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2001 Fiscal Year Final Research Report Summary

New Protium Function

Research Project

Project/Area Number 10148106
Research Category

Grant-in-Aid for Scientific Research on Priority Areas (A)

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionKyushu University

Principal Investigator

HAYASHI Yasunori  Graduate School of Engineering, Professor, 大学院・工学研究科, 教授 (80010940)

Co-Investigator(Kenkyū-buntansha) YUGAMI Hiroo  Tohoku University, Graduate School of Engineering, Associate Professor, 大学院・工学研究科, 助教授 (60192803)
Project Period (FY) 1998 – 2001
Keywordsprotium / hydrogen / transparent conductor / oxide / nitride / proton conduction / strain super lattice / low dimensional super structure
Research Abstract

In order to develop a new function of materials induced by hydrogen incorporation, thin films of nitrides, oxides and metal multilayers were investigated in relation to the optical and electrical properties. Investigations on proton conduction at middle-high temperatures were also carried out in strained super lattice films and low-dimensional artificial structures of perovskite type oxides.
The effects of hydrogen incorporation on electrical conduction of AlN and CuN were appeared differently depending on the difference in the stoichiometry of the nitrides. Electrical conductivities of Sn and Ge mixed oxides and ZnO films were increased more than 4 orders of magnitude without loosing their transparency for visible light.
Strain distribution in super-structures of SrCeO_3/SrZrO_3 modifies the proton conduction. The mutual distance between oxide ions around a proton was revealed to be a critical factor for the proton conduction. Nano-scale 2 dimensional structures of perovskite type oxides were fabricated for further investigation of proton conduction at the interface between electrodes and solid electrolytes.

  • Research Products

    (35 results)

All Other

All Publications (35 results)

