1998 Fiscal Year Annual Research Report

「集積型金属錯体」研究の総括

Research Project

Project/Area Number	10149101
Research Category	Grant-in-Aid for Scientific Research on Priority Areas (A)
Research Institution	Tohoku University
Principal Investigator	伊藤翼東北大学, 大学院・理学研究科, 教授 (90007328)
Co-Investigator(Kenkyū-buntansha)	北川進京都大学, 大学院・工学研究科, 教授 (20140303) 加藤礼三東京大学, 物性研究所, 教授 (80169531) 山口兆大阪大学, 大学院・理学研究科, 教授 (80029537) 山本隆一東京工業大学, 資源化学研究所, 教授 (10016743) 大川尚士九州大学, 理学部, 教授 (00037219)
Keywords	集積型金属錯体 / 金属クラスター錯体 / 超分子 / 錯体集合体 / 分子集合体 / 混合原子価錯体 / 協同効果 / 多重機能
Research Abstract	(1) 総括班会議の開催:研究方針,研究実施計画,予算配分・執行に関する打ち合わせ. 第1回(仙台,平成10年6月17日),第2回(京都,平成10年6月17日),第3回(福岡,平成11年1月22日) (2) 研究会の開催 (a) 平成10年度スタートアップ会議(仙台,平成10年6月15-17日):研究実施班員82名全員による研究計画概要の発表. (b) 国際シンポジウム"Recent Development and Future Prospects on Metal-Assembled and Metal -ClusterCompounds"(岡崎,平成10年10月5-7日):外国人9名,日本人10名による講演,ポスター発表58件.参加者,7か国外国人24名を含む126名. (c) A01/A02合同班会試(京都,平成10年11月20-21日):「集積型金属錯体の合成」研究会. (d) 公開シンポジウム平成10年度研究成果報告会(福岡,平成11年1月21-22日):2件の招待講演を含む11件の講演,並びに研究実施班員全員の研究成果報告発表. (3) 出版物の発行 (a) 広報,ニュースレター:第1号(班員名簿・班員の研究概要,平成10年6月),第2号(ニュースレター,平成10年9月),第3号(ニュースレター,平成11年1月). (b) 講演要旨集:国際シンポジウム"Recent Development and Future Prospects on Metal-Assembled andMetal-Cluster Compounds"要旨集(平成10年10月),A01/AO2合同班会議講演要旨集(平成10年11月),公開シンポジウム要旨集(平成11年1月) (c) 平成10年度研究成果報告書(平成11年2月)

Research Products
(18 results)

All Other

All Publications (18 results)

