分子の集積・組織化の精密設計と機能制御

1997 Fiscal Year Annual Research Report

• Project/Area Number: 08CE2005
• Research Institution: Kyushu University
• Principal Investigator: 岩村 秀 九州大学, 有機化学基礎研究センター, 教授 (10011496)
• Co-Investigator(Kenkyū-buntansha): 成田 吉徳 九州大学, 有機化学基礎研究センター, 教授 (00108979) ; 新海 征治 九州大学, 大学院・工学研究科, 教授 (20038045) ; 國武 豊喜 九州大学, 大学院・工学研究科, 教授 (40037734) ; 梶山 千里 九州大学, 大学院・工学研究科, 教授 (60037976) ; 稲津 孝彦 九州大学, 理学部, 教授 (60037207) ; 青山 安宏 九州大学, 有機化学基礎研究センター, 教授 (00038093)
• Keywords: 高スピン分子 / 錯体分子磁性体 / 有機ゼオライト / 含窒素多架橋カゴ型化合物 / 分子配列 / 合成二分子膜 / 分子認識素子 / 多核金属錯体

Research Abstract

分子の集積・組織体の設計の精密化が進み、得られた集積・組織体について構成分子の物性の代数和ではない協同現象が発見され、また制御された機能発現が下記の様に行われた。
[岩村 秀](1)フリーラジカルを置換基として有するピリジン塩基では、π系のトポロジーに従ってラジカル中心と配位した磁性金属イオンとが規則的にカップルするだけでなく、金属の不対電子が入っている3d軌道がd(xz)であるかd(x^2-y^2)かによって、窒素原子上の2p(z)軌道と重なりまた直交するため、相互作用が反強磁性的及び強磁性的となることが示された。(2)これにより、ジ(4-ピリジル)ジアゾメタンとMn(II)及びCu(II)イオンとから得られる1次元鎖状錯体に紫外線照射を行うと、それぞれフェリ及びフェロ磁性鎖が得られる原因が解明された。
[青山安宏](1)アントラセン-ビスレゾルシン誘導体の水素結合ネットワークのトポロジーを精密設計することにより、空孔サイズを制御し、ゲスト分子補足の選択性及び空孔内でのディールス・アルダー反応やエン反応などの立体選択性を向上させることに成功した。(2)カリックスアレーンと糖を組み合わせて糖クラスターモデル化合物を設計・合成し、ホスト機能と共にレクチンに大きな親和性を示すことを発見し、ゲスト分子をレクチンに分子輸送できることを示した。
[稲津孝彦](1)4個の窒素原子が6個の2,6-ルチジレン鎖で架橋された“ヘキサ(2,6-ルチジレン)テトラミン"を合成した。4個の橋頭位窒素原子と6個のピリジンの全ての非共有電子対が分子の空孔に向かって配向した、超高電子密度空間を有する。強力なプロトンクリプテートであることが明かとなった。(2)架橋位置に窒素を含むアザカリックスアレーンの合成に成功し、特異な金属イオンとの錯化を発見した。
[梶山千里](1)水面上単分子膜の分子凝縮構造を解析し、分類・体系化を行った。水面上単分子膜の分子運動特性を考慮した構造秩序化法により、従来の手法に比べて著しく高品質の大面積・無欠陥有機単分子膜の構築に成功した。(2)新しく提案された構造秩序化法で脂肪酸単分子膜を調整し、長時間一定の高表面圧下で保持しても崩壊しない程力学的に安定であることを証明し、原子間力顕微鏡による分子像の直接観察に初めて成功した。(3)走査型粘弾性顕微鏡を試作し、膜表面の動的粘弾性関数を直接評価し、表面の分子運動特性がバルクに比べて著しく活性化されていることを世界で初めて明らかにした。
[国武豊喜](1)相補的水素結合を介して初めて両親媒性を獲得するような疎水性メラミン誘導体と親水性シアヌル酸誘導体の複合体を系統的に構築し、水中で複合分子膜の自発的形成を観測した。NMR法により、サブユニット間の動的交換速度過程を解析した。(2)pt(en)_2錯体とPt(en)_2Cl_2錯体を等モル含む無色の水溶液にジアルキルスルホコハク酸等の二分子膜水溶液を添加することにより、紫色の沈殿を得た。これはクロロホルムに有機-無機ポリイオンコンプレックスとして安定に分散していることを、電子顕微鏡観察で確認した。サーモクロミズム等興味ある物性を示し、錯体化学の新分野を拓くものである。
[新海征治](1)側鎖にフェニルボロン酸をもつポルフィリン誘導体が糖分子と錯形成する際に、二分子間のキラル配向、多分子集合体における超分子構造の配向、蛍光スペクトル変化、糖の絶対構造を反映する円二色性スペクトルの発現などを行うことう明らかにした。(2)フェニルボロン酸を含むフェナントロリン及び2,2′-ビピリジルを糖を認識するインターフェイスとして用いることにより、金属錯体などの不斉にその構造情報を転写することに成功した。
[成田吉徳](1)チトクロームc酸化酵素の活性中心構造をミミックするモデル錯体の精度を上げる目的で、鉄-銅異核二核錯体を合成し、酸素分子活性化の機構を明らかにした。(2)マンガン(IV)ポルフィリン2量体錯体を合成し、構造の明確なマンガン錯体から水の酸化により酸素分子を触媒的に発生させることに世界で初めて成功した。

Research Products

• [Publications] Kenji Matsuda: "Singlet and Triplet States Are Degenerate in 2,3-Dimethylenecyclohexane-1,4-diyl" J.Am.Chem.Soc.119(31). 7412-7413 (1997)
