals unknown so far.
At this present time, most of the liguid crystals known are pure organic compounds. Nevertheless, we have synthesized different types of liquid crystals (LCs) : discotic LCs which molecular shapes are disk-like, metallomesogens which contain metals, hydrogenbonding LCs, ionic LCs, and so on. Although these investigations may be regarded as heretical from the conventional LC research works, very sueful novel functionalities like as high-conductivity, magnetism, and so on have been found in these materials.
Researchers of metallomesogens in Japan tend to represent their works in their own inherent conferences and/or sessions because of novelty of this field. We had no opportunity to discuss with all together at the same place. Hence, we proposed to make this research group named as "Syntheses and Functionalities of Metallomesogens" for two years from 1997 to 1998. In this research group, we could meet all together and discuss about the new fields of LCs at the first time. As the results, we have reached to our common consensus that great development of novel functional LC materials can be expected on three new expansive fields : (i) metallomesogens (including both thermotropic and lyotropic LCs), (ii) discotic LCs and high-conductive LCs, and (iii) hydrogenbonding LCs and ionic LCs. We strongly believe that these three fields can become future-promising mesophase chemistry.

  • Research Products

    (31 results)

All Other

All Publications (31 results)

  • [Publications] N.Kobayashi et al.: "A New Phthalocyanine Analog Containing One 1,8-Naphthalene Unit" Inorganic Chemistry. 36. 5674-5675 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Ohta et al.: "Gels of Bis[1,2-bis(3,4-di-n-alkoxyphenyl)ethanedione dioxmato]palladium(II)" Bulletin of the Chemical Society of Japan. 70. 1199-1203 (1997)

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      「研究成果報告書概要(和文)」より
  • [Publications] N.Nakamura et al.: "Synthesis and Physical Properties of Ferrocene Derivatives(VI)Crystal Structure of a liquid Cristaline Ferrocene Derivative[4[6-cholesteryoxycarbonyl]hexyloxy..." Molecular Crystals and Liquid Crystals. 307. 145-151 (1997)

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  • [Publications] M.Ioda et al.: "A novel Reverse Micellar System Composed of Bis(octylethylenediamine)zinc(II)in Aqueous Benzene and Chloroform Solution." Chem,Lett.663-664 (1997)

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      「研究成果報告書概要(和文)」より
  • [Publications] Y.Kuroda et al.: "Self-organized Porphyrin Dimer as Highly Specific Receptor for Pyrazine" Journal of the American Chemical Society. 119. 4929-4933 (1997)

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      「研究成果報告書概要(和文)」より
  • [Publications] T.Kato et al.: "Self-Assembly of Mesogenic Polyamide.Induction and Significant Stabilization of a Liquid-crystalline Phase through Complexation of a polymer Backbone Derived from." Angewandete Chemie.Int.Ed.Engl.36. 1617-1618 (1997)

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  • [Publications] 小林 長夫・白井 汪芳: "フタロシアニン 化学と機能" アイピーシー, 338 (1997)

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  • [Publications] N.Kobayashi, R.Higashi and T.Tomura: "Phthalocyanines Containing Silicons in Their Peripheral Substituent Groups." Bull.Chem.Soc.Jpn.70. 2693-2698 (1997)

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      「研究成果報告書概要(欧文)」より
  • [Publications] A.Mori, S.Takematsu and H.Takeshita: "Preparation of Sigmatropic 2-Acyloxy-5-perfluoroalkoxy-troponse : New Monocyclic Troponoid Liquid Crystals with an Enantiotropic Smectic A Phase" Chemistry Letters. 1009-1010 (1997)

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  • [Publications] A.M.vanCraats, J.M.Warman, H.Hasebe, R.Naito and K.Ohta: "Anomalous Charge Transport in the Mesomorphic Freeradical Compound : Bis (octakis-didodecyloxyphthalocyaninato) -lutetium (III)" J.Phys.Chem.B. 101. 9224-9232 (1997)

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  • [Publications] S.Nakashima, A.Hori, H.Sakai, M.Watanabe, and I.Motoyama: "^<57>Fe Mossbaue Spectra and X-ray Structural Analyzes of iodide salts for 1', 1'''-Bis (alpha-and beta-naphthylmethy1) -1,1''-biferrocenes" J.Organomet.Chem.542. 271-280 (1997)

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  • [Publications] S.Yano, M.Nakagoshi, A.Teratani, M.Kato, M.lida, T.Tanase, Y.Yamamoto, H.Uekusa and Y.Ohashi: "Unprecedented Chiral Inversion around Seven-coordinated Cobalt Center Induced by an Interaction between Sugars and Oxo Anions" Inorg.Chem.36. 4187-4194 (1997)

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  • [Publications] Y.Kuroda, A.Kawashima, Y.Hayashi, and H.Ogoshi: "Self-Organized Porphyrin Dimer as Highly Specific Receptor for Pyrazine Dericatives" J.Amer.Chem.Soc.119. 4929-4933 (1997)

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      「研究成果報告書概要(欧文)」より
  • [Publications] H.Monjushiro, K.Harada, M.Nakaura, N.Kato, M.Haga, M.Ryan, and A.B.P.Lever: "Preparation of Surfactant Ruthenium Complexes Containing (Benzimidazolyl) pyridine Derivatives with Long Alkyl Chains" Mol.Crys.Liq.Crys.294. 15-18 (1997)

