2001 Fiscal Year Annual Research Report

分子の集積・組織化の精密設計と機能制御

Research Project

Project/Area Number	08CE2005
Research Institution	Kyushu University
Principal Investigator	新海征治九州大学, 大学院・工学研究院, 教授 (20038045)
Co-Investigator(Kenkyū-buntansha)	筒井哲夫九州大学, 大学院・総合理工学研究院, 教授 (40037982) 梶山千里九州大学, 大学院・工学研究院, 教授 (60037976) 成田吉徳九州大学, 有機化学基礎研究センター, 教授 (00108979) 古賀登九州大学, 大学院・薬学研究院, 教授 (60161890) 大川尚士九州大学, 大学院・理学研究院, 教授 (00037219)
Keywords	高スピン分子 / 錯体分子磁性体 / 有機ゼオライト / 含窒素多架橋カゴ型化合物 / 分子配列 / 合成二分子膜 / 分子認識素子 / 多核金属錯体
Research Abstract	【平成13年度の研究実績の概要】分子の集積・組織体の設計の精密化が進み、得られた集積・組織体について構成分子の物性の代数和ではない協同現象が発見され、また制御された機能発現が下記の様に行われた。一次元デザイングループ【新海研究室】糖構造を有する新規なゲル化剤を用いて水、有機溶媒、イオン性液体に対してもゲル化挙動を示すことを見いだした。さらに糖部分を有するポルフィリンゲル化剤を新規に開発した。ゾルーゲル反応を利用し、単一分子が1次元的に集積した有機・無機複合体である1次元ナノ組織体を安定な状態で作成出来ることを見いだした。【君塚研究室】一次元ハロゲン架橋白金混合原子価錯体をキラル脂質で被覆した,新しい"自己組織性"の分子ワイヤーを合成した。有機溶媒中において脂質のキラリティーに依存したナノコイル超構造が形成されることを,原子間力顕微鏡観察から明らかにした。またこの電荷移動吸収は過塩素酸塩に比べて著しく小さなバンドギャップを与えることを明らかにした。二次元デザイングループ【梶山研究室】局所力学物性を考慮した有機単分子膜、高分子超薄膜のピンポイントナノ加工技術を確立するための、相溶系(脂肪酸/光応答性分子)混合単分子膜の構築に成功した。また、二次元空間に束縛された分子膜の力学物性の評価法を確立した。その結果、基板と分子膜の相互作用の分子運動特性に及ぼす影響を明らかにすることができた。また、分子の末端基構造制御に基づき、表面・薄膜物性を制御することに成功した。【筒井研究室】無機一有機層状ペロブスカイト化合物の真空蒸着法による薄膜形成手法において、微結晶のサイズを制御する方法を確立した。その結果、発光効率が格段に向上でき、電気励起発光素子の高輝度化が実現した。液晶類似化合物、自己組織化単分子膜などの自己組織性有機化合物を用いて基板上に大面積の自己組織化有機薄膜を形成する手法を開拓した。【高原研究室】シリコンウエハー基板上に有機シラン単分子膜を形成し、クロムマスクを介した真空紫外光照射による光分解で有機シラン相とSiO_2のパターン形成を確認した。さらに第2成分の化学吸着・真空紫外光照射、第3成分の化学吸着を行うことにより、3種類の化学的性質の異なる相が規則的に配列した表面の構築に成功した。フルオロアルキル成分とSiO_2のパターンを牛血清アルブミン(BSA)水溶液に浸漬した場合、BSAのフルオロアルキ相への選択吸着が観察された。三次元デザイングループ【古賀・岩村研究室】枝分かれ構造を持つ新規光応答型磁気カップラーと金属イオンからなる剛体溶媒中での集積体において、光照射後、磁石の一種であるスピングラスの生成が確認された。更に、同様の条件下、新たな発想のもとに単分子磁石構築を行い、今までに例のない光応答型単核単分子磁石の生成を示唆する磁気挙動を観測した。【大川研究室】異なるスピンの二種類の金属イオンからなる分子磁性系の研究を行ない、世界最高の磁気転移温度Tc=71Kの三次元フェリ磁性体の合成に成功した。又、透明磁性体のファラデー効果を研究して、磁気秩序状態で強い磁気円二色性の観測に成功した。新規磁性系としてシアン橋架け三元金属化合物の設計法を確立して、Ni(II)Gd(III)Cr(III)化合物でTc=57Kの強磁性転移を実現した。【入江研究室】フォトクロミックジアリールエテンの単結晶状態におけるフォトクロミズムに伴う表面モルフォロジーの変化を検討し、分子の厚みに相当する1nmスケールのステップが可逆的に出現・消失することを見出した。フォトクロミズムに伴い蛍光強度変化を示す単結晶ジアリールエテンについて3次元光記録・蛍光読み出しを検討し、5Tbit/cm^3相当の高密度光記録の可能性を実証した。総合デザイングループ【成田研究室】ミオグロピンのモデルである鉄ポルフィリン錯体では、配位場近傍の水酸基の非共有電子対からの負の静電的相互作用により、一酸化炭素と酸素が高い選択性をともなって識別されていることを見いだした。チトクロム酸化酵素のモデルであるヘム鉄-銅二核錯体のペルオキシ付加体を単離して、磁気的、電子的状態を明確に同定した。【青山研究室】有機ゼオライト関係では超臨界流体(二酸化炭素)中でのゲスト捕捉挙動を明らかにするとともに、工業的にも重要なブドウ糖から果糖への糖の異性化がランタン担持有機ゼオライト触媒により効率よく進行することを見出した。生体認識関係では中性の糖クラスターが受容体経由の遺伝子運搬に極めて有効に用いえることを明らかにした。

Research Products
(108 results)

All Other

All Publications (108 results)