• [Publications] Kenji Matsuda: "Control of the “Superexchenge" Interaction through Diphenyl Sulfide 4,4-Diyl Magnetic Coupler by Changing the Oxidation State and COnformation of the Sulfur Atom" J.Am.Chem.Soc.119(34). 8058-8064 (1997)
• [Publications] Kenji Matsuda: "Synthesis and ESR Characterization of Diphenylcarbenes Carrying t-Butyl Nitroxide and Nitronyl Nitroxide Radicals as Substituents and Having Quartet Ground States" Mol.Cryst.Liq.Cryst.306. 89-94 (1997)
• [Publications] Kenji Matsuda: "High-spin Organic Molecular Materials" Curr.Opin.Solid.State Mater.Sci.2(4). 446-450 (1997)
• [Publications] Yoko Sano: "Formation of Ferromagnetic Chains by Photolysis of 1:1 Complexes of Bis(hexafluoroacetylacetonato)copper(II) with Diazodi(4-pyridyl)methane" J.Am.Chem.Soc.119(35). 8246-8252 (1997)
• [Publications] Ryuji Akabane: "Crystal Structures and Magnetic Properties of m-Phenylenebis(imidazole) Derivatives Having Two Nitronyl Nitroxide or Iminyl Nitroxide Radicals.The Two Kinds of Antiferromagnetic Interaction Alternating along One-Dimensional Chains" J.Org.Chem.62(25). 8854-8861 (1997)
• [Publications] T.Ezuhara, K.Endo, O.Hayashida,and Y.Aoyama: "Metal-Ion Induced Alignment of an Orthogonal Anthracene-Pyrimidine Derivative.Cooperation of Metal Coordination,Hydrogen Bonding,and Aromatic Stacking in the Buildup of one-,two-,and Three-Dimensional Networks" New J.Chem.(in press). (1998)
• [Publications] T.Fujimoto, C.Shimizu, O.Hayashida, Y.Aoyama: "Octa(galactose) Derivative of calix[4]resorcarene as a verastile Host in Water" Gazzetta Chim.Ital.(in press). (1998)
• [Publications] K.Endo, T.Ezuhara, M.Koyanagi, H.Masuda,and Y.Aoyama: "Functional Self-Assembly of Hydrogen-Bonded Networks.Construction of Aromatic Stacks and Columns and Cavity-Size Control via Flexible Intercalation of 1D Chains Having Orthogonal Aromatic Substituents" J.Am.Chem.Soc.119. 499-505 (1997)
• [Publications] K.Kuriyama, H.Kikuchi, K.Aoyagi, T.Haga, H.Toi, Y.Aoyama, T.Mizutani,and H.Ogoshi: "Electron Deficient Porphyrins III.Facile Syntheses of Perfluoroalkyl-porphyrins Including water Soluble Porphyrin" Bull.Chem.Soc.Jpn.70. 937-945 (1997)
• [Publications] K.Endo, T.Koike, T.Sawaki, O.Hayashida, H.Masuda,and Y.Aoyama: "Catalysis by Organic Solids.Highly Stereoselective Diels-Alder Reactions Promoted by Microporous Molecular Crystals Having an Extensive Hydrogen-Bonded Network" J.Am.Chem.Soc.119. 4117-4122 (1997)
• [Publications] T.Fujimoto, C.Shimizu, O.Hayashida,and Y.Aoyama: "Solution-to-Surface Molecular Delivery System Using a Macrocyclic Sugar Cluster.Sugar-Directed Adsorption of Guests in Water on Polar Solid Surfaces" J.Am.Chem.Soc.119. 6676-6677 (1997)
