2000 Fiscal Year Annual Research Report

分子の集積・組織化の精密設計と機能制御

Research Project

Project/Area Number	08CE2005
Research Institution	Kyushu University
Principal Investigator	新海征治九州大学, 大学院・工学研究院, 教授 (20038045)
Co-Investigator(Kenkyū-buntansha)	梶山千里九州大学, 大学院・工学研究院, 教授 (60037976) 稲津孝彦九州大学, 大学院・理学研究院, 教授 (60037207) 青山安宏九州大学, 有機化学基礎研究センター, 教授 (00038093) 岩村秀放送大学, 教授 (10011496) 君塚信夫九州大学, 大学院・工学研究院, 教授 (90186304) 古賀登九州大学, 大学院・薬学研究院, 教授 (60161890) 成田吉徳九州大学, 有機化学基礎研究センター, 教授 (00108979)
Keywords	高スピン分子 / 錯体分子磁性体 / 有機ゼオライト / 含窒素多架橋カゴ型化合物 / 分子配列 / 合成二分子膜 / 分子認識素子 / 多核金属錯体
Research Abstract	分子の集積・組織体の設計の精密化が進み、得られた集積・組織体について構成分子の物性の代数和ではない協同現象が発見され、また制御された機能発現が下記の様に行われた。【新海征治】糖分子の構造および不斉情報をボロン酸というインターフェイスを通して金属錯体の絶対配置あるいはヘリシティーへ転写することに成功した。また、認識シグナルの増幅および認識に伴う機能の付与を目指し、認識過程にアロステリック効果を用いることを計画した。その結果、セリウムダブルデッカーポルフィリン錯体がアロステリックにゲスト分子を捕捉する構造を有することを明らかとした。さらに糖質を基体とするゲル化剤の開発に成功した。【青山安宏】平成12年度は主に分子集積体の水中での機能化を目指した。有機ゼオラオト関連分野ではランタンを固定化した多孔体を調製し、これを回収・再利用可能な固体触媒として用いればマイケル付加やアルドール縮合などの基本的な炭素-炭素結合生成反応を水中で効率よく進行できることを見い出した。また、生体機能分野においては、疎水性を隠蔽した大環状ガラクトースクラスターが肝細胞を高選択的に認識し、内包するゲスト分子をこの細胞に特異的に運搬できることを明らかにした。【成田吉徳】合理的設計に基ずく超分子型反応場の設計により酸素分子活性化酵素反応の解明と応用を目指して、鉄単核を活性中心に含むチトクロムP450と銅-鉄二核錯体を活性中心に持つチトクロムc酸化酵素の活性中心モデルの合成と酸素との反応を行い、始めて電子供与性軸配位子存在下で酸素付加体の形成とその分光法による構造決定に成功した。また、併せて酸素分子活性化による酸素-酸素結合開裂の中間体の検出にも成功した。【梶山千里】走査型フォース顕微鏡を用いて大面積・低欠陥単分子膜への超微細電圧印加加工を行った。得られたナノピットの直径は約10nm程度であり、任意の場所に再現性よく作成することに成功した。単分散ポリスチレン固体膜表面の粘弾的性質の温度・周波数依存性を水平力顕微鏡および走査粘弾性顕微鏡測定に基づき測定し、表面でのミクロブラウン運動に対応するα緩和の活性化エネルギーがバルクと比較して著しく低下していることを見出した。【稲津孝彦】デカメチル[5]ククルビットウリルの各種金属塩が、酸素、窒素、アルゴン、クリプトンなどの気体分子を包接することを明らかにした。アザカリクサレンと橋頭位に窒素原子を有するカゴ型化合物とのハイブリッドである分子内空孔に水酸基を有するカゴ型化合物の合成に成功した。分子内空孔に共有結合フッ素原子を配向させたカゴ型化合物を合成することにより、包接されたカチオンに対する共有結合フッ素、酸素、窒素原子の錯体形成への寄与を見積もることができた。【岩村秀・古賀登】鎖状構造や枝分かれ構造を持つ新規光応答型磁気カップラー(PMC)とM(hfac)2とを用いた剛体溶媒中での磁気研究において、次のことを示唆する結果が得られた。1)各種鎖状構造を持つPMCとの1:1錯体において、6〜8ユニット連結した一次元構造又は環状構造を持つ集積体をつくる組み合わせを見いだした。2)枝分かれ構造を持つPMCとの錯体で磁化の磁場依存性において強磁性体類似の履歴現象が観測された。【君塚信夫】ハロゲン架橋一次元混合原子価錯体と種々のアニオン性両親媒性化合物から脂溶性の超分子組織体を設計・合成し、それらが有機媒体に可溶化できることの一般性を示した。この結果は従来固体状態が研究対象であった一次元金属錯体を、溶液化学の対象にすることにはじめて成功したものである。また、種々のカチオン性ジスフィド保護剤により被覆された、カチオン性の金、銀ナノ粒子の調製にはじめて成功した。

Research Products
(85 results)

All Other

All Publications (85 results)