[Publications] S.Tamaru, R.Luboradzki, S.Shinkai: "On the Delicate Influence of a Minute Amount of Water on the Organogel Stability Comprised of a Sugar-integrated Gelator"Chem. Lett.. (4). 336-337 (2001)
[Publications] M.Ikeda, M.Takeuchi, S.Shinkai, F.Tani, Y.Naruta: "Synthesis of New Diaryl-substituted Triple-decker and Tetraaryl-substituted Double Decker Lanthanum(III) Porphyrins and Their Pohyrin Ring Rotation Speed as Compared with That of Double-decker Cerium(IV) Porphyrins"Bull. Chem. Soc. Jpn.. 74(4). 739-746 (2001)
[Publications] Z.Zhong, A.Ikeda, S.Shinkai, S.Sakamoto, K.Yamaguchi: "Creation of Novel Chiral Cryptophanes by a Self-assembling Method Utilizing a Pyridyl-Pd(II) Interaction"Org. Lett.. 3(7). 1085-1087 (2001)
[Publications] M.Yamazaki, M.Fujitsuka, 0.Ito, A.Ikeda, C.Fukuhara, M.Kawaguchi, S.Shinkai: "Energy Transfer and Electron Transfer of Photoexcited 5,6-open-azaC60 and 6,6-closed-azaC6O in the Presence of Retinyl Polyenes: Hydrogen-bonding Effect"J. Photochem. Photobiol. A: Chem.. 140(4). 139-146 (2001)
[Publications] I.Hamachi, J.Watanabe, R.Eboshi, T.Hiraoka, S.Shinkai: "Incorporation ofArtificial Receptors into a Protein Peptide Surfae: A strategy for On/Off-type of Switching of Semisynthetic Enzymes"Biopolymers. 55(6). 459-468 (2001)
[Publications] A.Ikeda, H.Udzu, Z.Zhong, S.Shinkai, S.Sakamoto, K.Yamaguchi: "A Self-Assembled Homooxacalix[3]arene-based Dimeric Capsule Constructed by a PdII-Pyridine Interaction Which Shows a Novel Chiral Twisting Motion in Response to Guest Inclusion"J. Am. Chem. Soc.. 123(17). 3872-3877 (2001)
[Publications] A.Ikeda, T.Hatano, S.Shinkai, T.Akiyama, S.Yamada: "Efficient Photocurrent Generation in Novel Self-Assembled Multilayers Comprised of [60]Fullerene-Cationic Homooxacalix[3]arene Inclusion Complex and Anionic Porphyrin Polymer"J. Am. Chem. Soc.. 123(20). 4855-4856 (2001)
[Publications] A.Robertson, M.Ikeda, M.Takeuchi, S.Shinkai: "Al losteric Binding of K+ to Crown Ether Macrocycles Appended to a Lanthanum Double Decker System"Bull. Chem. Soc. Jpn.. 74(5). 883-888 (2001)
[Publications] M.Kawaguchi, A.Ikeda, S.Shinkai: "A Novel Porphynn-Homooxacalix[3]arene Conjugate Which Creates a C3-Symmetrical Capsular Space"Tetrahedron Lett.. 42(16). 3725-3728 (2001)
[Publications] M.Yamamoto, A.Sugasaki, M.Ikeda, M.Takeuchi, K.Frimat, T.D.James, S.Shinkai: "Efficient Anion Binding to Cerium(IV) Bis(porphyrinate) Double Decker Utilizing Positive Homotropic Allosterism"Chem. Lett.. (6). 520-521 (2001)
[Publications] I.Hamachi, S.Kiyonaka, S.Shinkai: "Solid-phase Lipid Synthesis (SPLS-2): Incidental Discovery of Organogelators based on Artificial Glycolipids"Tetrahedron Lett.. 42(35). 6141-6145 (2001)
[Publications] Y.Mito-oka, S.Tsukiji, T.Hiraoka, N.Kasagi, S.Shinkai, I.Hamachi: "Zn(II) Dipicolylamine-based Artificial Receptor as a New Entry for Surface Recognition of a-Helical Peptides in Aqueous Solution"Tetrahedron Lett.. 42(40). 7059-7062 (2001)
[Publications] 梶山千里, 田中敬二, 高原淳: "高分子固体膜表面における分子鎖熱運動性の制御因子"機能材料(シーエムシー出版). 7 (2002)
[Publications] 梶山千里, 高原淳: "第4章第2節走査型プローブ顕微鏡"ポリマーABCハンドブック(NTS). 12 (2001)
[Publications] Y.Kubo, M.Ikeda, A.Sugasaki, M.Takeuchi, S.Shinkai: "A Porphyrin Tetramer for a Positive Homotropic Allosteric Recognition System: Efficient Binding Information Transduction through Butadiynyl Axis Rotation"Tetrahedron Lett.. 42(42). 7435-7438 (2001)
[Publications] A.Sugasaki, K.Sugiyasu, M.Ikeda, M.Takeuchi, S.Shinkai: "First Successful Molecular Design of an Artificial Lewis Oligosaccharide Binding System Utilizing Positive Homotropic Allosterism"J. Am. Chem. Soc.. 123(42). 10239-10244 (2001)
[Publications] A.Ikeda, M.Ayabe, S.Shinkai: "A Novel Self-assembled Porphyrin Polymer Constructed by a Pd(II)-Pyridine Interaction"Chem. Lett.. (11). 1138-1139 (2001)
[Publications] A.Ikeda, K.Sonoda, M.Ayabe, S.Tamarn, T.Nakashima, N.Kimizuka, S.Shinkai: "Gelation of Ionic Liquids with a Low Molecular-weight Gelator Showing Tgel above 100℃"Chem. Lett.. (11). 1154-1155 (2001)
[Publications] S.Tamaru, M.Nakamura, M.Takeuchi, S.Shinkai: "Rational Design of a Sugar-Assembled Porphyrin Gelator That Is Forced to Assemble into a One-Dimmensional Aggregate"Org. Lett.. 3(23). 3631-3634 (2001)
[Publications] S.Tamaru, M.Yamamoto, S.Shinkai, A.B.Khasanov, T.W.Bell: "A Hydrogen-Bonding That Binds Cationie Monosaccharides with High Affinity in Methanol"Chem. Eur. J.. 7(24). 5270-5276 (2001)
[Publications] M.Ikeda, A.Sugasaki, Y.Kubo, K.Sugiyasu, M.Takeuchi, S.Shinkai: "Porphyrin Polygons: A New Synthetic Strategy for Cyclic Porphyrin Oligomers Utilizing a Porphyrin Double Decker Structure"Chem. Lett.. (12). 1266-1267 (2001)
[Publications] H.Takashima, Y-Z.Hu, K.Sano, S.Shinkai, S.Oishi, I.Hamachi: "Supramolecular Construction of Covalently and Noncovalently-linked Photoinduced Electron Transfer Systems in Myoglobin Scaffold"Electrochemistry. 69(12). 942-945 (2001)
[Publications] 池田篤志: "3次元空孔を利用した精密分子認識素子の開発-巨大空孔を持つカプセル分子の構築を目指して-"化学と工業. 54(2). 160-163 (2001)
[Publications] 清中茂樹, 浜地格, 新海征治: "モジュール法を用いる糖鎖誘導体の合成とその分子集合超構造"表面. 39(5). 206-214 (2001)
[Publications] S, Shinkai, M.Ikeda, A.Sugasaki, M.Takeuchi: "Positive Allosteric Systems Designed on Dynamic Supramolecular Scaffolds: Toward Switching and Amplification of Guest Affinity and Selectivity"34(6). 494-503 (2001)
[Publications] 新海征治, 浜地格: "分子認識化学-人工ホストからバイオまで-"化学と工業. 54(6). 691-693 (2001)