• [Publications] K.Oshima, E.Kitazono,and Y.Aoyama: "Complexation-Induced Activation of Sugar OH Groups.Regioselective Alkylation of Methyl Fucopyranoside via Cyclic Phenylboronate in the Presence of Amine" Tetrahedron Lett.38. 5001-5004 (1997)
• [Publications] T.Sawaki, K.Endo, K.Kobayashi, O.Hayashida,and Y.Aoyama: "Catalysis by Organic Solids.Stereoselective Intramolecular Ene Reactions of Citronellal Promoted by Microporous Molecular Crystals Having an Extensive Hydrogen-Bonded Network" Bull.Chem.Soc.Jpn.70. 3075-3079 (1997)
• [Publications] O.Hayashida, C.Shimizu, T. Fujimoto,and Y.Aoyama: "Surface Plasmon Resonance Study on the Interaction of Immobilized Macrocyclic Sugar Clusters with Lectins and Water-Soluble Polymers" Chem.Lett.13-14 (1998)
• [Publications] K.Kobayashi, M.Koyanagi, H.Masuda,and Y.Aoyama: "Self-Assemble of Porphyrin Arrays by Hydrogen Bonding in the Solid State : An Orthogonal Porphyrin-Bis(resorcinol)System" Chem.Eur.J.4. 413-420 (1998)
• [Publications] T.Fujimoto, C.Shimizu, O.Hayashida,and Y.Aoyama: "Ternary Complexation Involving Proteins.Molecular Transport to Saccharide-Binding Proteins Using Macrocyclic Saccharide Cluster as Specific Transporter" J.Am.Chem.Soc.120. 601-602 (1998)
• [Publications] H.Takemura, N.Kon, K.Tani, T.Shinmyozu, T.Inazu et al.: "Stable Cu^+,Ag^+ complexes of aza-bridged macrocyclic molecules : structure and chemical properties" J.Chem.Soc.,Perkin Trans.I. 239-246 (1997)
• [Publications] H.Takemura, H.Kariyazono, N.Kon, T.Inazu et al.: "A Cage Compound containing Four Thiophene Rings : Synthesis and Structural Conversion by Desulfurization" J.Chem.Research(S). 372-373 (1997)
• [Publications] M.Suenaga, Y.Miyahara, N.Shimizu, T.Inazu: "Synthesis of the Trinaphthophenalenium Cation" Angew.Chem.Int.Ed.37,No.1/2. 90-91 (1998)
• [Publications] Alhussein A.Ibrahim, T.Inazu et al.: "Synthesis,Structure,and Complexing Behavior of Novel Macrocycles Containing the Troger Base Skeleton(s)" J.Heterocyclic Chem.(in press). (1998)
• [Publications] S.Yamada, A.Harada, T.Motsuo, S.Ohno, I.Ichinose, T.Kunitake: "Optical Second Harmonic Generation in Alternately Assembled Dye-Polyion Multilayers" Japanese J.Appl.Phys.Pt.2. 36(8B). L1110-L1112 (1997)
• [Publications] H.Koyano, P.Bissel, K.Yoshihara, K.Ariga, T.Kunitake: "Effect of Melamine-Amphiphile Structure on the Extent of Two-Dimensional Hydrogen-Bonded Networks Incorporating Barbituric Acid" Chem.Eur.J.3(7). 1077-1082 (1997)
• [Publications] Y.Lvov, S.Yamada, T.Kunitake: "Nonlinear Optical Effects in Layer-by-Layer Alternate Films of Polycations and an Azobenzene-Containing Polyanion" Thin Solid Films. 300. 107-112 (1997)