[Publications] k.Nakano,S.Tanaka,M.Takagi,S.Shinkai: "Calix[n]arenes Provided with Thiols for Modified Electrode Applications; Ring-size Dependent Voltammetric Behavior toward Ferrocene Derivatives"Chem.Lett.. (1). 60-61 (2000)
[Publications] S.D.-M.Islam,M.Fujitsuka,O.Ito,A.Ikeda,T.Hatano,S.Shinkai: "Photoexcited State Properties of C_<60> Encapsulated in a Water-soluble Calixarene"Chem.Lett.. (1). 78-79 (2000)
[Publications] M.Yamamoto,M.Takeuchi,S.shinkai,F.Tani,Y.Naruta: "Chirality Control of a Cu(I)・(phenanthroline)_2 Complex by a Sugar-Boronic Acid Interaction. A Preliminary Step toward the Total Chain Helicity Control by a Chain-end Sugar-binding"J.Chem.Soc.,Perkin Trans.2. (1). 9-16 (2000)
[Publications] Y.-Z.Hu,S.Tsukiji,S.Shinkai,S.Oishi,I.Hamachi: "Construction of Artificial Photosynthetic Reaction Centers on a Protein Surface : Vectorial, Multistep, and Proton-coupled Electron Transfer for Long-lived Charge Separation"J.Am.Chem.Soc.. 122(2). 241-253 (2000)
[Publications] T.Mizuno,T.Fukumatsu,M.Takeuchi,S.Shinkai: "Re-investigation of Optical Sensing properties of Boronic-acid-appended Re^1 Complexes for Saccharides"J.Chem.Soc.,Perkin Trans.1. (3). 407-413 (2000)
[Publications] A.Ikeda,H.Udzu,M.Yoshimura,S.Shinkai: "Inclusion of [60]Fullerene in a Self-assembled Homooxacalix[3]arene-based Dimeric Capsule Constructed by a PdII-Pyridine Interaction. The Li^+-binding to the Lower Rims Can Improve the Inclusion Ability"Tetrahedron. 56(13). 1825-1832 (2000)
[Publications] M.Numata,A.Ikeda,S.Shinkai: "Properly Assembled Dendrons Can Be Immobilized into Dendrimers by in situ Cross-link"Chem.Lett.. (4). 370-371 (2000)
[Publications] M.Yamamoto,M.Takeuchi,S.Shinkai: "Supramolecular macrocycles Self-assembled by Phenanthroline-Cu(I) and sugar-Boronic Acid Interactions"Tetrahedron Lett.. 41(17). 3137-3140 (2000)
[Publications] Y.-Z.Hu,S.Tsukiji,S.Shinkai,S.Oishi,H.Durr,I.Hamachi: "Coupling Covalent and Noncovalent Electron Transfer in a Catenane-type Donor-sensitizer-acceptor Triad"Chem.Lett.. (5). 442-443 (2000)
[Publications] I.Hamachi,R.Eboshi,J.Watanabe,S.Shinkai: "Guest-Induced Umpolung on a Protein Surface : A Strategy for Regulation of Enzymatic Activity"J.Am,Chem.Soc.. 122(18). 4530-4531 (2000)
[Publications] T.Hatano,A.Ikeda,T.Akiyama,S.Yamada,M.Sano,Y.Kanekiyo,S.Shinkai: "Facile Construction of an Ultra-thin [60]Fullerene Layer from [60]Fullerene-Homooxacalix[3]arene Complexes on a Gold Surface"J.Chem.Soc.,Perkin Trans.2. (5). 909-912 (2000)
[Publications] M.Kawaguchi,A.Ikeda,S.Shinkai,I.Neda: "Electrochemical Studies of Calixarene-[60]Fullerene Inclusion Processes"J.Inclusion Phenom.Macrocycl.Chem.. 37(3). 253-258 (2000)
[Publications] M.Ikeda,S.Shinkai,A.Osuka: "Meso-meso-linked Porphyrin Dimer as a Novel Scaffold for the Selective Binding of Oligosaccharides"Chem.Commun.. (12). 1047-1048 (2000)
[Publications] M.Ikeda,T.Tanida,M.Takeuchi,S.Shinkai: "Allosteric Silver(I) Ion Binding with Peripheral π Clefts of a Ce(IV) Double Decker Porphyrin"Org.Lett.. 2(13). 1803-1805 (2000)
[Publications] Y.-Z.Hu,H.Takashima,S.Tsukiji,S.Shinkai,T.Nagamune,S.Oishi,I.Hamachi: "Direct Comparison of Electron Transfer Properties of Two Distinct Semisynthetic Triads with Non-Protein Based Triad : Unambiguous Experimental Evidences on Protein Matrix Effects"Chem.Eur.J.. 6(11). 1907-1916 (2000)
[Publications] A.Sugasaki,M.Ikeda,M.Takeuchi,K.Koumoto,S.Shinkai: "The First Example of Positive Allosterism in an Aqueous Saccharide-Binding SystemDesigned on a Ce(IV) Bis(porphyrinate) Double Decker Scaffold"Tetrahedron. 56(27). 4717-4723 (2000)
[Publications] I.Hamachi,H.Takashima,Y.-Z.Hu,S.Shinkai,S.Oishi: "Cyclodextrin-appended Myoglobin as a Tool for Construction of a Donor-sensitizer-acceptor Triad on a Protein Surface"Chem.Commun.. (13). 1127-1128 (2000)
[Publications] I.Hamachi,S.Kiyonaka,S.Shinkai: "Solid Phase Lipid Synthesis (SPLS) for Construction of an Artificial Glycolipid Library"Chem.Commun.. (13). 1281-1282 (2000)
[Publications] K.Koumoto,S.Shinkai: "Colorimetric Sugar Sensing Metal Useful in "Neutral" Aqueous Media"Chem.Lett.. (8). 856-857 (2000)
[Publications] T.Mizuno,M.Yamamoto,M.Takeuchi,S.Shinkai: "Sugar 'Chirality' Sensing Using a 'Prochiral' Salen-Co(II) Complex"Tetrahedron. 56(34). 6193-6198 (2000)
[Publications] M.Takeuchi,T.Mizuno,S.Shinkai,S.Shirakami,T.Itoh: "Chirality Sensing of Saccharides Using a Boronic Acid-Appended Chiral Ferrocene"Tetrahedron Asymmetry. 11(16). 3311-3322 (2000)
[Publications] A.Rovertson,S.Shinkai: "Cooperative Binding in Selective Sensors, Catalysts and Actuators"Cordination Chemistry Reviews. 205. 157-199 (2000)
[Publications] R.Luboradzki,O.Gronwald,A.Ikeda,S.Shinkai: "Sugar-Integrated "Supergelators" Which Can Form Organogels with 0.03-0.05% [gmL-1]"Chem.Lett.. (10). 1148-1149 (2000)
[Publications] R.Luboradzki,O.Gronwald,A.Ikeda,S.Shinkai: "Sugar-Integrated "Supergelators" Which Can From Organogels with 0.03-0.05% [gmL-1]"Chem.Lett.. (10). 1148-1149 (2000)
[Publications] A.Ikeda,K.Sonoda,S.Shinkai: "Design of Homooxacalix[3]arene-Porphyrin Heterocapsules Which Provide Novel Cavities for Molecular Recognition"Chem.Lett.. (10). 1220-1221 (2000)
[Publications] A.Ikeda,S.Nobukuni,H.Udzu,Z.Zhong,S.Shinkai: "A Novel [60]Fullerene-Calexarene Conjugate Which Facilitates Self-Inclusion of the [60]Fullerene Moiety into the Homooxacalix[3]arene Cavity"Eur.J.Org.Chem.. (19). 3287-3293 (2000)
[Publications] A.Ikeda,M.Kawaguchi,Y.Suzuki,T.Hatano,M.Numata,S.Shinkai,A.Ohta,M.Aratono: "Thermodynamic Insight into the Origin of a Calix[n]arene-[60]Fullerene Interaction and Its Application to a Porphyrin-[60]Fullerene Energy Transfer System"J.Inclusion Phenom.Macrocyclic Chem.. 38(1-4). 163-167 (2000)
[Publications] S.Sugasaki,M.Ikeda,M.Takeuchi,S.Shinkai: "Novel Oligosaccharide Binding to the Cerium(IV) Bis(porphyrinate) Double Decker : Effective Amplification of a Binding Signal through Positive Homotropic Allosterism"Angew,Chem.Int.Ed.. 39(21). 3839-3842 (2000)
