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2006 Fiscal Year Final Research Report Summary

Development of novel contents to educe logical and creative thinking

Research Project

Project/Area Number 15300267
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Educational technology
Research InstitutionSaitama University

Principal Investigator

TOKITA Sumio  Saitama Univ., Graduate School of Science and Engineering, Professor, 理工学研究科, 教授 (20008866)

Co-Investigator(Kenkyū-buntansha) KOBAYASHI Hidehiko  Saitama Univ., Graduate School of Science and Engineering, Professor, 理工学研究科, 教授 (60125888)
TOYOOKA Akira  Saitama Univ., Graduate School of Science and Engineering, Professor, 理工学研究科, 教授 (90019753)
IWAMOTO Issei  Saitama Univ., Graduate School of Science and Engineering, Professor, 理工学研究科, 教授 (90008871)
NOGUCHI Fumio  Saitama Univ., Graduate School of Science and Engineering, Professor, 理工学研究科, 教授 (40008842)
TACHIKAWA Tatsuya  Saitama Univ., Graduate School of Science and Engineering, Lecturer, 理工学研究科, 講師 (20251142)
Project Period (FY) 2003 – 2006
Keywordseducational engineering / multimedia / hi-vision / probability density / laser sculpture / color chemistry / quantum organic chemistry / molecular orbital method
Research Abstract

In order to develop novel contents to educe logical and creative thinking, following research results were obtained.
(1) Development of novel video recording inducing Hi-vision system : for example, presentation of risky experiments such as the reactions of alkali metals and water, or an interaction between liquid oxygen and a strong magnet. Part of its work was adopted as broadcasting contents from 2006 to 2009 for the University of the Air.
(2) Electronic states in atoms or molecules are very important because a chemical bond is constructed by interaction of electrons. We have developed solid models of atomic orbitals to present at the National Science Museum (Ueno, Tokyo) from 2003 to 2012. A novel representation of Born's probability density of an electron was sculptured in a glass block using a laser technique. The designs thus obtained were registered as eight design rights to the Japanese Patent Office.
(3) Eleven books and 27 original papers and reviews were published by the head investigator.
(4) Original software relating molecular orbital calculations was developed and distributed to the requested 301 users. This software is especially useful for the quantum organic chemical design to the so called functional dyes (coloring materials).
(5) SUCRA (Saitama University Cyber Repositories for Academic resources) was developed under the direction of head investigator. Part of the above results have been opened to the public through the world-wide-web.
(6) Evaluation in terms of educational engineering was performed in actual lectures at Saitama Univ.(2003-2006), the Univ. of Tokyo (2003, 2005), Sophia Univ.(2004, 2006), Tokyo Gakugei Univ.(2003, 2005), and the Univ. of the Air (2003-2006).

  • Research Products

    (50 results)

All 2007 2006 2005 2004 2003 2000

All Journal Article (32 results) Book (9 results) Patent(Industrial Property Rights) (9 results)

  • [Journal Article] 化学について考える2007

    • Author(s)
      時田澄男
    • Journal Title

      埼玉大学応用化学・環境化学工学科同窓会会報 25

      Pages: 4

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] 量子化学計算によるチオフェンおよび五員環系アゾ色素の配座と吸収スペクトルに関る研究2007

    • Author(s)
      古後義也, 時田澄男, 西本吉助
    • Journal Title

      J. Comput. Chem. Jpn 6・2(in press)

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Novel mutation assay of high sensitivity based on direct measuring of genomic DNA alterations Accordant results with Ames test2007

    • Author(s)
      Masae Futakami, Md.Salimullah, Takashi Miura, Sumio Tokita, Koichi Nishigaki
    • Journal Title

      The Journal of Biochemistry (in press)

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] 混成原子軌道のn次元への一般化2007

    • Author(s)
      木戸冬子, 細矢治夫, 時田澄男
    • Journal Title

      J. Comput. Chem. Jpn (in press)

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Changes of Electron Donation by substituents for SN Ylides Obtained by ab initio Calculations2006

    • Author(s)
      Shun-ichi Mitomo, Sumio Tokita, Manabu Seno
    • Journal Title

      J. Photopolym. Sci. Technol. 19

      Pages: 9-14

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] A Three-Dimensional Representation of Bom's Probability Densities of Hydrogen Atomic Orbitals in Glass Blocks2006