[Publications] Tetsu YONEZAWA, Shin-ya ONOUE, Nobuo KIMIZUKA: "Self-Organized Superstructures of Fluorocarbon-Stabilized Silver Nanoparticles"Adv.Mater.. 13・2. 140-142 (2001)
[Publications] Tetsu YONEZAWA, Tetsu YONEZAWA, Nobuo KIMIZUKA: "Controlled Formation of Smaller Gold Narticles by the Use of Four-Chained Disulfide Stabilizer"Langmuir. 17・2. 271-273 (2001)
[Publications] Nobuo KIMIZUKA, Atsushi BABA, Toyoki KUNITAKE: "Supramolecular Holoenzymes. Activity Modulation of Endonuclease by the Use of Synthetic Bilayer Membranes as Regulatory Cofactors"J.Am.Chem. Soc.. 123・8. 1764-1765 (2001)
[Publications] Tetsu YONEZAWA, Shin-ya ONOUB, Nobuo KIMIZUKA: "Formation of Uniform Fluorinated Gold Nanoparticles and Their Highly Ordered Hexagonal Packing Monolayer"Langmuir. 17・8. 2291-2293 (2001)
[Publications] Takayoshi Kawasaki, Maki Tokuhiro, Nobuo Kimizuka, Toyoki Kunitake: "Hierarchical Self-Assembly of Chiral Complementary Hydrogen Bond Networks in Water. Reconstitution of Supramolecular Membranes"J. Am. Chem. Soc.. 123・28. 6792-6800 (2001)
[Publications] Tetsu Yonezawa, Kuniko Imamura, Nobuo Kimizuka: "Direct Preparation and Size Control of Palladium Nanoparticle Hydrosols by Water-Soluble Isocyanide Ligands"Langmuir. 17・16. 4701-4703 (2001)
[Publications] Nobuo Kimizuka, Takuya Nakashima: "Spontaneous Self-assembly of Glycolipid Bilayer Membranes in Sugar-philic Ionic Liquids and Formation of lonogels"Langmuir. 17・22. 6759-6761 (2001)
[Publications] Atsushi Ikeda, Kenshi Sonoda, Masatsugu Ayabe, Shun-ichi Tamaru, Takuya Nakashima, Nobuo Kimizukka, Seiji Shinkai: "Gelation of Ionic Liquids with a Low Molecular-weight Gelator Showing Tgel above 100℃"Chem. Lett.. 11. 1154-1155 (2001)
[Publications] D.Kawaguchi, K.Tanaka, A.Takahara, T.Kajiyama: "Surface Mobile layer of Polystyrene Film below Bulk Glass Transition temperature"Macromolecules. 34(18). 6164-6166 (2001)
[Publications] N.Satomi, K.Tanaka, A.Takahara, T.Kajiyama: "Effect of Internal Bulk Phase on Surface Viscoelastic Properties by Scanning Probe Microscopy"Macromolecules. 34(18). 6420-6423 (2001)
[Publications] N.Satomi, K.Tanaka, A.Takahara, T.Kajiyama: "Surface Molecular Motion of Monodisperse a, w-Diamino-Terminated and a, w-Dicaroxy-Tenninated Polystyrenes"Macromolecules. 34(25). 8761-8767 (2001)
[Publications] K.Kojio, K.Tanaka, A.Takahara, T.Kajiyama: "Novel Method to Prepare Organisilane Monolayers on Solid Substrate"Bull. Chem. Soc. Jpn.. 74(8). 1397-1401 (2001)
[Publications] D.Katsis, H.P.Chen, S.H.Chen, D.U.Kim, L.J.Lothberg, T.Tsutsui: "Circularly Polarized Photoluminescence from Gradient-Pitch Chiral-Nematic Films"Chem. Mater.. Vol.13. 643-647 (2001)
[Publications] T.Tsutsui, H.Yokogawa, M.Yokoyama, M.Yahiro, K.Kawano: "Doubling Coupling-Out Efficiency in Organic Light-Emitting Devices Using Thin Silica Aerogel Layer"Adv. Mater.. Vol.13 No.15. 1149-1152 (2001)
[Publications] S.Lee, T.Tsutsui, T.Nakamura: "Synthesis and Characterization of Oligo(9,9-Dihexyl-2,7-Fluorene Ethynylene)s: for Application as Blue Light-Emitting Diode"Organic Letters. Vol.3 No.13. 2001-2007 (2001)
[Publications] M.Yahiro, T.Tsutsui: "Influence of Device Configuration on External Quantum Efficiency in Organic Light-Emitting Devices"Mat. Res. Soc. Symp. Proc.. Vol.660. JJ5.27.1-6 (2001)
[Publications] K.Kojio, A.Takahara, T.Kajiyama: "Aggregation Structure and Surface Properties of Immobilized Fluoroalkylsilane and Their Mixed Monolayers"ACS Symp. Ser., Fluorinated Surfaces, Coatings, and Films. 787. 31-47 (2001)
[Publications] N.Torikai, M.Furusaka, H.Matsuoka, Y.Matsushita, M.Shibayama, A.Takahara, M.Takeda.S.Tasaki.H.Yamaoka: "A New Thermal Neutron Reflectometer for Free Surface at KENSr ARISA"Proceeding of 1 5th Meeting of the International Collaboration on Advanced Sources. 443-449 (2001)
[Publications] A.Takahara, Y.Hara, K.Kojio, T.Kajiyama: "Scanning Force Microscopic Study of Protein Adsorption on the Surface of Organosilane Monolayers Prepared by the Langmuir-Blodgett Method"Macromolecular Symposia. 167. 273-286 (2001)
[Publications] 4.K.Yamamoto, H.Otsuka, S.-I.Wada, A.Takahara: "Surface Modification of Aluminosilicate Nanofiber "Imogolite""Chemistry Letters. No.11. 1162-1163 (2001)
[Publications] Hiroshi NIORIKAWA, Fumika IMAMURA, Yasuo TSURUKAMI, Tetsuji ITOH, Harumi KUMADA, Satoru KARASAWA, Noboru KOGA, Hiizu IWAMURA: "2,2-Bipyridines Carrying Diazo Moiety and Their Complexes with Bis(hexafluoroacetylacetonato)copper: Synthesis, Structures, Electronic and Magnetic Properties of Their Photoproducts in Frozen Solutions"J. Matr. Chem.. 11・2. 493-502 (2001)
[Publications] Mariko ASO, Takeshi IKENO, Kouji NORIHISA, Masakazu TANAKA, Noboru KOGA, Hiroshi SUEMUNE: "2. Molecular Design of a New Class of Spin-Labeled Ribonucleosides with N-tert-Butylaminoxyl Radicals"J. Org. Chem.. 66・10. 3513-3520 (2001)
[Publications] Satoru KARASAWA, Noboru KOGA: "3 Photochemical Formations of Super High-spin Molecules Consisting of Carbenes and Metal ions in Frozen Solutions"Polyhedron. 20. 1387-1389 (2001)
[Publications] Takeyuki AKITA, Noboru KOGA: "Magnetic Properties After Irradiation of Poly(m-phenyleneethynylene) Having Diazo and Nitronylnitroxide Groups and Its Model Compounds"Polyhedron. 20. 1475-1477 (2001)
[Publications] Tetsuji ITOH, Kenji MATSUDA, Hiizu IWAMURA, Kenzi HORI: "The Ground Spin States ofTris[p-(N-oxyl-N-tert-butylamino)phenyl]amine, Methyl, and Borane. Prospects of Further Studies"J. Solid State Chem.. 159. 428-439 (2001)
