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1999 Fiscal Year Final Research Report Summary

Adsorption heat pump using porous materials - Development of environmental friendly energy system

Research Project

Project/Area Number 09355026
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 触媒・化学プロセス
Research InstitutionNagoya University

Principal Investigator

HATTORI Tadashi  Nagoya University, Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (50023172)

Co-Investigator(Kenkyū-buntansha) SATSUMA Atsushi  Nagoya University, Graduate School of Engineering, Associate Professor, 大学院・工学研究科, 助教授 (00215758)
KUNO Satoru  Nagoya University, Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (70153319)
HASATANI Masanobu  Nagoya University, Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (50021788)
WATANABE Fujio  Nagoya University, Graduate School of Engineering, Research Associate, 大学院・工学研究科, 助手 (70109312)
SAITOH Teruyukii  Nagoya University, Graduate School of Engineering, Assistant Professor, 大学院・工学研究科, 講師 (30281067)
Project Period (FY) 1997 – 1999
Keywordsenvironmental friendly energy system / Adsorption heat pump / Chemical heat pump / porous material / adsorption / porous silica / local energy system / comfortableness
Research Abstract

In this project, adsorption heat pump (AHP) technology was investigated by the researchers in the field of chemistry, chemical engineering and architecture. The aim of this project is (1) increase in the output of AHP system, (2) the promotion of heat and mass transfer diffusion in the AHP module, and (3) the optimization and controlling technology of the effective system for use of cold heat energy. As for the system design, the alcohol/activated carbon absorption heat pump (AHP) with a disk-module -type absorber was also proposed for producing of high quality and high power cold heat energy. The heat and mass transfer characteristics in adsorption and regeneration processes of the AHP operation were experimentally investigated. It was found that the adsorption/regeneration cycle period was about 10 times shorter than that of the packed-bed-type adsorber of SAC. The equilibrium adsorption capacity per weight was reduced by SAC modulation, but the cold heat output per unit time of the proposed AHP system was enlarged. The present system works well with regeneration temperatures of around 350 K and readily generates cold heat at around 270 K. It is concluded that AHP fabricated with the proposed disk-module adsorber units can be used as a compact refrigeration unit for generating cold heat energy below 273 K by using a low temperature waste heat energy source. Secondly, the adsorption properties of porous silica materials, i.e., zeolites, FSM-16, MCM-41 and amorphous silica, were characterized by various physico-chemical techniques. It was found that they have radical sites which is active for some chemical reactions on their surfaces. Finally, the local heat energy system, including offices, residences and stores, with AHP drove by cold heart from factories as heat sources was simulated. The effectiveness of the use of AHP for the local energy system was clarified.

  • Research Products

    (28 results)

All Other

All Publications (28 results)