    • Author(s)
      Sumio Tokita, Nakako Tokita, Teruo Nagao
    • Journal Title

      J. Comput. Chem. Jpn 5・3

      Pages: 153-158

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] An Attempt to Construct an Isosurface Having Symmetry Elements2006

    • Author(s)
      Sumio Tokita, Takao, Sugiyama, Fumio Noguchi, Hidehiko Fujii, Hidehiko Kobayashi
    • Journal Title

      J. Comput. Chem. Jpn 5・3

      Pages: 159-164

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] 有機合成化学と量子化学2006

    • Author(s)
      時田澄男
    • Journal Title

      MaLSFORUM 4

      Pages: 2-13

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] SYNTHESIS AND RADIATION SENSITIVITY OF PHENOXAZINE TYPE COLOR FORMERS INCLUDING THIOL ESTER PROTECTIVE GROUP2005

    • Author(s)
      Tachikawa T., Sato Y., Tokita S.
    • Journal Title

      Mol. Cryst. Liq. Cryst. 431

      Pages: 461-466

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] VISUALIZATION OF FOUR DIMENSIONAL ATOMIC ORBITALS2005

    • Author(s)
      Kido F., Tokita S., Hosoya H.
    • Journal Title

      Moil. Cryst. Liq. Cryst. 431

      Pages: 345-350

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Molecular Design, Synthesis and γ ray Detection of Novel Color Formers Having Phenazine Moiety2005

    • Author(s)
      Enomoto Y., Tokita S.
    • Journal Title

      J. Photopolym. Sci. Technol. 18

      Pages: 117-120

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Development of a Polymer Film Containing a Leuco-Phenoxazine Color Former for γ Ray Detection2005

    • Author(s)
      Tachikawa T., Tokita S.
    • Journal Title

      J. Photopolym. Sci. Technol. 18

      Pages: 121-124

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] 特色ある図書館に向けて2005

    • Author(s)
      時田澄男
    • Journal Title

      埼玉大学図書館報 むさしの 3

      Pages: 1-2

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] 新素材としての応用が多彩な機能性色素2004

    • Author(s)
      時田澄男
    • Journal Title

      埼経協ニュース 318

      Pages: 35

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] A fluorescence-active 1,3-bis(isothiouronium)-derived naphthalene exhibiting versatile binding modes toward oxoanions in aqueous MeCN solution : new methodology for sensing oxoanions2004

    • Author(s)
      Yuji Kubo, Masakazu Kato, YoshihiroMisawa, Sumio Tokita
    • Journal Title

      Tetrahedron Lett. 45

      Pages: 3769-3773

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] ファインケミカルのルーツと分子設計の概念2004

    • Author(s)
      時田澄男
    • Journal Title

      ファインケミカル 33・8

      Pages: 46-53

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] An Isothiouronium-derived Organized Monolayer at the Air-Water Interface : Design of Film-Based Anion sensor Systems for H_2PO_4^-2004

    • Author(s)
      Yoshihiro Misawa, Yuji Kubo, SumioTokita, Hirokazu Ohkuma, Hiroo Nakahara
    • Journal Title

      Chem. Lett. 33・9

      Pages: 1118-1119

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Characterization of Organized Molecular Layers Including Amphiphilic Isothiouronium Derivatives2004

    • Author(s)
      Yoshihiro Misawa, Yuji Kubo, SumioTokita, Hirokazu Ohkuma, Hiroo Nakahara
    • Journal Title

      Trans. Mater. Res. Soc. Jpn. 29・11

      Pages: 3155-3158

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Effective Cation-Assisted Chirality Induction Using a Dibenzo-Diaza-30-Crown-10 with Bis(Zinc(II) Porphyrin) Units2004

    • Author(s)
      Kubo Y., Ishii Y., Yoshizawa T., Tokita S.
    • Journal Title

      Chem. Commun. 2004

      Pages: 1394-1395

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] A fluorescence-active 1,3-bis(isothiouronium)-derived naphthalene exhibiting versatile binding modes toward oxoanions in aqueous MeCN solution : new methodology for sensing oxoanions2004

    • Author(s)
      Yuji Kubo, Masakazu Kato, Yoshihiro Misawa, Sumio Tokita
    • Journal Title

      Tetrahedron Lett. 45

      Pages: 3769-3773

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] An Isothiouronium-derived Organized Monolayer at the Air-Water Interface : Design of Film-Based Anion sensor Systems forH_2PO_4^-2004