[Publications] Motoko TANAKA, Yuko HOSOKOSHI, Ashot S.MARKOSYAN, Katsuya INGUE, Hiizu IWAMURA: "Metal (3d) Organic (2p)-hybnd Magnets Made of Mn(II) ions with Tris(aminoxyl) Radicals (R's) as Bridging Ligands. 2D Complexes [{Mn(hfac)2}3 R2]"Synthetic Metals.. 122. 463-470 (2001)
[Publications] Satoru KARASAWA, Harumi KUMADA, Noboru KOGA, Hiizu IWAMURA: "Magnetic Behavior of a 3:2 Mixture of Bis(hexafluoroacetylacetonato)copper(II) and 1, 3, 5-Benzenetriyltris(4-pyndyldiazomethane) in a Frozen Solution after Irradiation Photochemical Formation of a Solid Solution Magnet"J. Am. Chem. Soc.. 123・39. 9685-9686 (2001)
[Publications] Y.Takano, Y.Kitagawa, T.Onishi, Y.Yoshioka, K.Yamaguchi, N.Koga, H.Iwamura: "Theoretical Studies of Magnetic Interactions in Mn(II)(hfac)2 { di-(4-pyridyl)phenylcarbene} and Cu(LL)(hfac)2{di-(4-pyridyl)phenylcarbene}"J. Am. Chem. Soc.. 124・3. 450-461 (2002)
[Publications] Fukita, N; Ohba, M; Shiga, T; Okawa, H; Ajiro, Y: "Trinuclear Cu-<II>M^<II>Cu^<II> complexes of an oxamide/dioxime ligand and extension to a bimetallic magnetic compound"J. Chem. Soc.-Dalton Trans.. 1. 64-70 (2001)
[Publications] Mikami, S; Sugiura, K; Maruta, T; Maeda, Y; Ohba, M; Usuki, N; Okawa, H et al.: "Structure, optical and magnetic behaviour of meso-tetraphenylporphyrinatoiron(III) tetracyanoethenide, [Fe^<III>(TPP)]^+[TCNE]^-"J. Chem. Soc.-Dalton Trans.. 4. 448-455 (2001)
[Publications] Abe, K; Izumi, J; Ohba, M; Yokoyama, T; Okawa, H: "Dinuclear zinc complexes of phenol-based "end-off" compartmental ligands: Synthesis, structures and phosphatase-like activity"Bull. Chem. Soc. Jpn.. 74・1. 85-95 (2001)
[Publications] Arimura, K; Ohba, M; Yokoyama, T; Okawa, H: "Template synthesis of macrocyclic dinuclear Cull complexes and conversion into mononuclear complexes by site-selective copper elimination"Bull. Chem. Soc. Jpn.. 74・3. 495-503 (2001)
[Publications] Nakamura, Y; Yonemura, M; Arimura, K; Usuki, N; Ohba, M; Okawa, H: "Tetranuclear mixed-metal M_2^<II>Cu_2^<II> complexes derived from a phenol-based macrocyclic ligand having two N(amine)_2O_2 and two N(imine)_2O_2 metal-binding sites"Lnorg. Chem.. 40・15. 3739-3744 (2001)
[Publications] Kodera, M; Taniike, Y; Itoh, M; Tanahashi, Y; Shimakoshi, H; Kano, K; Ohba, M; Okawa, H.: "Synthesis, characterization, and activation of thermally stable m-1,2-peroxodiiron(III) complex"Inorg. Chem.. 40・19. 4821-4823 (2001)
[Publications] Ikeda, K; Ohba, M; Okawa, H: "Dinuclear Cu^<II> and Ni^<II> complexes of 3-formylsalicylic acid: cis/trans topology and extension of a cis-Cu_2(II) complex to a pentanuclear Cu^<II>Cu^<II>Mn^<II>Cu^<II>Cu^<II> complex"J. Chem. Soc.-Dalton Trans.. 20. 3119-3124 (2001)
[Publications] Arimura, K; Ohba, M; Yokoyama, T; Okawa, H: "Hydrolytic activity ofZn^<II>Zn^<II> and ZnBa^<II> complexes toward tri(p-nitrophenyl) phosphate and di(p-nitrophenyl) phosphate: A functional model of heterobimetallic phosphodiesterase"Chem. Lett.. 11. 1134-1135 (2001)
[Publications] Inoue, K; Imai, H; Ghalsasi, PS; Kikuchi, K; Ohba, M; Okawa, H; Yakhmi, JV: "A three-dimensional ferrimagnet with a high magnetic transition temperature (T_c) of 53 K based on a chiral molecule"Angew. Chem. -Int. Edit.. 40・22. 4242-4245 (2001)
[Publications] Inoue, K; Ohba, M; Okawa, H.: "Heterodinuclear M^<II>N^<II> (M=Co, Ni, Cu, Zn) Complexes a Macrocyclic Compartmental Ligand. Anomaloous EPR of Cu^<II>Ni^<II> Complex by Coordination of 1 -Methylimidazole"Bull. Chem. Soc. Jpn.. 75・1. 99-107 (2002)
[Publications] Yonemura, M; Arimura, K; Inoue, K; Usuki, N; Ohba, M; Okawa, H.: "Coordination-Position Isomeric M^<II>Cu^<II> and Cu^<II>M^<II>(M=Co, Ni, Zn) Complexes Derived from Macrocyclic Compartmental Ligands"Inorg. Chem.. 41・3. 582-589 (2001)
[Publications] T.D.James, S.Shinkai: "Artificial Receptors as Chemosensors for Carbohydrates"Top. Curr. Chem.. 218. 159-200 (2001)
[Publications] Shinichiro NAKAMURA: "Multiphoton Gated Photochromic Reaction in a Diarylethene Derivative"Journal of American Chemical Society. 123,4. 753-754 (2001)
[Publications] Masato FUKUDOME: "Photochromism of a Dithienylethene Having Diphenylamido Side Groups in the Bulk Amorphous Phase"Chemistry Letters. 2001,1. 70-71 (2001)
[Publications] Tuyoshi FUKAMINATO: "Three Dimensional Optical Erasable Optical Memory using a Photochromic Diarylethene Single Crystal as the Recording medium"Procceedings of Japanese Academy. B77,2. 30-35 (2001)
[Publications] Masahiro IRIE: "Reversible Surface Morphology Chanes of a Photochromic Diarylethene Single Crystal by Photoirrdiation"Science. 291. 1769-1772 (2001)
[Publications] Kenji MATSUDA: "Single-crystalline Photochromism of a Liner Coordination Polymer Composed of 1,2-bis[2-methyl-5-(4-pyridyl)-3-thienyl]perfluoro cyclopentene and bis(hexafluoroacetylacetonato)zinc(II)"Chemical Communications. 363-364 (2001)
[Publications] Tsuyoshi KAWAL: "A Photoresponsive Laser Dye Containing Photochromic Dithienylethene Units"Chemical Communications. 711-712 (2001)
[Publications] Jerome CHAUVIN: "Refractive Index Change of an Amorphous Bisbenzothienylethene"Japanese Journal of Applied Physics. 40,4A. 2518-2522 (2001)
[Publications] Kingo UCHIDA: "Photochromism of DiarAethenes on Porous Aluminum Oxide: Fatigue Resistance and Redox Potentials of the Photochromism"Chemistry Letters. 4. 366-367 (2001)
[Publications] Kingo UCHIDA: "Substituent Effect on the Photochromic Reactivity of Bis(2-thienyl) perfluorocyclopentenes"Tetrahedron. 57. 4559-4565 (2001)
