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2006 Fiscal Year Final Research Report Summary

Highly Efficiency Solar Energy Conversion Using Photointerface System

Research Project

Project/Area Number 14050023
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionKanagawa Academy of Science and Technology (2003-2006)
The University of Tokyo (2002)

Principal Investigator

FUJISHIMA Akira  Kanagawa Academy of Science and Technology, Research Special Laboratories, Chairman (30078307)

Co-Investigator(Kenkyū-buntansha) MURAKAMI Taketoshi  Kanagawa Academy of Science and Technology, Research Special Laboratories, Senior Research Associate (40392930)
Project Period (FY) 2002 – 2006
KeywordsPhotocatalyst / TiO2 / Self-Cleaning / Visible Light-Active Photocatalyst / Nano-Fiber / Nano-sheet / Dye-Sensitized Solar Cell / Water Treatment System
Research Abstract

Toward important technical developments in the effective use of solar energy, many devices by the application of photofunctional interface based on TiO2 have been investigated. In this research, we had investigated the followings that were particularly considered as playing the major roles in such devices.
-Development of Fabrication Process of Dye-Sensitized Solar Cell: With regard to wet-type dye-sensitized solar cells, there have been practical problems in terms of stability and durability due to the use of an electrolyte. To solve the problems, we fabricated a complete-solid-type dye-sensitized solar cell by using CuI as a p-type semiconductor in place of an electrolyte. Triethylamine hydro-thiocyanate was used as a grain refiner of CuI crystal. With this complete-solid-type dye-sensitized solar cell made by using a CuI automatic application device, photovoltaic conversion efficiency with reproducibility was achieved.
-Research on Low Reflectance Self-Cleaning Glass: The utilization … More of self-cleaning properties of photocatalyst for preventing stains on glass is disadvantageous in that the light transmittance of glass is reduced due to a high refractive-index and light reflectivity of TiO2. In order to solve this problem, we developed a low-reflectance self-cleaning glass using SiO2 particles and TiO2 nanoparticles. As a result, we succeeded in coating a glass substrate with a TiO2-SiO2 double layer, which showed a high self-cleaning function as well as a maximum light transmittance of 97% or higher.
-Research on Water Purification Reactor using Photocatalyst: A photocatalyst water purification reactor can treat 10 liters of water at a time. It can also be used in continuous water flow. With this reactor, the degradation of thionine solution having reproducibility was confirmed.
-Research on TiO2 Nano-Fiber: TiO2-SiO2 nano composite fiber is an excellent material that is expected to have high photocatalyst property, heat stability, and low thermal expansion. In this research, TiO2-SiO2 nano composite fiber was researched and developed on the basis of a new adjustment method that used P-25 (Nippon Aerosil) as Ti source and TEOS (Tetraethoxy-silane)-PDMS (Polydimethylsiloxane) sol composite as Si cource. By implanting TiO2 nanoparticles into a SiO2 fiber based on this method, we succeeded in developing a TiO2-SiO2 nano composite fiber having a diameter of 500-700nm and consisting of a TiO2-SiO2 linear complex chain with high mechanical strength. Less

  • Research Products

    (44 results)

All 2006 2005 2004 2003 2002 Other

All Journal Article (18 results) (of which Peer Reviewed: 8 results) Presentation (19 results) Book (5 results) Remarks (1 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Preparation and Photocatalytic Wettability Conversion of TiO2-Based Superhydrophobic Surfaces2006

    • Author(s)
      X. -T. Zhang, JIN MING, T. Murakami, A. Fujishima, 他
    • Journal Title

      Langmuir 22

      Pages: 9477-79

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Fibrous TiO2-SiO2 Nanocomposite Photocatalyst2006

    • Author(s)
      JIN MING, X. -T. Zhang, Z-Y. Liu, A. V. Emeline, T. Murakami, A. Fujishima
    • Journal Title

      Chem. Commun.

