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2001 Fiscal Year Final Research Report Summary

Dynamic Studies of Self-organizing Polymeric Materials

Research Project

Project/Area Number 11695049
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 高分子構造・物性(含繊維)
Research InstitutionKyoto Institute of Technology

Principal Investigator

KUNUGI Shigeru  Kyoto Institute of Technology, Faculty of Textile Science, Professor, 繊維学部, 教授 (70111929)

Co-Investigator(Kenkyū-buntansha) KIMURA Yoshiharu  Kyoto Institute of Technology, Faculty of Textile Science, Professor, 繊維学部, 教授 (10132276)
SAKURAI Shinichi  Kyoto Institute of Technology, Faculty of Textile Science, Ass. Prof., 繊維学部, 助教授 (90215682)
ITAYA Akira  Kyoto Institute of Technology, Faculty of Textile Science, Professor, 繊維学部, 教授 (80035071)
TSUTSUMI Naoto  Kyoto Institute of Technology, Faculty of Textile Science, Professor, 繊維学部, 教授 (50172036)
MIYATA Takaaki  Kyoto Institute of Technology, Faculty of Textile Science, Professor, 繊維学部, 教授 (50188827)
Project Period (FY) 1999 – 2001
KeywordsSelf-organixation / Polymer Materials / Dymanics / Polymer Gels / Polymer Films / Block-copolymerization / Polymer Blends / Photofuctinality
Research Abstract

This study has initiated by collaboration with the researchers in the related fields in the department of chemistry and materials science of Polytechnic University, N Y, USA, in order to elucidate the dynamic aspects of self-organizing and self-structuring polymeric materials, in which multi-phase and hierarchic structures are the characteristics. The total plan has been grouped in to the following five categories :
1. Slow dynamics of structural formation in polymer-blend organizing materials.
2. Development of new block copolymers and their organization and functionalization.
3.Analysis of organizing superstructures by use of dynamic light scattering method.
4. Structurization of synthetic-biological complex systems and reaction analysis.
5. Development of new photo-functional organizing materials.
6. Molecular design of self-organizing materials.
The attained results from each category were :
1. Optical observation of organizing process during the phase-separation of thermoresponsive phase-separating polymericmaterials.
2. Development of A-B-A type block copolymer having amphiphilic properties by using terechelic reactive oligomers.
3. Structural analysis of block- and blend-based organizing materials.
4. Unified understanding for structural formations in proteins and synthetic polymers.
5.Development of new self-organizing polymeric materials in which structural formation is induced by light stimulation.
6. Design and development of novel biodegradable polyester-based self-organizing materials.
These works have been carried out with a tight exchange of research information and discussion between two Institutes and Joint-symposium was organized every year to present the details of newly attained results and to exchange productive discussion upon every result.

  • Research Products

    (12 results)

All Other

All Publications (12 results)

  • [Publications] TSUTSUMI N.: "Diffraction measurement for grating formed in optically poled polymeric materials"Jpn. J. Appl. Phys.. 40. 2264-2268 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] URAKAWA O.: "A Dielectric Study on the Local Dynamics of Miscible Polymer Blends : Poly-2-chlorostyrene/Poly(vinyl methyl ether)Blend"Polymer. 42. 765-773 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] FUJIWARA T.: "Self-organization of Diblock and Triblock Copolymers of Poly(L-Lactide)and Poly(Oxy-ethylene)into Nanostructured Bands and their Network System. Proposition of a Doubly Twisted Chain Conformation of Poly(L-Lactide)"Macromolecule. 34(12). 4043-4050 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] SAKURAI S.: "Preferential Orientation of Lamellar Microdomains Induced by Uniaxial Stretching of Cross-Linked Polystyrene-block-Polybutadiene-block-polystyrene Triblock Copolymer"Macromolecules. 34. 3672-3678 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] TSUBOI Y.: "Pulsed laser deposition of silk protein : Effect of photosensitized-ablation on the secondary structure in thin deposited films"J. Appl. Phys.. 89. 7917-7923 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] KUNUGI S.: "Effects of Pressure on the Behavior of(Hydroxypropyl)cellulose in Aqueous Solution"Colloid Polym. Sci. 279. 1139-1143 (2001)

    • Description
      「研究成果報告書概要(和文)」より
  • [Publications] KUNUGI S., YOSHIDA D., KIMINAMI H.: "Effects of Pressure on the fehavior of (Hydroxypropyl)cellulose in Aqueous Solution"Colloid Polym. Sci.. 279. 1139-1143 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] TSUBOI Y., IKEJIRI T., SHIGA S., YAMADA K., ITAYA A: "an transform the secondary structure of silk protein"Appl. phys. A.. 73(5). 637-640 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] SAKURAI S., AIDA S., OKAMOTO S., ONO T., IMAIZUMI K., NOMURA S.: "Preferential Orientation of Lamellar Microdomains Induced by Uniaxial Stretching of Cross-Linked Polystyrene-block-Polybutadiene-block-polystyrene Triblock Copolymer"Macromolecules. 34. 3672-3678 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] FUJIWARA T., MIYAMOTO M., KIMURA Y., IWATA T., DOI Y.: "self-organization of Diblock and Triblock Copolymers of Poly(L-actide) and Poly(Oxyethylene) into Nanostructured Bands and their Network System. Proposition of a Doubly Twisted Chain Conformation of Poly(L-Lactide)"Macromolecules. 34(12). 4043-4050 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] URAKAWA O., FUSE Y., HORI H., TRAN-CONG-MIYATA Q.,YANO O: "A Dielectric Study on the Local Dynamics of Miscible Polymer Blends : Poly-2-chlorostyrene/Poly(vinyl methyl ether) Blend"Polymer. 42. 765-773 (2001)

    • Description
      「研究成果報告書概要(欧文)」より
  • [Publications] TSUTSUMI N., YAMAMOTO J. SAKAI W.: "Diffraction measurement for grating formed in optically poled polymeric materials"Jpn. J. Appl. Phys.. 40. 2264-2268 (2001)

    • Description
      「研究成果報告書概要(欧文)」より

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Published: 2003-09-17  

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