[Publications] Kenji MATSUDA: "Photoswitching of Intramolecular Magnetic Interaction Using Photochromic Diarylethene Spin Coupler: Introduction of Thiophene Spacer"Chemistry Letters. 2001,5. 436-437 (2001)
[Publications] Atsuhiro OSUKA: "Synthesis and Photoisomenzation of Dithienylethene-Bridged Diporphyrins"Journal of Organic Chemistry. 66,11. 3913-3923 (2001)
[Publications] Tsuyoshi TSUJIOKA: "Two-photon Absorption in Photochromic Layer with Highly Localized Coherent Photons"Optical Review. 8,3. 206-207 (2001)
[Publications] Katsunori SHIBATA: "Extraordinarily Low Cycloreversion Quantum Yields of Photochromic Diarylethenes with Methoxy Substituents"Chemistry Letters. 7. 618-619 (2001)
[Publications] Myeong-Suk KIM: "Synthesis of Fluorescent Amorphous Diarylethenes"Chemistry Letters. 7. 702-703 (2001)
[Publications] Christoph SCHNORPFEIL: "Aggregation and Photodimerization of Areno-Condensed Annulenes"Helvetica Chimica Acta. 84. 2467-2475 (2001)
[Publications] Kyoko YAGI: "Synthesis of Fluorescent Diarylethenes Having a 2,4,5-Triphenylimidazole Chromophore"Journal of Organic Chemistry. 66,16. 5419-5423 (2001)
[Publications] Tsuyoshi KAWAI: "Photo-Generation of Acids and its Fluorescence Detection in a Small Area: a Near Field Write-Once Memory"Japanese Journal of Applied Phjysics. 40,8A. 5145-5148 (2001)
[Publications] Kenji MATSUDA: "Photochromism of Diarylethenes with Two Nitronyl Nitroxides: Photoswitching of an Intramolecular Magnetic Interation"Chemistry of Europian Journal. 7,16. 3466-3473 (2001)
[Publications] Taro YAMADA: "Crystal Structure-Reactivity Correlation in Single-Crystalline Photochromism of 1,2-Bis(2-methyl-5-phenyl-3-thienyl)perfluorocyclopentene"Journal of Organic Chemistry. 66,18. 6141-6168 (2001)
[Publications] Kenji MATSUDA: "Diastereoselective Cyclization of a Diarylethene Having a Chiral N-phenylethylamide Substituent in Crystals"Tetrahedron Letters. 42,41. 7291-7293 (2001)
[Publications] Kenji MATSUDA: "Photoswitching of Intramolecular Magnetic Interaction Using a Diarylethene Dimer"Japanese of American Chemical Society. 23,40. 9896-9897 (2001)
[Publications] Tadatsugu YAMAGUCHI: "Photoinduced Pitch Changes in Chiral Nematic Liquid Crystals Formed by Doping with Chiral Diarylethene"Journal of Material Chemistry. 11,10. 2453-2458 (2001)
[Publications] Kenji MATSUDA: "Photoswitching of Intramolecular Magnetic Interaction Using Diarylethene with Oligothiophene p-Conjugated Chain"Journal of Organic Chemistry. 66,26. 8799-8803 (2001)
[Publications] Tadatsugu YAMAGUCHI: "Enantioresolution and Absolute Stereochemistry of a Photochromic Bis(benzo[b]thienyl)ethene Compound"Enantiomer. 6,5. 309-311 (2001)
[Publications] H.Shimakoshi, A.Nakazato, T.Hayashi, Y.Tachi, Y.Naruta, Y.Hisaeda: "Electroorganic Synthesis of Macrocyclic Lactones Mediated by Vitamin B 1 2 Model Complexes"J. Electroanal. Chem.. 507(1-. 170-176 (2001)
[Publications] Y.Naruta, T.Sasaki, F.Tani, Y.Tachi, N.Kawato, N.Nakamura: "Heme-Cu Complexes as Oxygen-Activating Functional Models for the Active Site of Cytochrome c Oxidase"J. Lnorg. Biochem. 83(4). 239-246 (2001)
[Publications] F.Tani, M.Matsu-ura, S.Nakayama, M.Ichimura, N.Nakamura, Y.Naruta: "Synthesis and Characterization of Alkanethiolate-coordinated Iron Porphyrins and Their Dioxygen Adducts as Models for the Active Center of Cytochrome P-450"J. Am. Chem. Soc.. 123(6). 1133-1142 (2001)
[Publications] H.Shimakoshi, A.Goto, Y.Tachi, Y.Naruta, Y.Hisaeda: "Synthesis and Redox Behavior of Dialkylated Dicobalt Complexes Having Discrete Two Salene Units"Tetrahedron Lett.. 42(10). 1949-1951 (2001)
[Publications] H.Shimakoshi, M.Koga, T.Hayashi, Y.Tachi, Y.Naruta, Y.Hisaeda: "Formation and Cleavage of a Dicobalt Complex Bridged with a Pentamethylene Group"Chem. Lett.. (4). 346-347 (2001)
[Publications] Y.Shimazaki, H.Takesue, T.Chishiro, F.Tani, Y.Naruta: "Synthesis and Characterization of the Dicobalt Bisporphyrin Complex Linked by 1,2-Phenylene Bridge"Chem. Lett.. (6). 538-539 (2001)
[Publications] M.Ikeda, M.Takeuchi, S.Shinkai, F.Tani, Y.Naruta: "Synthesis of New Diarl-substituted Triple-decker and Tetraaryl-substituted Double Decker Lanthanum(L1I) Porphyrins and Their Porphyrin Ring Rotation Speed as Compared with That ofDouble-decker Cerium(IV) Porphyrins"Bull. Chem. Soc. Jpn.. 74(4). 739-746 (2001)
[Publications] A.Kossanyi, F.Tani, N.Nakamura, Y.Naruta: "Properties of a Binaphthy-bridged Porphyrin-Iron Complex bearing Hydroxy Groups Inside Its Cavity"Eur. J. Chem.. 7(13). 2862-2872 (2001)
[Publications] Y.Naruta, Y.Tachi, T.Chishiro, Y.Shimazaki, F.Tani: "2-(Imidazol-1-yl)-4-methylphenol"Acta Crystallogr. Sect. E. 56(6). o550-o552 (2001)
[Publications] Z.Zhong, A.Ikeda, S.Shinkai: "Calixarenes 2001"Kluwer Academic Pub.. 476-495 (2001)
[Publications] S.Shinkai: "Molecular Switches"Wiley-VCH. 281-307 (2001)
[Publications] S.Shinkai, A.Robertson: "New Trends in Fluorescence Spectroscopy"Springer-Verlag. 173-185 (2001)
[Publications] S.Shinkai, T.D.James: "Optical Sensors and Switches"Marcel Dekker. 429-456 (2001)
[Publications] 筒井哲夫: "高分子科学と光物理学とのキャッチボール光情報化時代の新材料・新技術の展望(高分子学会編)"(株)エヌ・テイー・エス. 164 (2001)
[Publications] 筒井哲夫: "フラットパネルディスプレイ大事典(材料・技術・応用編)"(株)工業調査会. 1139 (2001)
[Publications] 松岡秀樹, 松下裕秀, 古坂道弘, 柴山充弘, 高原淳, 武田全康, 田崎誠司, 鳥飼直也, 山岡仁史: "あらゆる物質の界面ナノ構造が分かる中性子反射率法(図解ナノテクノロジー・川合知二監修)"工業調査会. 6 (2001)
[Publications] 林田修, 青山安宏: "学会出版センター"糖鎖分子の設計と生理機能. 7 (2001)
[Publications] 成田吉徳: "生物と金属-金属イオンの生体内で働く仕組み"クバプロ. 18 (2001)