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      「研究成果報告書概要(欧文)」より
  • [Publications] T.Kato, Y.Kubota, T.Uryu and S.Ujiie: "Self-Assembly of a Mesogenic Polyamide. Induction and Significant Stabilization of a Liquid-Crystalline Phase through Complexation of a Polymer Backbone Derived from 2,6-Bis- (amino) pyridine with a Phenylbenzoic Acid" Angew.Chem.Int.Ed.Engl.36. 1617-1618 (1997)

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  • [Publications] S.YOSHIDA,B.JIN,Y.TAKANISHI,K.ISHIKAWA,H.TAKEZOE,A.FUKUDA,T.NAKAI and S.MIYAJIMA: "Orientational Change of the Trifluoromethyl Group at the Ferroelectric-Antiferroelectric. Transition Observed by NMR Spectroscopy" Mol.Cryst.Liq.Cryst.30. 203-208 (1997)

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  • [Publications] Y.Izumi, K.Urabe and M.Onaka: "Development of Catalyst Materials for Acid-catalyzed Reactions in the Liquid Phase" Catalysis today. 35. 183-188 (1997)

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  • [Publications] K.Akagi, H.Goto, and H.Shirakawa: "Ferroelectric Liquid Crystalline Conducting Polymers-Synthesis and Properties of Polyacetylene Derivatives with Chiroptical Liquid Crystalline Groups" Synthetic Metals. 84. 313-818 (1997)

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  • [Publications] T.Sugioka, E.Yoneda, K.Onitsuka, S.Zhang and S.Takahashi: "Novel rhodium-catalyzed cyclic carbonylation of 2-phenyl-ethynylbenzoates leading to indeno [1,2-c] -isocumarin" Tetrahedron Lett.38. 4989-4992 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N.Nakamura and S.Setodoi: "Synthesess and Physical Properties of Ferrocene Derivatives (VIII) Crystal Structure of a Liquid Cryatalline Ferrocene Derivative, omega- [4- (4-methoxyphenoxycarbonyl) phenoxycarbonyl] buthyl 4-ferrocenylbenzoate" Mol.Cryst.Liq.Cryst.(in press). (1997)

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  • [Publications] Y.Kagaya and H.Isago: "Synthesis of Dichloro (phthalocyaninato) antimony (V) Perchlorate, Tetrafluororate, and Hexafluorophosphate and Electrochemical Reinvestigation on the New Complex Salts" Bull.Chem.Soc.Jpn.70. 2179-2185 (1997)

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  • [Publications] M.Fujita: "Supramolecular Self-assembly of Finite and Infinite Frameworks through Coordination" J.Synth.Org.Chem.Jpn.54. 953-958 (1996)

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  • [Publications] N.Nakamura, R.Mizoguchi, M.Ueda and T.Hanasaki: "Syntheses and Physical Properties of Ferrocene Derivatives (VII) ---Phase Transition Behavior and Liquid Crystal Structure of 1,1'-Disubstituted Ferrocene Derivatives" Mol.Cryst.Liq.Cryst.(in press). (1997)

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  • [Publications] A.Toyotama, S.Kugimiya, M.Yonese and T.Kinoshita: "Controllable Orientation of the Peptide-Based Surfactant at Air-Water Interface" Chem.Lett.443-444 (1997)

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  • [Publications] M.Valli, S.Matsuo, H.Wakita, T.Yamaguchi and M.Nomura: "Solvation of Copper (II) lons in Liquid Ammonia" Inorg.Chem.35. 5642-5645 (1996)

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  • [Publications] S.Yamashita, H.Adachi, M.Fujiwara, Y.Kato, T.Yamaguchi and H.Wakita: "X-Ray Absorption Near Edge Structure Study and DV-Xa Calculations on Some Square-planar Copper (II) Complexes with Macrocyclic Ligands" Advances in Quant.Chem.(in press). (1997)

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  • [Publications] K.Ohta, K.Nakao and Y.Shimizu: "FT-IR and FT-Raman Spectroscopic Studies on Phase Transitions of a Mesogenic Long-Chain Tetraphenylporphyrin" Mikrochim.Acta Suppl.14. 217-221 (1997)

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  • [Publications] H.Ueda, Y.Yamamoto, K.Miyamura, and Y.Gohshi: "Control of the Aggregation Structure of [Ni (dmit) 2] Utilising the Tendency of Artificial Lipid to Form Bilayr Membrane" J.Inorg.Biochem.67. 450-455 (1997)

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  • [Publications] M.Sato, A.Takeuchi, T.Yamada, H.Hoshi, K.Ishikawa, T.Mori and H.Takezoe: "Intermolecular Transitions Observed by Electric-Quadrupole-Resonant Second-Harmonic Generation in a Discotic Liquid Crystal of Phthalocyanine" Phys.Rev.E56. 6264-6270 (1997)

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  • [Publications] M.Komiyama, M.Yashiro, A.Ishikubo, A.Kajimura, M.Ohno and J.Sumaoka: "DNA and RNA Hydrolysis by Metal Complexes for Artificial Pin-Point Restriction Enzymes" J.Inorg.Biochem.67. 341-345 (1997)

    • Description
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  • [Publications] N.Kobayashi and H.Shirai: Phthalocyanines-Chemistry and Functionsed. by H.Shirai and N.Kobayashi. IPC,Tokyo, (1997)

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Published: 1999-03-16  

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