• [Publications] N.Kimizuka, T.Asai, S.Ohno, K.Fujiyoshi, T.Kunitake: "Deposition of Photo-Generated Mixed-Valent Fe(II)-Fe(III) Complexes at the Surface of Langmuir Monolayers" Surface Science. 386. 245-248 (1997)
• [Publications] Y.Lvov, K.Ariga, M.Onda, I.Ichinose, T.Kunitake: "Alternate Assembly of Ordered Multilayer of SiO2 and Other Nanoparticles and Polyions" Langmuir. 13(23). 6195-6203 (1997)
• [Publications] M.Onda, Y.Lvov, K.Ariga, T.Kunitake: "Molecularly Flat Films of Linear Polysions and Proteins Obtained by the Alternate Adsorption Method" Japanese J.Appl.Phys.36(12A). L1608-L1611 (1997)
• [Publications] K.Ariga, Y.Lvov, T.Kunitake: "Assembling Alternate Dye-Polyion Molecular Films by Electrostatic Layer-by-Layer Adsorption" J.Am.Chem.Soc.119(9). 2224-2231 (1997)
• [Publications] 君塚信夫、前田 憲、半田豊和、国武豊喜: "二分子キャストフィルムを鋳型とする無機構造制御ならびに分子膜/無機複合超格子の構築" 日本化学会会誌. 1997(5). 301-308 (1997)
• [Publications] K.Ariga, A.Kamino, H.Koyano, T.Kunitake: "Recognition of Aqueous Flavin Mononucleotide on the Surface of Binary Monolayers of Guanidinium and Melamine Amphiphiles" J.Mater.Chem.7(7). 1155-1161 (1997)
• [Publications] T.Yonezawa, M.Sutho, T.Kunitake: "Practical Preparation of Size-Controlled Gold Nanoparticles in Water" Chem.Lett.1997(7). 619-620 (1997)
• [Publications] I.Ichinose, H.Senzu, T.Kunitake: "Surface Sol-Gel Process of TiO2 and Other Metal Oxide Films with Molecular Precision" Chem.Mater.9(6). 1296-1298 (1997)
• [Publications] M.Sakurai, H.Tamagawa, Y.Inoue, K.Ariga, T.Kunitake: "A Theoretical Study of Intermolecular Interaction at the Lipid-Water Interface.1.Quantum Chemical Analysis Using a Reaction Field Theory" J.Phys.Chem.101(24). 4810-4816 (1997)
• [Publications] H.Tamagawa, M.Sakurai, Y.Inoue, K.Ariga, T.Kunitake: "A Theoretical Study of Intermolecular Interaction at the Lipid-Water Interface.2.Analysis Based on the Poisson-Boltzmann Equation" J.Phys.Chem.101(24). 4817-4825 (1997)
• [Publications] T.Kunitake: "Specific Recognition and Two-Dimensional Organization of Molecules at the Air-Water Interface" Pure & Appl.Chem.69(9). 1999-2006 (1997)
• [Publications] N.Kimizuka, M.Tokuhiro, H.Miyauchi, T.Wakiyama, T.Kunitake: "Bilayer Formation in Ethanol from Dialkylammonium Amphiphile Appended with Nitroaniline Moiety" Chem.Lett.1997. 1049-1050 (1997)
• [Publications] H.Koyano, P.Bissel, K.Yoshihara, K.Ariga, T.Kunitake: "Syntheses and Interfacial Hydrogen-Bonded Network of Hexaalkyl Tris(Melamine)Amphiphiles" Langmuir. 13(20). 5426-5432 (1997)