2001 Fiscal Year Annual Research Report

分子の集積・組織化の精密設計と機能制御

Principal Investigator

新海 征治 九州大学, 大学院・工学研究院, 教授 (20038045)

Research Products

[Publications] S.Tamaru, R.Luboradzki, S.Shinkai: "On the Delicate Influence of a Minute Amount of Water on the Organogel Stability Comprised of a Sugar-integrated Gelator"Chem. Lett.. (4). 336-337 (2001)

[Publications] Z.Zhong, A.Ikeda, S.Shinkai, S.Sakamoto, K.Yamaguchi: "Creation of Novel Chiral Cryptophanes by a Self-assembling Method Utilizing a Pyridyl-Pd(II) Interaction"Org. Lett.. 3(7). 1085-1087 (2001)

[Publications] I.Hamachi, J.Watanabe, R.Eboshi, T.Hiraoka, S.Shinkai: "Incorporation ofArtificial Receptors into a Protein Peptide Surfae: A strategy for On/Off-type of Switching of Semisynthetic Enzymes"Biopolymers. 55(6). 459-468 (2001)

[Publications] A.Ikeda, H.Udzu, Z.Zhong, S.Shinkai, S.Sakamoto, K.Yamaguchi: "A Self-Assembled Homooxacalix[3]arene-based Dimeric Capsule Constructed by a PdII-Pyridine Interaction Which Shows a Novel Chiral Twisting Motion in Response to Guest Inclusion"J. Am. Chem. Soc.. 123(17). 3872-3877 (2001)

[Publications] A.Ikeda, T.Hatano, S.Shinkai, T.Akiyama, S.Yamada: "Efficient Photocurrent Generation in Novel Self-Assembled Multilayers Comprised of [60]Fullerene-Cationic Homooxacalix[3]arene Inclusion Complex and Anionic Porphyrin Polymer"J. Am. Chem. Soc.. 123(20). 4855-4856 (2001)

[Publications] A.Robertson, M.Ikeda, M.Takeuchi, S.Shinkai: "Al losteric Binding of K+ to Crown Ether Macrocycles Appended to a Lanthanum Double Decker System"Bull. Chem. Soc. Jpn.. 74(5). 883-888 (2001)

[Publications] M.Kawaguchi, A.Ikeda, S.Shinkai: "A Novel Porphynn-Homooxacalix[3]arene Conjugate Which Creates a C3-Symmetrical Capsular Space"Tetrahedron Lett.. 42(16). 3725-3728 (2001)

[Publications] M.Yamamoto, A.Sugasaki, M.Ikeda, M.Takeuchi, K.Frimat, T.D.James, S.Shinkai: "Efficient Anion Binding to Cerium(IV) Bis(porphyrinate) Double Decker Utilizing Positive Homotropic Allosterism"Chem. Lett.. (6). 520-521 (2001)

[Publications] I.Hamachi, S.Kiyonaka, S.Shinkai: "Solid-phase Lipid Synthesis (SPLS-2): Incidental Discovery of Organogelators based on Artificial Glycolipids"Tetrahedron Lett.. 42(35). 6141-6145 (2001)

[Publications] Y.Mito-oka, S.Tsukiji, T.Hiraoka, N.Kasagi, S.Shinkai, I.Hamachi: "Zn(II) Dipicolylamine-based Artificial Receptor as a New Entry for Surface Recognition of a-Helical Peptides in Aqueous Solution"Tetrahedron Lett.. 42(40). 7059-7062 (2001)

[Publications] 梶山千里, 田中敬二, 高原淳: "高分子固体膜表面における分子鎖熱運動性の制御因子"機能材料(シーエムシー出版). 7 (2002)

[Publications] 梶山千里, 高原淳: "第4章第2節走査型プローブ顕微鏡"ポリマーABCハンドブック(NTS). 12 (2001)

[Publications] Y.Kubo, M.Ikeda, A.Sugasaki, M.Takeuchi, S.Shinkai: "A Porphyrin Tetramer for a Positive Homotropic Allosteric Recognition System: Efficient Binding Information Transduction through Butadiynyl Axis Rotation"Tetrahedron Lett.. 42(42). 7435-7438 (2001)

[Publications] A.Sugasaki, K.Sugiyasu, M.Ikeda, M.Takeuchi, S.Shinkai: "First Successful Molecular Design of an Artificial Lewis Oligosaccharide Binding System Utilizing Positive Homotropic Allosterism"J. Am. Chem. Soc.. 123(42). 10239-10244 (2001)

[Publications] A.Ikeda, M.Ayabe, S.Shinkai: "A Novel Self-assembled Porphyrin Polymer Constructed by a Pd(II)-Pyridine Interaction"Chem. Lett.. (11). 1138-1139 (2001)

[Publications] A.Ikeda, K.Sonoda, M.Ayabe, S.Tamarn, T.Nakashima, N.Kimizuka, S.Shinkai: "Gelation of Ionic Liquids with a Low Molecular-weight Gelator Showing Tgel above 100℃"Chem. Lett.. (11). 1154-1155 (2001)

[Publications] S.Tamaru, M.Nakamura, M.Takeuchi, S.Shinkai: "Rational Design of a Sugar-Assembled Porphyrin Gelator That Is Forced to Assemble into a One-Dimmensional Aggregate"Org. Lett.. 3(23). 3631-3634 (2001)

[Publications] S.Tamaru, M.Yamamoto, S.Shinkai, A.B.Khasanov, T.W.Bell: "A Hydrogen-Bonding That Binds Cationie Monosaccharides with High Affinity in Methanol"Chem. Eur. J.. 7(24). 5270-5276 (2001)

[Publications] M.Ikeda, A.Sugasaki, Y.Kubo, K.Sugiyasu, M.Takeuchi, S.Shinkai: "Porphyrin Polygons: A New Synthetic Strategy for Cyclic Porphyrin Oligomers Utilizing a Porphyrin Double Decker Structure"Chem. Lett.. (12). 1266-1267 (2001)

[Publications] H.Takashima, Y-Z.Hu, K.Sano, S.Shinkai, S.Oishi, I.Hamachi: "Supramolecular Construction of Covalently and Noncovalently-linked Photoinduced Electron Transfer Systems in Myoglobin Scaffold"Electrochemistry. 69(12). 942-945 (2001)

[Publications] 池田篤志: "3次元空孔を利用した精密分子認識素子の開発-巨大空孔を持つカプセル分子の構築を目指して-"化学と工業. 54(2). 160-163 (2001)

[Publications] 清中茂樹, 浜地格, 新海征治: "モジュール法を用いる糖鎖誘導体の合成とその分子集合超構造"表面. 39(5). 206-214 (2001)

[Publications] S, Shinkai, M.Ikeda, A.Sugasaki, M.Takeuchi: "Positive Allosteric Systems Designed on Dynamic Supramolecular Scaffolds: Toward Switching and Amplification of Guest Affinity and Selectivity"34(6). 494-503 (2001)

[Publications] 新海征治, 浜地格: "分子認識化学-人工ホストからバイオまで-"化学と工業. 54(6). 691-693 (2001)

[Publications] Tetsu YONEZAWA, Shin-ya ONOUE, Nobuo KIMIZUKA: "Self-Organized Superstructures of Fluorocarbon-Stabilized Silver Nanoparticles"Adv.Mater.. 13・2. 140-142 (2001)

[Publications] Tetsu YONEZAWA, Tetsu YONEZAWA, Nobuo KIMIZUKA: "Controlled Formation of Smaller Gold Narticles by the Use of Four-Chained Disulfide Stabilizer"Langmuir. 17・2. 271-273 (2001)