      Pages: 4483-85

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Titanium Dioxide Photocatalysis : Present Situation and Future Approaches2006

    • Author(s)
      A. Fujishima, X. -T. Zhang
    • Journal Title

      Comptes Rendus Chimie 9

      Pages: 750-760

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Preparation and Photocatalytic Wettability Conversion of TiO2-Based Superhydrophobic Surfaces2006

    • Author(s)
      X. -T. Zhang, JIN MING, Taketoshi Murakami, Akira Fujishima, 他.
    • Journal Title

      Langmuir 22

      Pages: 9477-79

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Fibrous TiO2-SiO2 Nanocomposite Photocatalyst2006

    • Author(s)
      JIN MING, X. -T. Zhang, Z-Y. Liu, A. V. Emeline, Taketoshi Murakami, Akira Fujishima
    • Journal Title

      Chem. Commun.

      Pages: 4483-85

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Titanium Dioxide Photocatalysis : Present Situation and Future Approaches2006

    • Author(s)
      Akira Fujishima, X. -T. Zhang
    • Journal Title

      Comptes Rendus Chimie 9

      Pages: 750-760

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Solid-State Dye-Sensitized Solar Cells2006

    • Author(s)
      Akira Fujisima, X. -T. Zhang
    • Journal Title

      Nanostructured materials for energy conversion, Elsevier Press

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Nanostructured Materials for Energy Conversion' Chapter 92006

    • Author(s)
      Akira Fujisima, X. -T. Zhang
    • Journal Title

      ELSEVIER (Netherland)

      Pages: 255-273

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Photoelectrochemical behavior of Nb-doped TiO_2 electrodes2005

    • Author(s)
      A. V. Emeline, A. Fujishima, X. -T. Zhang, JIN MING, T. Murakami
    • Journal Title

      J. Phys. Chem. 109

      Pages: 24441-24444

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Photoelectrochemical behavior of Nb-doped TiO_2 electrodes2005

    • Author(s)
      A. V. Emeline, Akira Fujishima, X. -T. Zhang, JIN MING, Taketoshi Murakami
    • Journal Title

      J. Phys. Chem. 109

      Pages: 24441-24444

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] TiO2 photocatalysis : Present situation and future approaches2005

    • Author(s)
      Akira Fujisima, X. -T. Zhang
    • Journal Title

      C. R. Chimie

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Slow Interfacial Charge Recombination in Solid-State Dye-Sensitized Solar Cells2004

    • Author(s)
      X. -T. Zhang, H. -W. Liu, T. Taguchi, Q. -B. Meng, O. Sato, A. Fujishima
    • Journal Title

      Solar Energy Materials & Solar Cells 81(2)

      Pages: 197-203

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Fabrication of an Efficient Solid-state Dye-Sensitized Solar Cell2003

    • Author(s)
      Q. -B. Meng, K. Takahashi, X. -T. Zhang, I. Sutanto, T. -N. Rao, O. Sato, A. Fujishima
    • Journal Title

      Langmuir 19(9)

      Pages: 3572-3574

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Improving the Performance of Solid-state Dye-Sensitized Solar Cell Using MgO Coated TiO_2 Nanoporous Film2003

    • Author(s)
      T. Taguchi, X. -T. Zhang, I. Sutanto, K. Tokuhiro, T. -N. Rao, H. Watanabe, T. Nakamori, M. Uragami, A. Fujishima
    • Journal Title

      Chemical Communications 19

      Pages: 2480-2481

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Al_2O_3-Coated Nanoporous TiO_2Electrode for Solid-state Dye-Sensitized Solar Cell2003

    • Author(s)
      X. -T. Zhang, I. Sutanto, T. Taguchi, K. Tokuhiro, Q. -B. Meng, T. -N. Rao, O. Sato, A. Fujishima
    • Journal Title

      Solar Energy Materials & Solar Cells 80(3)

      Pages: 315-326

    • Description
      「研究成果報告書概要(和文)」より
    • Peer Reviewed
  • [Journal Article] Fabrication of an Efficient Solid-State Dye-Sensitized Solar Cell2003