  • [Publications] 渡辺藤雄、架谷昌信: "吸着ヒートポンプの吸着剤充填吸着器内熱・物質移動"伝熱研究. 36巻140号. 12-17 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 窪田光宏、松田仁樹、架谷昌信: "ヒートポンプ技術の概要-化学反応式ヒートポンプを中心に-"燃料及燃焼. 64巻3号. 12-21 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M. Kanamori, M. Hiramatsu, K. Katsurayama, F. Watanabe, H, Matsuda, M. Hasatani: "Production of Cold Heat Energy by Alcohol/Activated Carbon Adsorption Heat Pump with a Disk-Module-Type Adsorber"J. Chem. Eng. Japan. 30巻3号. 434-439 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H. Yoshida, T. Yoshida, T. Tanaka, F. Funabiki, S. Yoshida, T. Abe, K. Kimura, and T. Hattori: "Mg K-edge XAFS Study of Silica-Magnesia Systems"J. Phys. IV. 7. C2-900-912 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H. Yoshida, K. Kiumura, Y. Inaki and T. Hattori: "Catalytic Activity of FSM-16 for Photometathesis of Propene"Chem. Commun.. 1997. 129-130 (1997)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 金森道人、葛山弘一、渡辺藤雄、松田仁樹、架谷昌信、辻本聡一郎、栢原義孝: "平板状スーパー活性炭/伝熱版一体型吸着器で構成されるエタノール系吸着ヒートポンプの冷熱生成特性"化学工学論文集. 24巻1号. 131-141 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 金森道人、平松正義、柴田貴之、渡辺藤雄、松田仁樹、架谷昌信: "低相対水蒸気圧下におけるゼオライト/水系の吸着平衡と吸着蓄熱に関する実験的検討"化学工学論文集. 24巻2号. 243-247 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T. Hattori and S. Kito: "Neural Networks in Catalyst Design : An Art Turning into a Science"Proc. 15th World Petroleum Congress. 15. 783-790 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 鬼頭繁治、服部忠: "触媒化学におけるニューラルネットワークの利用"触媒. 40号3号. 169-175 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K. Nishi, K. Shimizu, M. Takamatsu, H. Yoshida, A. Satsuma, T. Tanaka, S. Yoshida and T. Hattori: "Deconvolution Analysis of Ga K-Edge XANES for Quantification of Gallium Coordinations in Oxide Environment"J. Phys. Chem. B. 102(50). 10190-10195 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H. Yoshida, C. Murata and T. Hattori: "Photooxidation of Propene to Propene Oxide by Molecular Oxygen over Zinc Oxide Dispersed on Silica"Chem. Lett.. 1999. 901-902 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 久野覚: "温熱環境における快適性-Comfortとpleasantness"The Japanese Journal of Psychonomic Science. Vol.18, No.1. 102-106 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] E. Yamamoto, K. Katsurayama, F. Watanabe, H. Matsuda, M. Hasatani: "Heat and Mass Transfer Characteristics in Adsorption of Water Vapor For Silica Gel Packed Bed Asdorber"J. Chem. Eng. Japan. 33(1). 12-18 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] A. Shichi, A. Satsuma, S. Komai and T. Hattori: "Influence of intracrystalline diffusion on the selective catalytic reduction of NO by hydrocarbons Cu-MFI zeolite"Appl. Catal. B. 24. 97-105 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] F. Watanabe, M. Hasatani: "Heat and Mass Transfer in Packed Bed Adsorber of Adsorption Heat Pump"Den-netsu Kenkyu. 36(140). 12-17 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kubota, F. Watanabe, M. Hasatani: "Outline of Heat Pump -Focusing on Reaction Heat Pump-"Fuel and Combustion. 64(3). 12-21 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kanamori, M. Hiramatsu, K. Katsuyama, F. Watanabe, H. Matsuda, M. Hasatani: "Production of Cold Heat Energy by Alcohol/Activated Carbon Adsorption Heat Pump with a Disk-Module-Type Adsorber"J. Chem. Eng. Japan. 30(3). 434-439 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Yoshida, T. Yoshida, T. Yoshida, T. Tanaka, F. Funabiki, S. Yoshida, T. Abe, K. Kimura, and T. Hattori: "Mg K-edge XAFS Study of Silica-Magnesia Systems"J. Phys. IV. 7. C2-900-C2-912 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Yoshida, K. Kimura, Y. Inaki and T. Hattori: "Catalytic Activity of FSM-16 for Photometathesis of Propene"Chem. Commun.. 129-130 (1997)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kanamori, R. Fujisawa, F. Watanabe, H. Matsuda, M. Hasatani, M. Hisamatsu: "Experimental Study of Adsorption Equilibrium of Water on Zeolite and Adsorption Heat Storage under Low Relative Vapor Pressure"Kagakukougaku Ronbunshu. 24(2). 243-247 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Kanamori, R. Fujisawa, F. Watanabe, H. Matsuda, M. Hasatani, M. Hisamatsu: "Numerical Analysis of Heat and Mass Transfer Characteristics of Ethanol Adsorption Heat Pump Composed of Plate Super Activated Carbon (PSAC) and Heat Transfer Sheet"Kagakukougaku Ronbunshu. 24-6. 845-850 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Hattori and S. Kito: "Neural Networks in Catalyst Design : An Art Turning into a Science"Proc. 15ィイD1thィエD1 World Petroleum Congress. 783-790 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Kito and T. Hattori: "Application of Neural Networks on Catalysis"Syokubai. 40(3). 169-175 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Nishi, K. Shimizu, M. Takamatsu, H. Yoshida, A. Satsuma, T. Tanaka, S. Yoshida and T. Hattori: "Deconvolution Analysis of Ga K-Edge XANES for Quantification of Gallium Coordinations in Oxide Environment"J. Phys. Chem. B. 102(50). 10190-10195 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Yoshida, C. Murata and T. Hattori: "Photooxidation of Propene to Propene Oxide by Molecular Oxygen over Zinc Oxide Dispersed on Silica"Chem. Lett.. 901-902 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Kuno: "Comfort on Thermal Environment -Comfort and Pleasantness"The Japanese Journal of Psychonomic Science. Vol.18, No.1. 102-106 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] E. Yamamoto, K. Katsurayama, F. Watanabe, H. Matsuda, M. Hasatani: "Heat and Mass Transfer Characteristics in Adsorption of Water Vapor for Silica Gel Packed Bed Adsorber"J. Chem. Eng. Japan. 33(1). 12-18 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] A. Shichi, A. Satsuma, S. Komai and T. Hattori: "Influence of intracrystalline diffusion on the selective catalytic reduction of NO by hydrocarbons over Cu-MFI zeolite"Appl. Catal. B. 24. 97-105 (2000)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2001-10-23  

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