[Publications] Nobuo KIMIZUKA, Atsushi BABA, Toyoki KUNITAKE: "Supramolecular Holoenzymes. Activity Modulation of Endonuclease by the Use of Synthetic Bilayer Membranes as Regulatory Cofactors"J.Am.Chem. Soc.. 123・8. 1764-1765 (2001)

[Publications] Tetsu YONEZAWA, Shin-ya ONOUB, Nobuo KIMIZUKA: "Formation of Uniform Fluorinated Gold Nanoparticles and Their Highly Ordered Hexagonal Packing Monolayer"Langmuir. 17・8. 2291-2293 (2001)

[Publications] Takayoshi Kawasaki, Maki Tokuhiro, Nobuo Kimizuka, Toyoki Kunitake: "Hierarchical Self-Assembly of Chiral Complementary Hydrogen Bond Networks in Water. Reconstitution of Supramolecular Membranes"J. Am. Chem. Soc.. 123・28. 6792-6800 (2001)

[Publications] Tetsu Yonezawa, Kuniko Imamura, Nobuo Kimizuka: "Direct Preparation and Size Control of Palladium Nanoparticle Hydrosols by Water-Soluble Isocyanide Ligands"Langmuir. 17・16. 4701-4703 (2001)

[Publications] Nobuo Kimizuka, Takuya Nakashima: "Spontaneous Self-assembly of Glycolipid Bilayer Membranes in Sugar-philic Ionic Liquids and Formation of lonogels"Langmuir. 17・22. 6759-6761 (2001)

[Publications] Atsushi Ikeda, Kenshi Sonoda, Masatsugu Ayabe, Shun-ichi Tamaru, Takuya Nakashima, Nobuo Kimizukka, Seiji Shinkai: "Gelation of Ionic Liquids with a Low Molecular-weight Gelator Showing Tgel above 100℃"Chem. Lett.. 11. 1154-1155 (2001)

[Publications] D.Kawaguchi, K.Tanaka, A.Takahara, T.Kajiyama: "Surface Mobile layer of Polystyrene Film below Bulk Glass Transition temperature"Macromolecules. 34(18). 6164-6166 (2001)

[Publications] N.Satomi, K.Tanaka, A.Takahara, T.Kajiyama: "Effect of Internal Bulk Phase on Surface Viscoelastic Properties by Scanning Probe Microscopy"Macromolecules. 34(18). 6420-6423 (2001)

[Publications] N.Satomi, K.Tanaka, A.Takahara, T.Kajiyama: "Surface Molecular Motion of Monodisperse a, w-Diamino-Terminated and a, w-Dicaroxy-Tenninated Polystyrenes"Macromolecules. 34(25). 8761-8767 (2001)

[Publications] K.Kojio, K.Tanaka, A.Takahara, T.Kajiyama: "Novel Method to Prepare Organisilane Monolayers on Solid Substrate"Bull. Chem. Soc. Jpn.. 74(8). 1397-1401 (2001)

[Publications] D.Katsis, H.P.Chen, S.H.Chen, D.U.Kim, L.J.Lothberg, T.Tsutsui: "Circularly Polarized Photoluminescence from Gradient-Pitch Chiral-Nematic Films"Chem. Mater.. Vol.13. 643-647 (2001)

[Publications] T.Tsutsui, H.Yokogawa, M.Yokoyama, M.Yahiro, K.Kawano: "Doubling Coupling-Out Efficiency in Organic Light-Emitting Devices Using Thin Silica Aerogel Layer"Adv. Mater.. Vol.13 No.15. 1149-1152 (2001)

[Publications] S.Lee, T.Tsutsui, T.Nakamura: "Synthesis and Characterization of Oligo(9,9-Dihexyl-2,7-Fluorene Ethynylene)s: for Application as Blue Light-Emitting Diode"Organic Letters. Vol.3 No.13. 2001-2007 (2001)

[Publications] M.Yahiro, T.Tsutsui: "Influence of Device Configuration on External Quantum Efficiency in Organic Light-Emitting Devices"Mat. Res. Soc. Symp. Proc.. Vol.660. JJ5.27.1-6 (2001)

[Publications] K.Kojio, A.Takahara, T.Kajiyama: "Aggregation Structure and Surface Properties of Immobilized Fluoroalkylsilane and Their Mixed Monolayers"ACS Symp. Ser., Fluorinated Surfaces, Coatings, and Films. 787. 31-47 (2001)

[Publications] N.Torikai, M.Furusaka, H.Matsuoka, Y.Matsushita, M.Shibayama, A.Takahara, M.Takeda.S.Tasaki.H.Yamaoka: "A New Thermal Neutron Reflectometer for Free Surface at KENSr ARISA"Proceeding of 1 5th Meeting of the International Collaboration on Advanced Sources. 443-449 (2001)

[Publications] A.Takahara, Y.Hara, K.Kojio, T.Kajiyama: "Scanning Force Microscopic Study of Protein Adsorption on the Surface of Organosilane Monolayers Prepared by the Langmuir-Blodgett Method"Macromolecular Symposia. 167. 273-286 (2001)

[Publications] 4.K.Yamamoto, H.Otsuka, S.-I.Wada, A.Takahara: "Surface Modification of Aluminosilicate Nanofiber "Imogolite""Chemistry Letters. No.11. 1162-1163 (2001)

[Publications] Mariko ASO, Takeshi IKENO, Kouji NORIHISA, Masakazu TANAKA, Noboru KOGA, Hiroshi SUEMUNE: "2. Molecular Design of a New Class of Spin-Labeled Ribonucleosides with N-tert-Butylaminoxyl Radicals"J. Org. Chem.. 66・10. 3513-3520 (2001)

[Publications] Satoru KARASAWA, Noboru KOGA: "3 Photochemical Formations of Super High-spin Molecules Consisting of Carbenes and Metal ions in Frozen Solutions"Polyhedron. 20. 1387-1389 (2001)

[Publications] Takeyuki AKITA, Noboru KOGA: "Magnetic Properties After Irradiation of Poly(m-phenyleneethynylene) Having Diazo and Nitronylnitroxide Groups and Its Model Compounds"Polyhedron. 20. 1475-1477 (2001)

[Publications] Tetsuji ITOH, Kenji MATSUDA, Hiizu IWAMURA, Kenzi HORI: "The Ground Spin States ofTris[p-(N-oxyl-N-tert-butylamino)phenyl]amine, Methyl, and Borane. Prospects of Further Studies"J. Solid State Chem.. 159. 428-439 (2001)

[Publications] Motoko TANAKA, Yuko HOSOKOSHI, Ashot S.MARKOSYAN, Katsuya INGUE, Hiizu IWAMURA: "Metal (3d) Organic (2p)-hybnd Magnets Made of Mn(II) ions with Tris(aminoxyl) Radicals (R's) as Bridging Ligands. 2D Complexes [{Mn(hfac)2}3 R2]"Synthetic Metals.. 122. 463-470 (2001)

[Publications] Y.Takano, Y.Kitagawa, T.Onishi, Y.Yoshioka, K.Yamaguchi, N.Koga, H.Iwamura: "Theoretical Studies of Magnetic Interactions in Mn(II)(hfac)2 { di-(4-pyridyl)phenylcarbene} and Cu(LL)(hfac)2{di-(4-pyridyl)phenylcarbene}"J. Am. Chem. Soc.. 124・3. 450-461 (2002)

