• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to project page

2001 Fiscal Year Final Research Report Summary

Selective Synthesis of Fine Chemicals in Controlled Nano-Spaces as Reaction Rooms

Research Project

Project/Area Number 11555215
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section展開研究
Research Field 触媒・化学プロセス
Research InstitutionTeikyo University of Science and Technology

Principal Investigator

NAMBA Seitaro  Teikyo University of Science and Technology, Faculty of Science and Engineering, Professor, 理工学部, 教授 (80114883)

Co-Investigator(Kenkyū-buntansha) HORITA Yoshiharu  Nippon Steel Chemical Co., Ltd., Research and Development Laboratories, Director, 総合研究所, 取締役所長
KUGITA Tsuyoshi  Teikyo University of Science and Technology, Faculty of Science and Engineering, Assistant Professor, 理工学部, 講師 (80225127)
ONAKA Makoto  The University of Tokyo, Graduate School of Arts and Science, Associate Professor, 大学院・総合文化研究科, 助教授 (10144122)
Project Period (FY) 1999 – 2001
KeywordsSolid acid catalyst / Mesoporous Molecular Sieve / MCM-41 / SBA-15 / Diels-Alder reaction / Friedol-Crafts reaction / Nano-space
Research Abstract

The replacement of homogeneous catalysts by heterogeneous catalysts is very important in practical productions of fine chemicals from the standpoint of the so-called "zero-emission" or "green chemistry". In the present study we find some Al-introduced mesoporous molecular sieves "MCM-41" catalysts show very high activities for Diels-Alder and Friedel-Crafts reactions. We also find the manner of Al-introduction is very important, because the total amounts of acid sites and the ratio of Bronsted/Lewis acid sites are influenced by the manner of the Al-introduction. The activity per Al-atom of Al-introduced MCM-41 catalyst with the highest activity for Diels-Alder and Friedel-Crafts reactions is almost the same as that of homogeneous AlCl_3 catalyst.

  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] T.Kugita: "MCM-41 Highly Active Catalyst for Diels-Alder Reaction of Anthracene with p-Benzoquinone"Micropor. Mesopor. Mater.. 44. 44-45 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Namba: "Pressure Swing Adsorption of Ethyl Acetate on Silica MCM-41"Stud. Surf. Sci. Catal.. 135. 228 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] M.Sugioka: "Hydrodesulfurization of Benzothiophene over Noble Metals Supported on Mesoporous Silica MCM-41"Stud. Surf. Sci. Catal.. 135. 301 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] S.Namba: "Pressure Swing Adsorption of Butanone on Silica MCM-41"Stud. Surf. Sci. Catal.. 129. 757-764 (2000)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] R.S.Mulakutla: "Synthesis and Characterization of Rhodium Oxide Nanoparticles in Mesoporous MCM-41"Phys. Chem. Chem. Phys.. 1. 2027-2032 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] 難波征太郎: "メソポーラスモレキュラーシーブ"MCM-41"の細孔径制御"ゼオライト. 16. 10-15 (1999)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] T. Kugita et al.: "MCM-41 as a Highly Active Catalyst for Diels-Alder Reaction of Anthracene with p-Benzoquinone"Micropor. Mesopor. Mater.. 44. 531-536 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Namba et al: "Pressure Swing Adsorption of Ethyl Acetate on Silica MCM-41"Stud. Surf. Sci. Catal.. 135. 228 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] M. Sugioka et al.: "Hydrodesulfurizatlon of Benzothiophene over Noble Metals Supported on Mesoporous Silica MCM-41"Stud. Surf. Sci. Catal.. 135. 301 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Namba et al.: "Pressure Swing Adsorption of Butanone on Silica MCM-41"Stud. Surf. Sci. Catal.. 129. 757-764 (2000)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] R.S. Mulukutla et al.: "Synthesis and Characterization of Rhodium Oxide Nanoparticles in Mesoporous MCM-41"Phys. Chem. Chem. Phys.. 1. 2027-2032 (1999)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] S. Namba et al.: "Pore Size Control of Mesoporous Molecular Sieve "MCM-41" (Japanese)"Zeolite. 16. 10-15 (1999)

    • Description
      「研究成果報告書概要(欧文)」より

URL: 

Published: 2003-09-17  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi