2002 Fiscal Year Final Research Report Summary
Synthesis, Structure, and Reactivities of Germylborates
| Project/Area Number |
13640542
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Gakushuin University |
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Principal Investigator |
MOCHIDA Kunio Faculty of Science, Professor, 理学部, 教授 (20118772)
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| Co-Investigator(Kenkyū-buntansha) |
NANJO Masto Faculty of Science, Assistant Professor, 理学部, 助手 (50302352)
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| Project Period (FY) |
2001 – 2002
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| Keywords | Germylborate / Ate complex / X-ray diffraction analysis / Catalytic reaction |
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| Research Abstract |
The structure and reactivity of lithium(germyl)triphenylborates, prepared from unsolvated germyllithium and triphenylboran, with organic substrates in methanol were investigated. The germylborates reacted with acetylenes, organic halides, and acyl halides to give the corresponding germyl-substituted compounds. From the reaction with carbonyl compounds, esters, carboxylic acids, and alkenes, germylborates were completely recovered.
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