[Publications] A.Ikeda,M.Ayabe,S.Shinkai,S.Sakamoto,K.Yamaguchi: "A Self-Assembled Porphyrin-Based Dimeric Capsule Constructed by a Pd(II)-Pyridine Interaction Which Shows Efficient Guest Inclusion"Org.Lett.. 2(23). 3707-3710 (2000)
[Publications] T.Hayashi,K.Okazaki,H.Shimakoshi,F.Tani,Y.Naruta,Y.Hisaeda: "Synthesis and Properties of Alkylperoxocobalt(III) Porphylin and Porphycen"Chem.Lett. (1). 90-91 (2000)
[Publications] N.Kamiya,M.Inoue,M.Goto,N.Nakamura,Y.Naruta: "Catalytic and Structual Properties of Surfactant-Horseradish Perpxoidase Complex in Organic Media"Biotechnology Progress. 16(1). 52-58 (2000)
[Publications] H.Wariishi,D.Nonaka,T.Johjima,N.Nakamura,Y.Naruta,S.Kubo,K.Fukuyama: "Direct Binding of Hydroxylamine to the Heme Iron of Arthromyces remousus Peroxidase"J.Biol.Chem.. (42). 32919-32924 (2000)
[Publications] M.Yamamoto,M.Takeuchi,S.Shinkai,F.Tani,Y.Naruta: "Chirality Control of a Cu(I)-(phenanthroline)_2 Complex by a Sugar-boronic Acid Interaction.A Preliminary Step Toward the Total Chain helicity Control by a Chain-end Sugar-binding"J.Chem.Soc.,Perkin Trans.2. (1). 9-16 (2000)
[Publications] M.Matsu-ura,F.Tani,S.Nakayama,N.Nakayama,Y.Naruta: "Hydrogen-bounded Dioxygen Addyct of an Iron porphyrin With an Alkylthiolate ligand; An Elabolate Model of Cytochrome P-450"Angew.Chem.Int.Ed.. 37(11). 1989-1991 (2000)
[Publications] M.Matsu-ura,F.Tani,Y.Naruta: "Formation and Spectroscopic Characterization of the Carbon Monoxide Adduct of an Alkanethiolate-coordinated Heme"Chem.lett.. (7). 812-813 (2000)
[Publications] S.Takami,M.Kimura,Y.Tachi,Y.Naruta: "2,4,5-Triphenuy-4H-imidazol-4-yl-hydroperoxide"Acta Crystaroger.Sect.C. C56. e465-e466 (2000)
[Publications] H.Shimakoshi,A.Nakazato,T.Hayashi,Y.Tachi,Y.Naruta,Y.Hisaeda: "Electroorganic Synthesis of Macrocyclic Lactones Mediated by Vitamin B12 Model Complexes"J.Electroanal.Chem.. (印刷中). (2001)
[Publications] 成田吉徳: "酸化還元反応を触媒する含マンガンタンパク質のモデル反応"電気化学および工業物理化学. 68(10). 811-815 (2000)
[Publications] Y.Naruta,T.Sasaki,F.Tani,Y.Tachi,N.kawato,N.Nakamura: "Heme-Cu Complexes as Oxygen-Activating Functional Models for the Active Site of Cytochrome c Oxidase"J.Inorg.Biochem.. 83(印刷中). (2001)
[Publications] F.Tani,M.Matsu-ura,S.Nakayama,M.Ichimura,N.Nakamura,Y.Naruta: "Suntjesisi and Characterization of Alkanethiolate-coordinated Iron Porphyrins and Their Dioxygen Adducts as Models for the Agtive Center of cytochrome P-450"J.Am.Chem.Soc.. 123. 1133-1142 (2001)
[Publications] H.Shimakoshi,M.Koga,T.Hayashi,Y.Tachi,Y.Naruta,Y.Hisaeda: "Synthesis and Redox Behavior of Dialkylated Dicobalt Complexes Having Discrete Two Salene Units"Tetrahedron Lett.. (印刷中). (2001)
[Publications] H.Shimakoshi,M.Koga,T.Hayashi,Y.Tachi,T.Naruta,Y.Hisaeda: "Formation and Cleavage of a Dicobalt Complex Bridged with a Pentamethylene Group"Chem.Lett.. (印刷中). (2001)
[Publications] T.Kajiyama,D.Kawaguchi,A.Sakai,N.Satomi,K.Tanaka,A.Takahara: "Determination Factors on Surface Glass Transition Temperatures of Polymeric Solids"High Peform.Polym.. 12. 587-597 (2000)
[Publications] T.Kajiyama,K.Tanaka,N.Satomi,A.Takahara: "Surface Glass Transition Temperatures of Monodisperse Polystyrene Films by Scanning Force Microscopy"Sci.Tech.Adv.Mater.. 1. 31-35 (2000)
[Publications] K.Tanaka,A.Takahara,T.Kajiyama: "Rheological Analysis of Surface Relaxation Process of Monodisperse Polystyrene Films"Macromolecules. 33(20). 7588-7593 (2000)
[Publications] K.Kojio,A.Takahara,T.Kajiyama: "Molecular Aggregation State and Molecular Motion of Organosilane Monolayers Prepared at the Air/Water Interface"Langmuir. 16(24). 9314-9320 (2000)
[Publications] K.Kojio,A.Takahara,K.Omote,T.Kajiyama: "Molecular Aggregation State of n-Octadecyltrichlorosilane Monolayers Prepared by the Langmuir and Chemisorption Methods"Langmuir. 16(8). 3932-3936 (2000)
[Publications] M.Yanagida,A.Takahara,T.Kajiyama: "Construction of C60 Monolayer Based on Structural Relaxation on the Water Surface"Bull.Chem.Soc.Jpn.. 73(6). 1429-1435 (2000)
[Publications] H.Takemura,H.Kariyazono,M.Yasutake,N.Kon,K.Tani,K.Sako,T.Shinmyozu,T.Inazu: "Syntheses of Macrocyclic Compounds Possessing Fluorine Atoms in Their Cavities : Structures and Complexation with Cations"Europ.J.Org.Chem.. 141-148 (2000)
[Publications] Y.Miyahara,K.Goto,T.Inazu: "Synthesis and Properties of a Novel Tetraazamacrocycle Containing Two Bispidine Units"Chem.lett.. 620-621 (2000)
[Publications] N.kon,H.Takemura,K.Otsuka,K.Tanoue,S.Nakashima,M.Yasutake,K.Tani,J.Kimoto,T.Shinmyozu,T.Inazu: "Synthesis of Macrocyclic Cage Compounds by Diamine-Dihalide One-Step Coupling Reaction"J.Org.Chem.. 65(12). 3708-3715 (2000)
[Publications] H.Takemura,N.Kon,M.Yasutake,S.Nakashima,T.Shinmyozu,T.Inazu: "The C-F - Cation Interaction : An Ammonium Complex of Hexafluoro Macrocyclic Cage Compound"Chemistry-A European Journal. 6(13). 2334-2337 (2000)
[Publications] H.Takemura,S.Nakashima,N.Kon,T.Inazu: "The C-F - Cation Interaction : Alkali Metal Complexes of Hexafluoro Cage Compound"Tetrahedron Lett.. 41(32). 6105-6109 (2000)
[Publications] P.Rabu,M.Drillon,H.Iwamura,G.Gorlitz,T.Itoh,K.Matsuda,N.Koga,K.Inoue: "Exchange Coupling Parameters and Energy Levels for Cyclic Metal-Radical Complexes of Bis (hexafluoroacetylacetonato) manganese (II) with 5-tert-butyl-1, 3-phenylenebis (N-tert-butylaminoxyl) and (4-N-tert-butyl-N-oxyamino) pyridine"Eur.J.Inorg.Chem.. 211-216 (2000)
[Publications] H.Kumada,A.Sakane,N.Koga,H.Iwamura,: "Magnetic Interaction between the 2p Spin of the Aminoxyl Radical and the 3d Spin of the Metal Ions in the Complexes of Bis (hexafluoroacetylacetonato) manganese (II), copper (II), and zinc (II) with 4-(N-tert-Butyl-N-oxylamino)-2, 2'-bipyridine."J.Chem.Soc,Dalton. (6). 911-914 (2000)