• [Publications] I.Hamachi, A.Fujita, T.Kunitake: "Protein Engineering Using Molecular Assembly : Functional Conversion of Cytochrome c via Noncovalent Interactions" J.Am.Chem.Soc.119(39). 9096-9102 (1997)
• [Publications] Y.Oishi, T.Kato, M.Kuramori, K.Suehiro, K.Ariga, A.Kamino, H.Koyano, T.Kunitake: "Control of Molecular Ordering in Guanidnium-Finctionalized Monolaayer by Carboxylate Template Molecules" Chem.Commun.1357-1358 (1997)
• [Publications] I.Ichinose, H.Tagawa, S.Mizuki, Y.Lvov, T.Kunitake: "Formation Process of Ultrathin Multilayer Films of Molybdenum Oside by Alternate Adsorption of Octamoly" Langmuir. 14(1). 187-192 (1998)
• [Publications] I.Ichinose, H.Miyauchi, M.Tanaka, T.Kunitake: "Controlled Growth of Polypyrrole Thin Films by Polymerization-induced Adsorption" Chem.Lett.1998(1). 19-20 (1998)
• [Publications] S.Shinkai: "Aqueous Sugar Sensing by Boronic-acid-based Artificial Receptors" ″Chemosensors of Ion and Molecule Recognition″. 37-59 (1997)
• [Publications] A.Ikeda, S.Shinkai: "Novel Cavity Design Using Calix[n]arene and Skeletons : Toward Molecular Recognition and Metal Binding" Chem.Rev.97(5). 1713-1734 (1997)
• [Publications] P.Lhotak, S.Shinkai: "Cation-π Interaction in Calix[n]arene and Related Systems" J.Phys.Org.Chem.10(5). 273-285 (1997)
• [Publications] I.Hamachi, Y.Tajiri, T.Nagase, S.Shinkai: "Design and Synthesis of Sugar-Responsive Semiartificial Myoglobin Triggered by Modulation of Apoprotein-Cofactor Interactions" Che.Eur.J.3(7). 1025-1031 (1997)
• [Publications] M.Nishida, D.Ishii, I.Yoshida, S.Shikai: "Molecular Association of Water-Soluble Calixarenes with Several Stibene Dyes and Its Application to the Facile Determination of Cationic Surfactant Concentrations" Bull.Chem.Soc.Jpn.70(9). 2131-2140 (1997)
• [Publications] M..Nishida, M.Yamamoto, S.Sinkai: "Fluorescent Sensing of Uronic Acids Based on a Cooperative Action of Boronic Acid and Metal Chelate" J.Chem.Soc.,Chem.Commun.(18). 1731-1732 (1997)
• [Publications] T.Kuri, K.Muto, Y.Oishi, K.Suehiro, T.Kajiyama: "Construction of Two-dimensional Single Crystal of Fatty Acid by Two-step Cooling Crystallization Method" Chem.lett.417-418 (1997)
• [Publications] Y.Oishi, Y.Takashima, K.Suehiro, T.Kajiyama: "Effect of Ionic Repulsion among Hydrophilic Groups on Aggregation Structure of Fatty Acid Monolayer on the Water Surface" Langmuir. 13. 2527-2532 (1997)
• [Publications] T.Kajiyama, K.Tanaka, A.Takahara: "Surface Molecular Motion of Amorphous Polymeric Solids" Bull.Chem.Soc.Jpn.70. 1491-1503 (1997)
• [Publications] M.Yanagida, T.Kuri, T.Kajiyama: "Construction of C_<60> Monolayer on the Water Surface" Chem.Lett.911-912 (1997)