    • Author(s)
      Q. -B. Meng, K. Takahashi, X. -T. Zhang, I. Sutanto, T. -N. Rao, O. Sato. A. Fujishima
    • Journal Title

      Langmuir 19. (9)

      Pages: 3572-3574

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Improving the Performance of Solid-state Dye-Sensitized Solar Cell Using MgO Coated TiO_2 Nanoporous Film2003

    • Author(s)
      T. Taguchi, X. -T. Zhang, I. Sutanto, K. Tokuhiro, T. -N. Rao, H. Watanabe, T. Nakamori, M. Uragami, A. Fujishima
    • Journal Title

      Chmical Communications 19

      Pages: 2480-2481

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] AI_2O_3-Coated Nanoporous TiO_2Electrode for Solid-State Dye-Sensitized Solar Cell2003

    • Author(s)
      X. -T. Zhang, I. Sutanto, T. Taguchi, K. Tokuhiro, Q. -B. Meng, T. -N. Rao, O. Sato, A. Fujishima
    • Journal Title

      Solar Energy Materials & Solar Cells 80(3)

      Pages: 315-326

    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] 研究にはセンスと雰囲気、そしてプラスα2006

    • Author(s)
      A. Fujishima
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      琉球大学
    • Year and Date
      2006-11-18
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] One Application of Nanotechnology - Photocatalysis : Present Situation and Future Direction2006

    • Author(s)
      A. Fujishima
    • Organizer
      ナノテクノロジー国際シンポジウム
    • Place of Presentation
      学士会館
    • Year and Date
      2006-06-27
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] One Application of Nanotechnology - Photocatalysis : Present Situation and Future Direction2006

    • Author(s)
      A. Fujishima
    • Organizer
      Nano technology international symposium
    • Place of Presentation
      Gakushikaikan
    • Year and Date
      2006-06-27
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] 人傑地霊-研究には雰囲気が大切2006

    • Author(s)
      A. Fujishima
    • Organizer
      電気化学会第25回加藤記念講演会
    • Place of Presentation
      東京
    • Year and Date
      2006-04-02
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Degradation of hormonal substances in water by TiO_2 photocatalysis2005

    • Author(s)
      A. Fujishima
    • Organizer
      The 56th Annual Meeting of the International Society of Electrochemistry.
    • Place of Presentation
      Busan. Korea
    • Year and Date
      20050900
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Water Photolysis and Photocatalysis - How to Extend Fundamental Findings to Actual Applications2005

    • Author(s)
      A. Fujishima
    • Organizer
      IUPAC 40th Congress
    • Place of Presentation
      Beijing
    • Year and Date
      20050800
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] TiO_2 Photocatalysis - from Water Photolysis to Actual Applications2005

    • Author(s)
      A. Fujishima
    • Organizer
      New Materials Science Kyoto/UCSB Workshop 2005
    • Place of Presentation
      Kyoto
    • Year and Date
      20050400
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] Degradation of hormonal substances in water by TiO_2 photocatalysis2005

    • Author(s)
      A. Fujishima
    • Organizer
      The 56th Annual Meeting of the International Society of Electrochemistry
    • Place of Presentation
      Busan, Korea
    • Year and Date
      2005-09-25
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] Water Photolysis and Photocatalysis - How to Extend Fundamental Findings to Actual Applications.2005

    • Author(s)
      A. Fujishima
    • Organizer
      IUPAC 40th Congress
    • Place of Presentation
      Beijing
    • Year and Date
      2005-08-14
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] New approach of TiO_2 Photocatalysis and diamond electrochemistry2005

    • Author(s)
      A. Fujishima
    • Organizer
      The 5^<th> Asian Conference on Electrochemistry
    • Place of Presentation
      Shanghai
    • Year and Date
      2005-05-09
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] TiO_2 Photocatalysis - from Water Photolysis to Actual Applications2005