[Publications] 伊藤翼: "Complexed Bridging Ligand,{M(bpca)_2}(M=Mn(II) or Fe(II):Hbpca=bis(2-pyridylcarbonyl)amine).as a Building Block for Linear Trinuclear Complexes" J.Chem.Soc.Dalton Trans.3351-3352 (1998)
[Publications] 伊藤翼: "Self-assembling Tetranuclear Copper(II) Complex of a Bis-bidentate Schiff Base:Double-helical Structure Induced by Aromatic π…π and CH…π interactions" J.Chem.Soc.,Chem.Commun.63-64 (1998)
[Publications] 伊藤翼: "Kinetic Study on the Substitution of Dimethylacetamide for the Terminal Aqua Ligands in the Trinoclear Chromium(III) Complexes [Cr_3(μ_3-O)(μ-RCO_2)_6(H_2O)_3]^+(R=H,CH_3,CH_3CH_2,CH_2Cl,CHCl_2,CH_3OCH_2,(CH_3)_3C,CH_2ClCCH_2,(CH_3CH_2)_2CH).Elucidation of the Mechanism from the Activation Volumes and the Sybstituent Effects of Bridging Carboxylate Ligands" Inorg.Chem.37. 3779-3784 (1998)
[Publications] 伊藤翼: "A Short Platinum to Silver Dative Bond and its Application to the Construction of Extended Structures:Syntheses and Structures of Ag_2[Pt(ox)_2]・2H_2O and [Ag_2H_2O)]_2[Ag_2(CF_2SO_3)_4][Pt(acac)_2]_2" J.Chem.Soc.Dolton Trans.inpress (1998)
[Publications] 大川尚士: "Bimetallic Assemblies [Ni(L)_2]_3[Fe(CN)_6]X_2(L=en,tn:X=PF_6-,ClO_4-)with a 3-D Network Extended through Fe^<II>-CN-Ni^<II> Linkages." Inorg.Chem.37. 842-848 (1998)
[Publications] 大川尚士: "Structure and Magnetic Properties of One-Dimensional PPh_4[Ni(pn)_2][M(CN)_6]・H_2O(M=Fe,Cr,Co)Bimetallic Assemblies." Inorg.Chem.37. 3349-3354 (1998)
[Publications] 大川尚士: "Copper(II) Compounds Extended by 5-Carboxysalicylaldehyde and Its Schiff Bases: Interplay of Two Metal-Binding Sites and Intermolecular Stacking Contributing to Their Netwok and Bulk Structures." Bull.Chem.Soc.Jpn.71. 2365-2373 (1998)
[Publications] 大川尚士: "Heterodinuclear Metal Complexes of Phenol-based Compartmental Macrocycles." Coord.Chem.Rev.174. 51-75 (1998)
[Publications] 山本隆一: "Preparation of Poly(diphenylamine-4,4′-diyl)and Related Random Copolymers by Organometallic Polycondensation. Electrical,Electrochemical,and Optical Properties." Macromolecules. 31. 988-993 (1998)
[Publications] 山本隆一: "Preparation of π-Conjugated poly(hydroquinone-2,5-diyl)and Poly(p-benzoquinone-2,5-diyl)and Their Electrochemical Behavior." Macromolecules. 31. 2683-2685 (1998)
[Publications] 山本隆一: "New Type of Polymer Containing 1,1′-Ferrocenylene Unit in π-Conjugated Main Chain. Preparation and Redox Behavior." Inorg.Chim.Acta. 269. 310-312 (1998)
[Publications] 山本隆一: "Extensive Studies on π-Stacking of Poly(3-alkylthiophene-2,5-diyls and Poly(4-alkylthiazole-2,5-diyl)s by Optical Spectgroscopy. NMR Analysis,Light Scattering Analyss,and X-ray Crystallography." J.Am.Chem.Soc.120. 2047-2058 (1998)
[Publications] 山口兆: "Quantum Dynamics of Linear Molecular Aggregates." Int.J.Quantum.Chem.70. 77-87 (1998)
[Publications] 山口兆: "Dependence of a Polarizability on Field Intensity and Size." J.Phys.Chem.A.102. 6807-6811 (1998)
[Publications] 山口兆: "Quasiprobability Distribution Dynamics." Chem.Phys.Lett.295. 317-327 (1998)
[Publications] 山口兆: "Electron-photon Field Dynamics." Chem.Phys.Lett.295. 328-336 (1998)
[Publications] 加藤礼三: "A New Molecular Superconductor β′-Et_2Me_2P[Pd(dmit)_2]_2(dmit=2-thioxo-1,3-dithiole-4,5-dithiolate)." Solid State Commun.105. 561-565 (1998)
[Publications] 加藤礼三: "Multicomponent Molecular Conductors with Supramolecular Assembly: Iodine-Containing Netural Molecules as Building Blocks." J.Am.Chem.Soc.120. 5905-5913 (1998)

1998 Fiscal Year Annual Research Report

「集積型金属錯体」研究の総括

Principal Investigator

伊藤 翼 東北大学, 大学院・理学研究科, 教授 (90007328)

Research Products

[Publications] 伊藤翼: "Complexed Bridging Ligand,{M(bpca)_2}(M=Mn(II) or Fe(II):Hbpca=bis(2-pyridylcarbonyl)amine).as a Building Block for Linear Trinuclear Complexes" J.Chem.Soc.Dalton Trans.3351-3352 (1998)