• [Publications] T.Kuri, J.Hirose, Y.Oishi, K.Suehiro, T.Kajiyama: "Construction of a Defect-Diminished Fatty Acid Crystalline Monolayer by a Multistep Creep Method Based on Its Area-Creep Characteristics" Langmuir. 13. 6497-6501 (1997)
• [Publications] 高原 淳、梶山千里: "高分子化有機シラン単分子膜の表面凝集構造と表面物性" 機能材料. 17, 12. 40-47 (1997)
• [Publications] 竹下道範、新海征治: "カリックスアレーンは「第3の包接化合物」になりうるか?" 季刊化学総説「超分子をめざす化学」. 31. 80-89 (1997)
• [Publications] 新海征治: "原子・分子の識別法における“意外性"の科学" 科学ジャーナル. 4. 18-19 (1997)
• [Publications] H.Suenaga, k.Nakashima, H.Hamachi, S.Shinkai: "Pyrenylboronec Acid as a Novel Entry for Photochemical DNA Cleavage" Tetrahedron Lett.38(14). 2479-2482 (1997)
• [Publications] M.Takeuchi, S.Yoda, T.Imada, S.Shinkai: "Chiral Sugar Recognition by a Diboronic-Acid-Appendend Binaphthyl Derevative through Rigidification Effect" Tetrahedron. 53(25). 8335-8348 (1997)
• [Publications] A.Ikeda, C.Fukuhara, S.Shinkai: "Synthesis and Metal-Binding Properties of Novel “Fullerenocrowns"" Chem.Lett.(5). 407-408 (1997)
• [Publications] A.Ikeda, T.Tsudera, S.Shinkai: "Molecular Design of a “Molecular Syringe" Mimic for Metal Cations Using a 1,3-Alternate Calix[4]arene Cavity" J.Org.Chem.62(11). 3568-3574 (1997)
• [Publications] T.D.James, H.Shinmori, S.Shinkai: "Novel Fluorescence Sensor for ‘Small' Saccharides" J.Chem.Soc.,Chem.Commun. (1). 71-72 (1997)
• [Publications] Y.Suzuki, H.Otsuka, A.Ikeda, S.Shinkai: "Thermodynamic Studies of Slow Metal Exchange Processes in Ionophoric Calix[n]arenes with a Capsule-like Closed Cavity" Tetrahedron Lett.38(12). 421-424 (1997)
• [Publications] M.Takeuchi, H.Kijima, I.Hamachi, S.Shinkai: "A Novel Sugar Sensing System Designed with a Cooperative Action of a Boronic-Acid-Appended Zinc Porphyrin and a 3-Pyridylboronic Acid Axial Ligand" Bull.Chem.Soc.Jpn.70(3). 699-705 (1997)
• [Publications] A.Ikeda, M.Yoshimura, S.Shinkai: "Solution Complexes Formed from C60 and Calixarenes. On the Importance of the Preorganized Structure for Cooperative Interactions" Tetrahedron Lett.38(12). 2107-2110 (1997)
• [Publications] K.Ohto, M.Yano, K.Inoue, T.Nagasaki, M.Goto,: "Effect of Coexisting Alkaline Metal Ions on the Extraction Selectivity of Lanthanide Ion with Calixarene Carboxylate Derivatives" Polyhedron. 16(10). 1655-1661 (1997)
• [Publications] S.Shinkai et al.: "Vibrationl Spectrum of C60 in the p-tert-Butylcalix[8]arene(1:1)C60 Complex" Phys.Rev.B. 55(9). 5566-5569 (1997)
• [Publications] S.W.Jeong, S.Shinkai: "Remarkable Influence of the Preparation Method on the Gelaton Ability of a Cholesterol-Based Isocyanuric Acid-2,4,6-Triaminopyrimidine Pair.Does the Formation of a ‘Mollecular Tape' Contribute to the Gelation?" Nanotechnology. 8(4). 179-185 (1997)
