1999 Fiscal Year Final Research Report Summary
Systemization of Palladium Complex Catalysts and Their Application to Organic Synthesis
| Project/Area Number |
09650962
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Synthetic chemistry
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| Research Institution | Tottori University |
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Principal Investigator |
KIJI Jitsuo Tottori University, Faculty of Engineering, Professor, 工学部, 教授 (60026002)
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| Co-Investigator(Kenkyū-buntansha) |
TSUJI Jiro Tokyo Institute of Technology, Emeritus, 名誉教授 (00016685)
OKANO Tamon Tottori University, Faculty of Engineering, Associate Professor, 工学部, 助教授 (20112104)
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| Project Period (FY) |
1997 – 1999
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| Keywords | Palladium catalyst / Carbonylation / Olefin-CO copolymerization / Bis-π-allylpalladium |
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| Research Abstract |
The purpose of the present study was to develop palladium-catalyzed synthetic reactions and to elucidate their reaction mechanisms.
1 Derivatives of 2-butyne-1, 4-diol were carbonylated in ethanol in the presence of Pd-phosphine catalyst. Its carbonate of ethyl chloroformate gave bis(methylene)butanedioate in a high yield.
2 Thienyl-substituted 2-butyne-1, 4-diols were carbonylated in benzene in the presence of palladium acetate and iodine to give photochromic bisthienylfulgides in one-pot.
3 Palladium- and copper-catalyzed copolymerizations of carbon monoxide with ethylene or styrene were investigated. Pyrolysis-GC revealed that the polymers obtained were of alternating structures.
4 Allylation of pronucleophiles, and telomerization and cocyclization of buta-diene were investigated under neutral conditions. Their reaction mechanisms were discussed from a viewpoint of amphiphilic nature of the bis-π-allylpalladium intermediate.
5 Styrenes, stilbenes, and poly(phenylene vinylene)s were synthesized by the Heck reaction of ethylene with haloarenes.
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