[Publications] A.Sakane,H.Kumada,S.Karasawa,N.Koga,H.Iwamura: "Molecular Structures and Magnetic Properties of the Mixed-Ligand Complexes of Bis (hexafluoroacetylacetonato) -manganese (II), copper (II), and zine (II) with 4,4'-Bis (N-tert-butyl-N-oxylamino)-2,2'-bipyridine. Isosceles Triangular Hetero-Three-Spin Systems Consisting of Aminoxyls and Metal Ions"Inorg.Chem.. 39. 2891-2896 (2000)
[Publications] M.Aso,K.Norihisa,M.Tanaka,N.Koga,H.Suemune: "Synthesis of a New Class of Spin-labeled Purine Ribonucleosides and Development of a Novel Nucleophilic Reaction to Form 2,6,8-Trifunctionalized Purine Derivatives."J.Chem.Soc.,Parkin Trans.2. 1637-1638 (2000)
[Publications] Y.Ajiro,T.Asano,Y.Inagaki,S.Karasawa,N.Koga,K.Nishiyama,Y.Miyake,K.Nagamine: "μSr Study of 1 : 1 Complex of Bis (hexafluoroacetylacetonato) manganese (II) with Diazodi (4-pyridyl) methane as a Photo-responsible Magnetic Coupler"Mol.Cryst.and Liq.Cryst.. 343. 103-108 (2000)
[Publications] T.Yonezawa,S.Onoue,N.Kimizuka: "Preparation of Highly Positively Charged Silver Nanoballs and Their Stability"Langmuir. 16(2). 5218-5220 (2000)
[Publications] N.Kimizuka,N.Oda,T.Kunitake: "Self-Assembling Molecular Wires of Halogen-Bridged Platinum Complexes in Organic Media. Mesoscopic Supramolecular Assemblies Consisting of a Mixed Valent Pt (II)/Pt (III) Complex and Anionic Amphiphiles"Inorg.Chem.. 39(12). 2684-2689 (2000)
[Publications] N.Kimizuka,H.Ohira,K.Hattori,T.Kunitake: "Morphological Transcription of Monolayer Domains to Aggregates : Specific Adsorption of Cyanine Dyes to Pre-Compressed Chiral Monolayers"Colloids and Surfaces A : Physicochemical and Engineering Aspects. 171. 265-267 (2000)
[Publications] N.Kimizuka,K.Yamada,T.Kunitake: "Organization of One-Dimensional Mixed Valence Platinum Complexes at the Air-Water Interface and in Langmuir-Blodgett Films"Mol.Cryst.Liq.Cryst.. 342. 103-110 (2000)
[Publications] N.Kimizuka: "Towards Self-Assembling Inorganic Molecular Wires"Adv.Mater.. 12(19). 1461-1463 (2000)
[Publications] T.Yonezawa,K.Yasui,N.Kimizuka: "Controlled Formation of Smaller Gold Nanoparticles by the Use of Four-Chained Disulfide Stabilizer"Langmuir. 17(2). 271-273 (2000)
[Publications] N.Kimizuka,A.Baba,T.Kunitake: "Supramolecular Holoenzymes : Activity modulation of Endonuclease by the Use of Synthetic Bilayer Membranes as Regulatory Cofactors"J.Am.Chem.Soc.. 123(8). 1764-1765 (2001)
[Publications] T.Yonezawa,S.Onoue,N.kimizuka: "Self-Organized Superstructures of Fluorocarbon-Stabilized SIlver Nanoparticles"Adv.Mater.. 13(2). 140-142 (2001)
[Publications] T.Yonezawa,M.Fukumaru,N.Kimizuka: "Controlled Growth of Gold Nanoparticles in Organic Gels"Studies in Surface Science and Catalysis, in press.. (2001)
[Publications] 米澤徹: "高電荷密度表面によるナノ粒子の二次元集積化"高分子錯体アニュアルレビュー. 12-13 (2000)
[Publications] 君塚信夫: "自己組織性を有する分子ワイヤーの構築に向けて"科学と工業. 74(10). 483-488 (2000)
[Publications] 君塚信夫: "新しい分子組織性ナノ材料の設計有機分子により被覆された無機ナノワイヤー"化学工業. 52(3). 198-203 (2001)
[Publications] K.Ariga,K.Endo,Y.Aoyama,Y.Okahata: "QCM Analyses on Adsorption of Gaseous Guests to Cast Films of Porphyrin-Resorcinol Derivatives"Colloid and Surfaces. 169. 177-186 (2000)
[Publications] T.Saiki,T.Dewa,Y.Aoyoma: "A Hydrogen-Bonded Organic Network with Appended Chiral Metal Complexes"Mol.Cryst.Liq.Cryst. 342. 241-248 (2000)
[Publications] T.Dewa,Y.Aoyama: "Ligand Control of the Catalytic Activities of Al3+-Immobilized Solid lewis Acids"J.Mol.Catal.A,Chemical. 152. 257-260 (2000)
[Publications] G.Arena,A.Contino,T.Fujimoto,D.Sciotto,Y.Aoyama: "1H NMR and Calorimetric Studies of the Inclusion of Trimethylammonium Cations into Water Soluble Calixresorcinarenes"Supramol.Chem.. 11. 279-288 (2000)
[Publications] T.Ezuhara,K.Endo,K.Matsuda,Y.Aoyama: "One-Dimensional Chains Consisting of Copper(I) Ion and Orthogonal Anthracene-Pyrimidine Derivative : Hierarchical Formation of High-Dimensional Networks and Their Magnetic Properties"New J.Chem.. 24. 609-613 (200)
[Publications] T.Dewa,Y.Aoyama: "Lattice Inclusion Complexation under Two-Guest Conditions.Preservation of a Single Phase vs Separation of Two Phases"Chem.Let.. 854-855 (2000)
[Publications] K.Matsuura,K.Ariga,K.Endo,Y.Aoyama,Y.Okahata: "Dynamic Analyses on Induced -fit Gaseous Guest Binding to Organic Crystals Having Extensive Hydrogen-Bonded Network by using a Quartz Crystal Microbalance"Chem.Eur.J.. 6. 1750-1756 (2000)
[Publications] H.Kitamura,T.Ozawa,K.Jitsukawa,H.Maseuda,Y.Aoyama,H.Einaga: "Syntheses, Structures, and Properties of Tetrakis (m-acetato) dirhodium(II) Complexes with Axial Pyridine Nitrogen Donor Ligands with or without Assistance of Hydrogen Bonds"Inorg.Chem.. 39. 3294-3300 (2000)
[Publications] K.Fujimoto,T.Miyata,Y.Aoyama: "Saccharide-Directed Cell Recognition and Molecular Delivery Using macrocyclic Sccharide Clusters. Masking of Hydrophobicity to Enhance the Saccharide Specificity"J.Am.Chem.Soc.. 122(14). 3558-559 (2000)
[Publications] T.Dewa,T.Saiki,K.Endo,Y.Aoyama: "Lattice Inclusion Complexation in Water. Hydrogen Bonding in Selective Guest Binding and Catalysis"Bull.Chem.Soc.Jpn.. 73(9). 2123-2127 (2000)
[Publications] T.Tanaka,K.Endo,Y.Aoyama: "A Roust Two-Dimernsional Hydrogen-Bonded Network. Rerversible Guest Adsorption/Desorption without a Phase Change"Chem.Lett.,. 1424-1425 (2000)
[Publications] D.S.Reddy,T.Dewa,K.Endo,Y.Aoyama: "Charge-Transfer Diamondoid lattices : An Unprecedentedly Huge and Highly Catenation Diamondoid Network Arising from a Tetraphenol as a Tetrahedral Node and Benzoquinone as a Liners Spacer"Angew.Chem.Int.Ed.Engl.. 39(23). 4266-4268 (2000)
[Publications] O.Hayashida,A.Matsuo,Y.Aoyama: "Macrocyclic Saccharide Bundles as a New Type of Firm DNB Binders"Chem.Lett.. (in press). (2001)
[Publications] T.Tanaka,K.Endo,Y.Aoyama: "Stacked Porphyrin Arrays from Hydrogen-Bonded Porphyrin-Resorcinol 1D Chains"Bull.Chem.Soc.Jpn.. (in press). (2001)
[Publications] 君塚信夫: "分子がつくるナノの不思議"第14回「大学と科学」公開シンポジウム組織委員会編,クバプロ発行. 207 (2000)