[Publications] Fukita, N; Ohba, M; Shiga, T; Okawa, H; Ajiro, Y: "Trinuclear Cu-<II>M^<II>Cu^<II> complexes of an oxamide/dioxime ligand and extension to a bimetallic magnetic compound"J. Chem. Soc.-Dalton Trans.. 1. 64-70 (2001)

[Publications] Mikami, S; Sugiura, K; Maruta, T; Maeda, Y; Ohba, M; Usuki, N; Okawa, H et al.: "Structure, optical and magnetic behaviour of meso-tetraphenylporphyrinatoiron(III) tetracyanoethenide, [Fe^<III>(TPP)]^+[TCNE]^-"J. Chem. Soc.-Dalton Trans.. 4. 448-455 (2001)

[Publications] Abe, K; Izumi, J; Ohba, M; Yokoyama, T; Okawa, H: "Dinuclear zinc complexes of phenol-based "end-off" compartmental ligands: Synthesis, structures and phosphatase-like activity"Bull. Chem. Soc. Jpn.. 74・1. 85-95 (2001)

[Publications] Arimura, K; Ohba, M; Yokoyama, T; Okawa, H: "Template synthesis of macrocyclic dinuclear Cull complexes and conversion into mononuclear complexes by site-selective copper elimination"Bull. Chem. Soc. Jpn.. 74・3. 495-503 (2001)

[Publications] Nakamura, Y; Yonemura, M; Arimura, K; Usuki, N; Ohba, M; Okawa, H: "Tetranuclear mixed-metal M_2^<II>Cu_2^<II> complexes derived from a phenol-based macrocyclic ligand having two N(amine)_2O_2 and two N(imine)_2O_2 metal-binding sites"Lnorg. Chem.. 40・15. 3739-3744 (2001)

[Publications] Kodera, M; Taniike, Y; Itoh, M; Tanahashi, Y; Shimakoshi, H; Kano, K; Ohba, M; Okawa, H.: "Synthesis, characterization, and activation of thermally stable m-1,2-peroxodiiron(III) complex"Inorg. Chem.. 40・19. 4821-4823 (2001)

[Publications] Ikeda, K; Ohba, M; Okawa, H: "Dinuclear Cu^<II> and Ni^<II> complexes of 3-formylsalicylic acid: cis/trans topology and extension of a cis-Cu_2(II) complex to a pentanuclear Cu^<II>Cu^<II>Mn^<II>Cu^<II>Cu^<II> complex"J. Chem. Soc.-Dalton Trans.. 20. 3119-3124 (2001)

[Publications] Arimura, K; Ohba, M; Yokoyama, T; Okawa, H: "Hydrolytic activity ofZn^<II>Zn^<II> and ZnBa^<II> complexes toward tri(p-nitrophenyl) phosphate and di(p-nitrophenyl) phosphate: A functional model of heterobimetallic phosphodiesterase"Chem. Lett.. 11. 1134-1135 (2001)

[Publications] Inoue, K; Imai, H; Ghalsasi, PS; Kikuchi, K; Ohba, M; Okawa, H; Yakhmi, JV: "A three-dimensional ferrimagnet with a high magnetic transition temperature (T_c) of 53 K based on a chiral molecule"Angew. Chem. -Int. Edit.. 40・22. 4242-4245 (2001)

[Publications] Inoue, K; Ohba, M; Okawa, H.: "Heterodinuclear M^<II>N^<II> (M=Co, Ni, Cu, Zn) Complexes a Macrocyclic Compartmental Ligand. Anomaloous EPR of Cu^<II>Ni^<II> Complex by Coordination of 1 -Methylimidazole"Bull. Chem. Soc. Jpn.. 75・1. 99-107 (2002)

[Publications] Yonemura, M; Arimura, K; Inoue, K; Usuki, N; Ohba, M; Okawa, H.: "Coordination-Position Isomeric M^<II>Cu^<II> and Cu^<II>M^<II>(M=Co, Ni, Zn) Complexes Derived from Macrocyclic Compartmental Ligands"Inorg. Chem.. 41・3. 582-589 (2001)

[Publications] T.D.James, S.Shinkai: "Artificial Receptors as Chemosensors for Carbohydrates"Top. Curr. Chem.. 218. 159-200 (2001)

[Publications] Shinichiro NAKAMURA: "Multiphoton Gated Photochromic Reaction in a Diarylethene Derivative"Journal of American Chemical Society. 123,4. 753-754 (2001)

[Publications] Masato FUKUDOME: "Photochromism of a Dithienylethene Having Diphenylamido Side Groups in the Bulk Amorphous Phase"Chemistry Letters. 2001,1. 70-71 (2001)

[Publications] Tuyoshi FUKAMINATO: "Three Dimensional Optical Erasable Optical Memory using a Photochromic Diarylethene Single Crystal as the Recording medium"Procceedings of Japanese Academy. B77,2. 30-35 (2001)

[Publications] Masahiro IRIE: "Reversible Surface Morphology Chanes of a Photochromic Diarylethene Single Crystal by Photoirrdiation"Science. 291. 1769-1772 (2001)

[Publications] Kenji MATSUDA: "Single-crystalline Photochromism of a Liner Coordination Polymer Composed of 1,2-bis[2-methyl-5-(4-pyridyl)-3-thienyl]perfluoro cyclopentene and bis(hexafluoroacetylacetonato)zinc(II)"Chemical Communications. 363-364 (2001)

[Publications] Tsuyoshi KAWAL: "A Photoresponsive Laser Dye Containing Photochromic Dithienylethene Units"Chemical Communications. 711-712 (2001)

[Publications] Jerome CHAUVIN: "Refractive Index Change of an Amorphous Bisbenzothienylethene"Japanese Journal of Applied Physics. 40,4A. 2518-2522 (2001)

[Publications] Kingo UCHIDA: "Photochromism of DiarAethenes on Porous Aluminum Oxide: Fatigue Resistance and Redox Potentials of the Photochromism"Chemistry Letters. 4. 366-367 (2001)

[Publications] Kingo UCHIDA: "Substituent Effect on the Photochromic Reactivity of Bis(2-thienyl) perfluorocyclopentenes"Tetrahedron. 57. 4559-4565 (2001)

[Publications] Kenji MATSUDA: "Photoswitching of Intramolecular Magnetic Interaction Using Photochromic Diarylethene Spin Coupler: Introduction of Thiophene Spacer"Chemistry Letters. 2001,5. 436-437 (2001)

[Publications] Atsuhiro OSUKA: "Synthesis and Photoisomenzation of Dithienylethene-Bridged Diporphyrins"Journal of Organic Chemistry. 66,11. 3913-3923 (2001)

[Publications] Tsuyoshi TSUJIOKA: "Two-photon Absorption in Photochromic Layer with Highly Localized Coherent Photons"Optical Review. 8,3. 206-207 (2001)

[Publications] Katsunori SHIBATA: "Extraordinarily Low Cycloreversion Quantum Yields of Photochromic Diarylethenes with Methoxy Substituents"Chemistry Letters. 7. 618-619 (2001)

新海征治九州大学, 大学院・工学研究院, 教授 (20038045)