[Publications] 伊藤翼: "Self-assembling Tetranuclear Copper(II) Complex of a Bis-bidentate Schiff Base:Double-helical Structure Induced by Aromatic π…π and CH…π interactions" J.Chem.Soc.,Chem.Commun.63-64 (1998)

[Publications] 伊藤翼: "A Short Platinum to Silver Dative Bond and its Application to the Construction of Extended Structures:Syntheses and Structures of Ag_2[Pt(ox)_2]・2H_2O and [Ag_2H_2O)]_2[Ag_2(CF_2SO_3)_4][Pt(acac)_2]_2" J.Chem.Soc.Dolton Trans.inpress (1998)

[Publications] 大川尚士: "Bimetallic Assemblies [Ni(L)_2]_3[Fe(CN)_6]X_2(L=en,tn:X=PF_6-,ClO_4-)with a 3-D Network Extended through Fe^<II>-CN-Ni^<II> Linkages." Inorg.Chem.37. 842-848 (1998)

[Publications] 大川尚士: "Structure and Magnetic Properties of One-Dimensional PPh_4[Ni(pn)_2][M(CN)_6]・H_2O(M=Fe,Cr,Co)Bimetallic Assemblies." Inorg.Chem.37. 3349-3354 (1998)

[Publications] 大川尚士: "Copper(II) Compounds Extended by 5-Carboxysalicylaldehyde and Its Schiff Bases: Interplay of Two Metal-Binding Sites and Intermolecular Stacking Contributing to Their Netwok and Bulk Structures." Bull.Chem.Soc.Jpn.71. 2365-2373 (1998)

[Publications] 大川尚士: "Heterodinuclear Metal Complexes of Phenol-based Compartmental Macrocycles." Coord.Chem.Rev.174. 51-75 (1998)

[Publications] 山本隆一: "Preparation of Poly(diphenylamine-4,4′-diyl)and Related Random Copolymers by Organometallic Polycondensation. Electrical,Electrochemical,and Optical Properties." Macromolecules. 31. 988-993 (1998)

[Publications] 山本隆一: "Preparation of π-Conjugated poly(hydroquinone-2,5-diyl)and Poly(p-benzoquinone-2,5-diyl)and Their Electrochemical Behavior." Macromolecules. 31. 2683-2685 (1998)

[Publications] 山本隆一: "New Type of Polymer Containing 1,1′-Ferrocenylene Unit in π-Conjugated Main Chain. Preparation and Redox Behavior." Inorg.Chim.Acta. 269. 310-312 (1998)

[Publications] 山本隆一: "Extensive Studies on π-Stacking of Poly(3-alkylthiophene-2,5-diyls and Poly(4-alkylthiazole-2,5-diyl)s by Optical Spectgroscopy. NMR Analysis,Light Scattering Analyss,and X-ray Crystallography." J.Am.Chem.Soc.120. 2047-2058 (1998)

[Publications] 山口兆: "Quantum Dynamics of Linear Molecular Aggregates." Int.J.Quantum.Chem.70. 77-87 (1998)

[Publications] 山口兆: "Dependence of a Polarizability on Field Intensity and Size." J.Phys.Chem.A.102. 6807-6811 (1998)

[Publications] 山口兆: "Quasiprobability Distribution Dynamics." Chem.Phys.Lett.295. 317-327 (1998)

[Publications] 山口兆: "Electron-photon Field Dynamics." Chem.Phys.Lett.295. 328-336 (1998)

[Publications] 加藤礼三: "A New Molecular Superconductor β′-Et_2Me_2P[Pd(dmit)_2]_2(dmit=2-thioxo-1,3-dithiole-4,5-dithiolate)." Solid State Commun.105. 561-565 (1998)

[Publications] 加藤礼三: "Multicomponent Molecular Conductors with Supramolecular Assembly: Iodine-Containing Netural Molecules as Building Blocks." J.Am.Chem.Soc.120. 5905-5913 (1998)

伊藤翼東北大学, 大学院・理学研究科, 教授 (90007328)