2000 Fiscal Year Annual Research Report

分子の集積・組織化の精密設計と機能制御

Principal Investigator

新海 征治 九州大学, 大学院・工学研究院, 教授 (20038045)

Research Products

[Publications] k.Nakano,S.Tanaka,M.Takagi,S.Shinkai: "Calix[n]arenes Provided with Thiols for Modified Electrode Applications; Ring-size Dependent Voltammetric Behavior toward Ferrocene Derivatives"Chem.Lett.. (1). 60-61 (2000)

[Publications] S.D.-M.Islam,M.Fujitsuka,O.Ito,A.Ikeda,T.Hatano,S.Shinkai: "Photoexcited State Properties of C_<60> Encapsulated in a Water-soluble Calixarene"Chem.Lett.. (1). 78-79 (2000)

[Publications] M.Yamamoto,M.Takeuchi,S.shinkai,F.Tani,Y.Naruta: "Chirality Control of a Cu(I)・(phenanthroline)_2 Complex by a Sugar-Boronic Acid Interaction. A Preliminary Step toward the Total Chain Helicity Control by a Chain-end Sugar-binding"J.Chem.Soc.,Perkin Trans.2. (1). 9-16 (2000)

[Publications] Y.-Z.Hu,S.Tsukiji,S.Shinkai,S.Oishi,I.Hamachi: "Construction of Artificial Photosynthetic Reaction Centers on a Protein Surface : Vectorial, Multistep, and Proton-coupled Electron Transfer for Long-lived Charge Separation"J.Am.Chem.Soc.. 122(2). 241-253 (2000)

[Publications] T.Mizuno,T.Fukumatsu,M.Takeuchi,S.Shinkai: "Re-investigation of Optical Sensing properties of Boronic-acid-appended Re^1 Complexes for Saccharides"J.Chem.Soc.,Perkin Trans.1. (3). 407-413 (2000)

[Publications] A.Ikeda,H.Udzu,M.Yoshimura,S.Shinkai: "Inclusion of [60]Fullerene in a Self-assembled Homooxacalix[3]arene-based Dimeric Capsule Constructed by a PdII-Pyridine Interaction. The Li^+-binding to the Lower Rims Can Improve the Inclusion Ability"Tetrahedron. 56(13). 1825-1832 (2000)