    • Author(s)
      A. Fujishima
    • Organizer
      New Materials Science Kyoto/UCSB Workshop 2005
    • Place of Presentation
      京都
    • Year and Date
      2005-04-25
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 光触媒で快適空間をつくる2005

    • Author(s)
      藤嶋 昭
    • Organizer
      日本化学会第85春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2005-03-26
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 環境改善に寄与する光触媒2004

    • Author(s)
      藤嶋 昭
    • Organizer
      「日本国際賞」受賞記念講演会
    • Place of Presentation
      東京
    • Year and Date
      2004-04-21
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] PHOTOCATALYSIS FOR THE ENVIRONMENT2004

    • Author(s)
      A. Fujishima
    • Organizer
      Japan Prize Laureates Contribution
    • Place of Presentation
      Tokyo
    • Year and Date
      2004-04-21
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] 光触媒の新展開2004

    • Author(s)
      藤嶋 昭
    • Organizer
      日本化学会創立125周年記念化学イノベーションシンポジウム
    • Place of Presentation
      東京
    • Year and Date
      2004-01-06
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] 光機能界面の新展開2003

    • Author(s)
      藤嶋 昭
    • Organizer
      第42回日本油化学会年会
    • Place of Presentation
      名古屋
    • Year and Date
      2003-09-18
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] TiO2 Photocatalysis and Diamond Sensor2002

    • Author(s)
      A. Fujishima
    • Organizer
      5^<th> Japan-Italy Seminar
    • Place of Presentation
      ITALY
    • Year and Date
      20020900
    • Description
      「研究成果報告書概要(欧文)」より
  • [Presentation] TiO_2 Photocatalysis and Diamond Sensor2002

    • Author(s)
      A. Fujishima
    • Organizer
      5^<th> Japan-Italy Seminar
    • Place of Presentation
      ITALY
    • Year and Date
      2002-09-23
    • Description
      「研究成果報告書概要(和文)」より
  • [Presentation] ダイヤモンド電極の基礎特性と応用の可能性(特3L19)2002

    • Author(s)
      藤嶋 昭
    • Organizer
      電気化学会第69回大会
    • Place of Presentation
      東北大学
    • Year and Date
      2002-04-01
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] Solid-State Dye-Sensitized Solar Cells2006

    • Author(s)
      藤嶋昭, 張〓〓
    • Total Pages
      33-42
    • Publisher
      Nanostructured materials for energy conversion Elsevier Press
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] ‘Nanostructured Materials for Energy Conversion, Chapter92006

    • Author(s)
      藤嶋昭, 張〓〓
    • Total Pages
      255-273
    • Publisher
      ELSEVIER (Netherland)
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 光化学の驚異2006

    • Author(s)
      藤嶋昭
    • Total Pages
      232
    • Publisher
      光化学協会
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] TiO2 photocatalysis : Present situation and future approaches2005

    • Author(s)
      藤嶋昭, 張〓〓
    • Total Pages
      750-760
    • Publisher
      C. R. Chimie
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] -プラスチック化、大面積化、耐久性・変換効率向上- 色素増感太陽電池の開発技術2004

    • Author(s)
      早瀬修二, 藤嶋昭
    • Total Pages
      229
    • Publisher
      技術教育出版社
    • Description
      「研究成果報告書概要(和文)」より
  • [Remarks] 「研究成果報告書概要(和文)」より

    • URL

      http://www.newkast.or.jp/innovation/kenkyusitu/k_project/iv_h_group.html

  • [Patent(Industrial Property Rights)] 反射防止機能を持つ二重構造セルフクリーニング膜とこの二重構造セルフクリーニング膜が形成された構造体並びに製造方法2006

    • Inventor(s)
      張〓〓, 藤嶋昭, 村上武利
    • Industrial Property Rights Holder
      (財)神奈川科学技術アカデミー
    • Industrial Property Number
      特願2006-004605
    • Filing Date
      2006-01-12
    • Description
      「研究成果報告書概要(和文)」より

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Published: 2010-06-09  

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