• [Publications] T.Hayashita, K.Kunogi, H.Yamamoto, S.Shinkai: "Selective Colorimetry of Sodium Ion in Acidic Aqueous Media by Calix[4]crown Chromoionophore" Anal.Sci.13. 161-166 (1997)
• [Publications] T.Kakoi, T.Nishiyori, T.Oshima, F.Kubota: "Extraction of Rare-earth Metals by Liquid Surfactant Membranes Containing a Novel Cyclic Carrier" J.Memb.Sci.136. 261-271 (1997)
• [Publications] A.Ikeda, M.Kawaguchi, S.Shinkai: "Synthesis of Multiply-connected 1,3-Alternate-calix[4]arenes.A Novei Approach to Synthetic “Nano-tubes"" Anal.Quim.Int.Ed.93(6). 408-414 (1997)
• [Publications] Y.Naruta, M.Sasayama, K.Ichihara: "Functional Modeling of Manganese-containing O_2 Evolution Enzymes with Manganese Porphyrin Dimers" J.Mol.Catal.A,Chemical. 117. 115-121 (1997)
• [Publications] F.Tani, Y,Naruta: "Synthesis and Properties of an Ultimate P-450 Model : Iron Porphyrin Bearing OH Groups and a Thiolate Ligand in the Cavity above the Heme" J.Inorg.Biochem.67(1-4). 90 (1997)
• [Publications] K.Ichihara, Y.Naruta: "Synthesis and Characterization of High-valent Mn Porphyrin Dimers,and Their Oxidation Properties" J.Inorg.Biochem.67(1-4). 95 (1997)
• [Publications] T.Sasaki, N.Nakamura, Y.Naruta: "Synthesis of Cu-TPA linked Hemes and Their O2 Complexes as a Cytochrome c Oxidase Model" J.Inorg.Biochem.67(1-4). 108 (1997)
• [Publications] K.Ichihara, Y.Naruta: "Synthesis of the High-valent Mn Porphyrin Spiecies by Peroxy Acid Oxidation of Mn^<III> Dimers.Characterization of the Mn^<IV>_2 Species and Evidence of the Mn^V-Mn^<III> Intermediate" Chem.Lett.(1). 185-186 (1998)
• [Publications] T.Sasaki, N.Nakamura, Y.Naruta: "Formation and Spectroscopic Characterization of PeroxoFe^<III>-Cu^<II> Complex.A Modering Reaction of the Heme-Cu Site in Cytochrome c Oxidase" Chem.Lett.(4)(発表予定). (1998)
• [Publications] 青山安宏: "季刊化学総説31,「超分子化学をめざす化学」" カリックスレゾルカレン, 9 (1997)
• [Publications] 青山安宏: "触媒" 有機ゼオライトの触媒作用, 75 (1997)
• [Publications] 青山安宏: "有機合成化学協会誌" 人工超分子:多点相互作用の展開, 5 (1997)
• [Publications] Y.Aoyama: "Comprehensive Supramolecular Chemistry" Cyclophane Hosts : Binding of Polyols and Related Guests, 30 (1997)
• [Publications] Y.Aoyama: "Top.Curr.Chem." Functional Organic Zeolite Analogues(in press), (1998)
• [Publications] 梶山千里: "現代界面コロイド化学の基礎" 丸善, 7 (1997)
• [Publications] 谷 文都、成田 吉徳: "分子認識化学" 三共出版, 173-197 (1997)
• [Publications] Y.Naruta: "New Challenges in Organic Electrochemistry" Gordon and Breach Science Publishers, 323-338 (1998)