[Publications] M.Numata,A.Ikeda,S.Shinkai: "Properly Assembled Dendrons Can Be Immobilized into Dendrimers by in situ Cross-link"Chem.Lett.. (4). 370-371 (2000)

[Publications] M.Yamamoto,M.Takeuchi,S.Shinkai: "Supramolecular macrocycles Self-assembled by Phenanthroline-Cu(I) and sugar-Boronic Acid Interactions"Tetrahedron Lett.. 41(17). 3137-3140 (2000)

[Publications] Y.-Z.Hu,S.Tsukiji,S.Shinkai,S.Oishi,H.Durr,I.Hamachi: "Coupling Covalent and Noncovalent Electron Transfer in a Catenane-type Donor-sensitizer-acceptor Triad"Chem.Lett.. (5). 442-443 (2000)

[Publications] I.Hamachi,R.Eboshi,J.Watanabe,S.Shinkai: "Guest-Induced Umpolung on a Protein Surface : A Strategy for Regulation of Enzymatic Activity"J.Am,Chem.Soc.. 122(18). 4530-4531 (2000)

[Publications] T.Hatano,A.Ikeda,T.Akiyama,S.Yamada,M.Sano,Y.Kanekiyo,S.Shinkai: "Facile Construction of an Ultra-thin [60]Fullerene Layer from [60]Fullerene-Homooxacalix[3]arene Complexes on a Gold Surface"J.Chem.Soc.,Perkin Trans.2. (5). 909-912 (2000)

[Publications] M.Kawaguchi,A.Ikeda,S.Shinkai,I.Neda: "Electrochemical Studies of Calixarene-[60]Fullerene Inclusion Processes"J.Inclusion Phenom.Macrocycl.Chem.. 37(3). 253-258 (2000)

[Publications] M.Ikeda,S.Shinkai,A.Osuka: "Meso-meso-linked Porphyrin Dimer as a Novel Scaffold for the Selective Binding of Oligosaccharides"Chem.Commun.. (12). 1047-1048 (2000)

[Publications] M.Ikeda,T.Tanida,M.Takeuchi,S.Shinkai: "Allosteric Silver(I) Ion Binding with Peripheral π Clefts of a Ce(IV) Double Decker Porphyrin"Org.Lett.. 2(13). 1803-1805 (2000)

[Publications] A.Sugasaki,M.Ikeda,M.Takeuchi,K.Koumoto,S.Shinkai: "The First Example of Positive Allosterism in an Aqueous Saccharide-Binding SystemDesigned on a Ce(IV) Bis(porphyrinate) Double Decker Scaffold"Tetrahedron. 56(27). 4717-4723 (2000)

[Publications] I.Hamachi,H.Takashima,Y.-Z.Hu,S.Shinkai,S.Oishi: "Cyclodextrin-appended Myoglobin as a Tool for Construction of a Donor-sensitizer-acceptor Triad on a Protein Surface"Chem.Commun.. (13). 1127-1128 (2000)

[Publications] I.Hamachi,S.Kiyonaka,S.Shinkai: "Solid Phase Lipid Synthesis (SPLS) for Construction of an Artificial Glycolipid Library"Chem.Commun.. (13). 1281-1282 (2000)

[Publications] K.Koumoto,S.Shinkai: "Colorimetric Sugar Sensing Metal Useful in "Neutral" Aqueous Media"Chem.Lett.. (8). 856-857 (2000)

[Publications] T.Mizuno,M.Yamamoto,M.Takeuchi,S.Shinkai: "Sugar 'Chirality' Sensing Using a 'Prochiral' Salen-Co(II) Complex"Tetrahedron. 56(34). 6193-6198 (2000)

[Publications] M.Takeuchi,T.Mizuno,S.Shinkai,S.Shirakami,T.Itoh: "Chirality Sensing of Saccharides Using a Boronic Acid-Appended Chiral Ferrocene"Tetrahedron Asymmetry. 11(16). 3311-3322 (2000)

[Publications] A.Rovertson,S.Shinkai: "Cooperative Binding in Selective Sensors, Catalysts and Actuators"Cordination Chemistry Reviews. 205. 157-199 (2000)

[Publications] R.Luboradzki,O.Gronwald,A.Ikeda,S.Shinkai: "Sugar-Integrated "Supergelators" Which Can Form Organogels with 0.03-0.05% [gmL-1]"Chem.Lett.. (10). 1148-1149 (2000)

[Publications] R.Luboradzki,O.Gronwald,A.Ikeda,S.Shinkai: "Sugar-Integrated "Supergelators" Which Can From Organogels with 0.03-0.05% [gmL-1]"Chem.Lett.. (10). 1148-1149 (2000)

[Publications] A.Ikeda,K.Sonoda,S.Shinkai: "Design of Homooxacalix[3]arene-Porphyrin Heterocapsules Which Provide Novel Cavities for Molecular Recognition"Chem.Lett.. (10). 1220-1221 (2000)

[Publications] A.Ikeda,S.Nobukuni,H.Udzu,Z.Zhong,S.Shinkai: "A Novel [60]Fullerene-Calexarene Conjugate Which Facilitates Self-Inclusion of the [60]Fullerene Moiety into the Homooxacalix[3]arene Cavity"Eur.J.Org.Chem.. (19). 3287-3293 (2000)

[Publications] S.Sugasaki,M.Ikeda,M.Takeuchi,S.Shinkai: "Novel Oligosaccharide Binding to the Cerium(IV) Bis(porphyrinate) Double Decker : Effective Amplification of a Binding Signal through Positive Homotropic Allosterism"Angew,Chem.Int.Ed.. 39(21). 3839-3842 (2000)

[Publications] A.Ikeda,M.Ayabe,S.Shinkai,S.Sakamoto,K.Yamaguchi: "A Self-Assembled Porphyrin-Based Dimeric Capsule Constructed by a Pd(II)-Pyridine Interaction Which Shows Efficient Guest Inclusion"Org.Lett.. 2(23). 3707-3710 (2000)

[Publications] T.Hayashi,K.Okazaki,H.Shimakoshi,F.Tani,Y.Naruta,Y.Hisaeda: "Synthesis and Properties of Alkylperoxocobalt(III) Porphylin and Porphycen"Chem.Lett. (1). 90-91 (2000)

[Publications] N.Kamiya,M.Inoue,M.Goto,N.Nakamura,Y.Naruta: "Catalytic and Structual Properties of Surfactant-Horseradish Perpxoidase Complex in Organic Media"Biotechnology Progress. 16(1). 52-58 (2000)