  • [Publications] K.Kandasamy: "Hydrogen-induced Changes of the Magnetic Properties of Copper-cobalt Multilayers"J. Alloys Comp.. 282. 23-31 (1998)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K.Kandasamy: "Hydrogen-induced Changes of Magnetic Properties of Iron-chromium Multilayers"J. Alloys Comp.. 288. 13-24 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ishikawa: "Effect of Hydrogen Implantation on the Electrical Properties of Cu-N Thin Films"Proceedings of the 5th Korea-Japan Joint Sumposium '99 on Hydrogen Energy. 174-180 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Hayashi: "Hydrogen Ion Implantation Effect on the Magnetic Properties of Metallic Multilayerd Films"J. Alloys Comp.. 293-295. 463-467 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Kawada: "Oxygen Isotope Exchange with a Dense La_<0.6>Sr_<0.4>CoO_<3-δ> Electrode on a Ce_<0.9>Ca_<0.1>O_<1.9> Electrolyte"Solid State Ionics. 121. 271-279 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Sata: "Studies on the Superlattice of Perovskite-type Proton Conductors Synthesized by Pulsed Laser Ablation"Solid State Ionics. 121. 321-327 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] N.Sata: "Proton Conduction in Mixed Perovskite-type Oxides"Solid State Ionics. 125. 383-387 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.OTAKE: "Nonstoichiometry of Zr_<0.164> Ce_<0.654> Y_<0.182>O_<1.91-δ>"Electrichemistry. 68. 451-454 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Otake: "Ce^<3+> Concentration in ZrO_2-CeO_2-Y_2O_3 System Studied by Electronic Raman Scattering"Solid State Ionics. 135. 663-667 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Naito: "Oxygen Transport Properties in ZrO_2-CeO_2-Y_2O_3 by SIMS Analysis"Solid State Ionics. 135. 669-673 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Yugami: "Structural Properties of SrCeO_3/SrZrO_3 Proton Conducting Superlattices"Solid State Ionics. 136-137. 203-207 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Arita: "Effects of Hydrogen Introduction on Electrical and Optical Properties of Cd-doped Ge Oxide and Zn Oxide Thin Films"The Fourth Pacific Rim Proceedings of International Conference on Advanced Materials and Processing. PRICM4. 2841-2844 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T.Ishikawa: "Hydrogen Implantation Effects on the Electrical and Optical Propertied of Metal Nitride Thin Films"The Fourth Pacific Rim Proceedings of International Conference on Advanced Materials and Processing. PRICM4. 2837-2840 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Hayashi: "Modification of Electrical Properties of Metal Oxide and Nitride Thin Films by Protium Inclusion"Progress In Hydrogen Treatment of Materials, Donetsk-2001-Coral Gables. 67-72 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Matsuo: "Local Proton Dynamics in Perovskite-type Protonic Conductors by Spectral Hole Burning Spectroscopy"Physical Review B. 64. 024302-1-024302-6 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] Y.Hayashi: "Modification of Electrical and Optical Properties of Metal Nitride Thin Films by Hydrogen Inclusion"J. Alloys Comp.. 330-332. 348-351 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Yamaguchi: "Operation of Hudrogen-air Fuel Cells Based on Proton Conducting Oxides and Hydrogen Strage Metals"Journal of Alloys and Compounds. 330-331. 911-915 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] H.Yugami: "Fabrication of proton conductors with nano-structured surface by porous alumina membrane mask"Solid State Ionics. 154-155. 693-697 (2002)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] K. Kandasamy: "Hydrogen-induced Changes of the Magnetic Properties of Copper-cobalt Multilayers"J. Alloys Comp.. 282. 23-31 (1998)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] K. Kandasamy: "Hydrogen-induced Changes of Magnetic Properties of Iron-chromium Multilayers"J. Alloys Comp.. 288. 13-24 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Tsutomu Ishikawa: "Effect of Hydrogen Implantation on the Electrical Properties of Cu-N Thin Films"Proceedings of the 5th Korea-Japan Joint Sumposium '99 on Hydrogen Energy, Yusong Taejon, Korea, November 26. 174-180 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Hayashi: "Hydrogen Ion Implantation Effect on the Magnetic Properties of Metallic Multilayerd Films"J. Alloys Comp.. 293-295. 463-467 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Kawada: "Oxygen Isotope Exchange with a Dense La_<0.6>Sr_<0.4>CoO_<3-ヲト> Electrode on a Ce_<0.9>Ca_<0.1>O_<1.9> Electrolyte"Solid State Ionics. 121. 271-279 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N. Sata: "Studies on the Superlattice of Perovskite-type Proton Conductors Synthesized by Pulsed Laser Ablation"Solid State Ionics. 121. 321-327 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] N. Sata: "Proton Conduction in Mixed Perovskite-type Oxides"Solid State Ionics. 125. 383-387 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Otake: "Ce^<3+> Concentration in ZrO_2-CeO_2-Y_2O_3 System Studied by Electronic Raman Scattering"Solid State Ionics. 135. 663-667 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Naito: "Oxygen Transport Properties in ZrO_2-CeO_2-Y_2O_3 by SIMS Analysis"Solid State Ionics. 135. 669-673 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Yugami: "Structural Properties of SrCeO_3/SrZrO_3 Proton Conducting Superlattices"Solid State Ionics. 136-137. 203-207 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Arita: "Effects of Hydrogen Introduction on Electrical and Optical Properties of Cd-doped Ge Oxide and Zn Oxide Thin Films"The Fourth Pacific Rim Proceedings of International Conference on Advanced Materials and Processing (PRICM4). 2841-2844 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] T. Ishikawa: "Hydrogen Implantation Effects on the Electrical and Optlcal Propertied of Metal Nitride Thin Films"The Fourth Pacific Rim Proceedings of International Conference on Advanced Materials and Processing (PRICM4). 2837-2840 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Hayashi: "Modification of Electrical Properties of Metal Oxide and Thin Films by Protium Inclusion"Progress In Hydrogen Treatment of Materials, Donetsk-2001-Coral Gables. 67-72 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Matsuo: "Local Proton Dynamics in Perovskite-type Protonic Conductors by Spectral Hole Burning Spectroscopy"Physical Review B. 64 (2). 024302-1-024302-6 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] Y. Hayashi: "Modification of Electrical and ptical Properties of Metal Nitride Thin Films by Hydrogen Inclusion"J. Alloys Comp.. 330-332. 348-351 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Yamaguchi: "Operation of Hydrogen-air Fuel Cells Based on Proton Conducting Oxides and Hydrogen Strage Metals"Journal of Alloys and Campounds. 330-331. 911-915 (2002)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] H. Yugami: "Fabrication of proton conductors with nano-structured surface by alumina membrane mask"Solid State Ionics. 154-155. 693-697 (2002)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2004-04-14  

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