[Publications] H.Wariishi,D.Nonaka,T.Johjima,N.Nakamura,Y.Naruta,S.Kubo,K.Fukuyama: "Direct Binding of Hydroxylamine to the Heme Iron of Arthromyces remousus Peroxidase"J.Biol.Chem.. (42). 32919-32924 (2000)

[Publications] M.Yamamoto,M.Takeuchi,S.Shinkai,F.Tani,Y.Naruta: "Chirality Control of a Cu(I)-(phenanthroline)_2 Complex by a Sugar-boronic Acid Interaction.A Preliminary Step Toward the Total Chain helicity Control by a Chain-end Sugar-binding"J.Chem.Soc.,Perkin Trans.2. (1). 9-16 (2000)

[Publications] M.Matsu-ura,F.Tani,S.Nakayama,N.Nakayama,Y.Naruta: "Hydrogen-bounded Dioxygen Addyct of an Iron porphyrin With an Alkylthiolate ligand; An Elabolate Model of Cytochrome P-450"Angew.Chem.Int.Ed.. 37(11). 1989-1991 (2000)

[Publications] M.Matsu-ura,F.Tani,Y.Naruta: "Formation and Spectroscopic Characterization of the Carbon Monoxide Adduct of an Alkanethiolate-coordinated Heme"Chem.lett.. (7). 812-813 (2000)

[Publications] S.Takami,M.Kimura,Y.Tachi,Y.Naruta: "2,4,5-Triphenuy-4H-imidazol-4-yl-hydroperoxide"Acta Crystaroger.Sect.C. C56. e465-e466 (2000)

[Publications] H.Shimakoshi,A.Nakazato,T.Hayashi,Y.Tachi,Y.Naruta,Y.Hisaeda: "Electroorganic Synthesis of Macrocyclic Lactones Mediated by Vitamin B12 Model Complexes"J.Electroanal.Chem.. (印刷中). (2001)

[Publications] 成田吉徳: "酸化還元反応を触媒する含マンガンタンパク質のモデル反応"電気化学および工業物理化学. 68(10). 811-815 (2000)

[Publications] Y.Naruta,T.Sasaki,F.Tani,Y.Tachi,N.kawato,N.Nakamura: "Heme-Cu Complexes as Oxygen-Activating Functional Models for the Active Site of Cytochrome c Oxidase"J.Inorg.Biochem.. 83(印刷中). (2001)

[Publications] F.Tani,M.Matsu-ura,S.Nakayama,M.Ichimura,N.Nakamura,Y.Naruta: "Suntjesisi and Characterization of Alkanethiolate-coordinated Iron Porphyrins and Their Dioxygen Adducts as Models for the Agtive Center of cytochrome P-450"J.Am.Chem.Soc.. 123. 1133-1142 (2001)

[Publications] H.Shimakoshi,M.Koga,T.Hayashi,Y.Tachi,Y.Naruta,Y.Hisaeda: "Synthesis and Redox Behavior of Dialkylated Dicobalt Complexes Having Discrete Two Salene Units"Tetrahedron Lett.. (印刷中). (2001)

[Publications] H.Shimakoshi,M.Koga,T.Hayashi,Y.Tachi,T.Naruta,Y.Hisaeda: "Formation and Cleavage of a Dicobalt Complex Bridged with a Pentamethylene Group"Chem.Lett.. (印刷中). (2001)

[Publications] T.Kajiyama,D.Kawaguchi,A.Sakai,N.Satomi,K.Tanaka,A.Takahara: "Determination Factors on Surface Glass Transition Temperatures of Polymeric Solids"High Peform.Polym.. 12. 587-597 (2000)

[Publications] T.Kajiyama,K.Tanaka,N.Satomi,A.Takahara: "Surface Glass Transition Temperatures of Monodisperse Polystyrene Films by Scanning Force Microscopy"Sci.Tech.Adv.Mater.. 1. 31-35 (2000)

[Publications] K.Tanaka,A.Takahara,T.Kajiyama: "Rheological Analysis of Surface Relaxation Process of Monodisperse Polystyrene Films"Macromolecules. 33(20). 7588-7593 (2000)

[Publications] K.Kojio,A.Takahara,T.Kajiyama: "Molecular Aggregation State and Molecular Motion of Organosilane Monolayers Prepared at the Air/Water Interface"Langmuir. 16(24). 9314-9320 (2000)

[Publications] K.Kojio,A.Takahara,K.Omote,T.Kajiyama: "Molecular Aggregation State of n-Octadecyltrichlorosilane Monolayers Prepared by the Langmuir and Chemisorption Methods"Langmuir. 16(8). 3932-3936 (2000)

[Publications] M.Yanagida,A.Takahara,T.Kajiyama: "Construction of C60 Monolayer Based on Structural Relaxation on the Water Surface"Bull.Chem.Soc.Jpn.. 73(6). 1429-1435 (2000)

[Publications] H.Takemura,H.Kariyazono,M.Yasutake,N.Kon,K.Tani,K.Sako,T.Shinmyozu,T.Inazu: "Syntheses of Macrocyclic Compounds Possessing Fluorine Atoms in Their Cavities : Structures and Complexation with Cations"Europ.J.Org.Chem.. 141-148 (2000)

[Publications] Y.Miyahara,K.Goto,T.Inazu: "Synthesis and Properties of a Novel Tetraazamacrocycle Containing Two Bispidine Units"Chem.lett.. 620-621 (2000)

[Publications] N.kon,H.Takemura,K.Otsuka,K.Tanoue,S.Nakashima,M.Yasutake,K.Tani,J.Kimoto,T.Shinmyozu,T.Inazu: "Synthesis of Macrocyclic Cage Compounds by Diamine-Dihalide One-Step Coupling Reaction"J.Org.Chem.. 65(12). 3708-3715 (2000)

[Publications] H.Takemura,N.Kon,M.Yasutake,S.Nakashima,T.Shinmyozu,T.Inazu: "The C-F - Cation Interaction : An Ammonium Complex of Hexafluoro Macrocyclic Cage Compound"Chemistry-A European Journal. 6(13). 2334-2337 (2000)

[Publications] H.Takemura,S.Nakashima,N.Kon,T.Inazu: "The C-F - Cation Interaction : Alkali Metal Complexes of Hexafluoro Cage Compound"Tetrahedron Lett.. 41(32). 6105-6109 (2000)

[Publications] M.Aso,K.Norihisa,M.Tanaka,N.Koga,H.Suemune: "Synthesis of a New Class of Spin-labeled Purine Ribonucleosides and Development of a Novel Nucleophilic Reaction to Form 2,6,8-Trifunctionalized Purine Derivatives."J.Chem.Soc.,Parkin Trans.2. 1637-1638 (2000)

[Publications] Y.Ajiro,T.Asano,Y.Inagaki,S.Karasawa,N.Koga,K.Nishiyama,Y.Miyake,K.Nagamine: "μSr Study of 1 : 1 Complex of Bis (hexafluoroacetylacetonato) manganese (II) with Diazodi (4-pyridyl) methane as a Photo-responsible Magnetic Coupler"Mol.Cryst.and Liq.Cryst.. 343. 103-108 (2000)

[Publications] T.Yonezawa,S.Onoue,N.Kimizuka: "Preparation of Highly Positively Charged Silver Nanoballs and Their Stability"Langmuir. 16(2). 5218-5220 (2000)

[Publications] N.Kimizuka,N.Oda,T.Kunitake: "Self-Assembling Molecular Wires of Halogen-Bridged Platinum Complexes in Organic Media. Mesoscopic Supramolecular Assemblies Consisting of a Mixed Valent Pt (II)/Pt (III) Complex and Anionic Amphiphiles"Inorg.Chem.. 39(12). 2684-2689 (2000)

[Publications] N.Kimizuka,H.Ohira,K.Hattori,T.Kunitake: "Morphological Transcription of Monolayer Domains to Aggregates : Specific Adsorption of Cyanine Dyes to Pre-Compressed Chiral Monolayers"Colloids and Surfaces A : Physicochemical and Engineering Aspects. 171. 265-267 (2000)

[Publications] N.Kimizuka,K.Yamada,T.Kunitake: "Organization of One-Dimensional Mixed Valence Platinum Complexes at the Air-Water Interface and in Langmuir-Blodgett Films"Mol.Cryst.Liq.Cryst.. 342. 103-110 (2000)

[Publications] N.Kimizuka: "Towards Self-Assembling Inorganic Molecular Wires"Adv.Mater.. 12(19). 1461-1463 (2000)

[Publications] T.Yonezawa,K.Yasui,N.Kimizuka: "Controlled Formation of Smaller Gold Nanoparticles by the Use of Four-Chained Disulfide Stabilizer"Langmuir. 17(2). 271-273 (2000)

[Publications] N.Kimizuka,A.Baba,T.Kunitake: "Supramolecular Holoenzymes : Activity modulation of Endonuclease by the Use of Synthetic Bilayer Membranes as Regulatory Cofactors"J.Am.Chem.Soc.. 123(8). 1764-1765 (2001)

[Publications] T.Yonezawa,S.Onoue,N.kimizuka: "Self-Organized Superstructures of Fluorocarbon-Stabilized SIlver Nanoparticles"Adv.Mater.. 13(2). 140-142 (2001)

[Publications] T.Yonezawa,M.Fukumaru,N.Kimizuka: "Controlled Growth of Gold Nanoparticles in Organic Gels"Studies in Surface Science and Catalysis, in press.. (2001)

[Publications] 米澤徹: "高電荷密度表面によるナノ粒子の二次元集積化"高分子錯体アニュアルレビュー. 12-13 (2000)

[Publications] 君塚信夫: "自己組織性を有する分子ワイヤーの構築に向けて"科学と工業. 74(10). 483-488 (2000)

[Publications] 君塚信夫: "新しい分子組織性ナノ材料の設計有機分子により被覆された無機ナノワイヤー"化学工業. 52(3). 198-203 (2001)

[Publications] K.Ariga,K.Endo,Y.Aoyama,Y.Okahata: "QCM Analyses on Adsorption of Gaseous Guests to Cast Films of Porphyrin-Resorcinol Derivatives"Colloid and Surfaces. 169. 177-186 (2000)

[Publications] T.Saiki,T.Dewa,Y.Aoyoma: "A Hydrogen-Bonded Organic Network with Appended Chiral Metal Complexes"Mol.Cryst.Liq.Cryst. 342. 241-248 (2000)

[Publications] T.Dewa,Y.Aoyama: "Ligand Control of the Catalytic Activities of Al3+-Immobilized Solid lewis Acids"J.Mol.Catal.A,Chemical. 152. 257-260 (2000)

[Publications] G.Arena,A.Contino,T.Fujimoto,D.Sciotto,Y.Aoyama: "1H NMR and Calorimetric Studies of the Inclusion of Trimethylammonium Cations into Water Soluble Calixresorcinarenes"Supramol.Chem.. 11. 279-288 (2000)

[Publications] T.Ezuhara,K.Endo,K.Matsuda,Y.Aoyama: "One-Dimensional Chains Consisting of Copper(I) Ion and Orthogonal Anthracene-Pyrimidine Derivative : Hierarchical Formation of High-Dimensional Networks and Their Magnetic Properties"New J.Chem.. 24. 609-613 (200)

[Publications] T.Dewa,Y.Aoyama: "Lattice Inclusion Complexation under Two-Guest Conditions.Preservation of a Single Phase vs Separation of Two Phases"Chem.Let.. 854-855 (2000)

[Publications] K.Matsuura,K.Ariga,K.Endo,Y.Aoyama,Y.Okahata: "Dynamic Analyses on Induced -fit Gaseous Guest Binding to Organic Crystals Having Extensive Hydrogen-Bonded Network by using a Quartz Crystal Microbalance"Chem.Eur.J.. 6. 1750-1756 (2000)

[Publications] H.Kitamura,T.Ozawa,K.Jitsukawa,H.Maseuda,Y.Aoyama,H.Einaga: "Syntheses, Structures, and Properties of Tetrakis (m-acetato) dirhodium(II) Complexes with Axial Pyridine Nitrogen Donor Ligands with or without Assistance of Hydrogen Bonds"Inorg.Chem.. 39. 3294-3300 (2000)

[Publications] K.Fujimoto,T.Miyata,Y.Aoyama: "Saccharide-Directed Cell Recognition and Molecular Delivery Using macrocyclic Sccharide Clusters. Masking of Hydrophobicity to Enhance the Saccharide Specificity"J.Am.Chem.Soc.. 122(14). 3558-559 (2000)

[Publications] T.Dewa,T.Saiki,K.Endo,Y.Aoyama: "Lattice Inclusion Complexation in Water. Hydrogen Bonding in Selective Guest Binding and Catalysis"Bull.Chem.Soc.Jpn.. 73(9). 2123-2127 (2000)

新海征治九州大学, 大学院・工学研究院, 教授 (20038045)