    • Author(s)
      Yoshihiro Misawa, Yuji Kubo, Sumio Tokita, Hirokazu Ohkuma, Hiroo Nakahara
    • Journal Title

      Chem.Lett. 33・9

      Pages: 1118-1119

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Characterization of Organized Moelcular Layers Including Amphiphilic Isothiouronium Derivatives.2004

    • Author(s)
      Yoshihiro Misawa, Yuji Kubo, Sumio Tokita, Hirokazu Ohkuma, Hiroo Nakahara
    • Journal Title

      Trans. Mater. Res. Soc. Jpn. 29・11

      Pages: 3155-3158

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] コンピューターケミストリーとファインケミカル2003

    • Author(s)
      時田澄男
    • Journal Title

      ファインケミカル(隔月刊) 32・3

      Pages: 15-16

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Chirality Induction in a Dibenzo-30-Crown-10 Congener Promoted by an Ion-Pair Coordinated Self-Assembly2003

    • Author(s)
      Tozawa T., Tachikawa T., Tokita S., Kubo Y.
    • Journal Title

      New. J. Chem. 27

      Pages: 221-223

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Solid film Device to Visualize UV-Irradiation2003

    • Author(s)
      Kaburagi Y.^*, Tokita S., Kaneko M.
    • Journal Title

      Chem. Lett. 32

      Pages: 888-889

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Synthesis and Radiation Sensitivity of Tris(4-N, N-dimethyl-aminophenyl) methanethiol2003

    • Author(s)
      Tachikawa T., Handa C., Tokita S
    • Journal Title

      J. Photopoly. Sci. Technol. 16

      Pages: 187-19O

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Development of Novel Color Former Containing Phenoxazine Moiety2003

    • Author(s)
      Nakazawa D., Tachikawa T., Handa C., Tokita S.
    • Journal Title

      J. Photopoly. Sci. Technol. 16

      Pages: 191-194

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] 高感度γ線検出のための機能性色素2003

    • Author(s)
      時田澄男
    • Journal Title

      放射線化学 76

      Pages: 29-33

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] 色、いろいろ2003

    • Author(s)
      時田澄男
    • Journal Title

      欅(埼玉大学広報誌) 13

      Pages: 8-9

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Solid film Device to Visualize UV-Irradiation2003

    • Author(s)
      Kaburagi Y.^*, Tokita S., Kaneko M.
    • Journal Title

      Chem.Lett. 32

      Pages: 888-889

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] Synthesis and Radiation Sensitivity of Tris(4-N, N-dimethyl-aminophenyl) methanethiol2003

    • Author(s)
      Tachikawa T., Handa C., Tokita S.
    • Journal Title

      J. Photopoly. Sci. Technol. 16

      Pages: 187-190

    • Description
      「研究成果報告書概要(欧文)」より
  • [Journal Article] 文化の継承と図書館2000

    • Author(s)
      時田澄男
    • Journal Title

      SALA (Saitama Academic Library Association) 会報 13号

      Pages: 2

    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 硫黄を含む色素材料,サルファーケミカルズのフロンティア第19章(中山重蔵編)2007

    • Author(s)
      時田澄男
    • Total Pages
      273-291
    • Publisher
      シーエムシー出版
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 回解でわかる有機化学のしくみ2007

    • Author(s)
      時田澄男
    • Total Pages
      1-198
    • Publisher
      日本実業出版
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 「実験科学とその方法」第10章 未来をつくる科学 色素化学の場合(濱田嘉昭,菊山宗弘編)2006

    • Author(s)
      時田澄男
    • Total Pages
      164-181, 269, 273
    • Publisher
      放送大学教育振興会
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 放送大学放送教材「実験科学とその方法」第10講のビデオ録画作成(2006-2009-放映)2006

    • Author(s)
      時田澄男
    • Total Pages
      45 min
    • Publisher
      放送大学教育振興会
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] パソコンで考える量子イヒ学の基礎 第2版2006

    • Author(s)
      時田澄男, 染川賢一
    • Total Pages
      1-174
    • Publisher
      裳華房
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] エレクトロニクス用機能性色素普及版第1章モーブ (Mauve) からエレクトロニクス用色素まで2005

    • Author(s)
      時田澄男
    • Total Pages
      3-19
    • Publisher
      シーエムシー
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] パソコンで考える量子化学の基礎2005

    • Author(s)
      時田澄男, 染川賢一
    • Total Pages
      1-174
    • Publisher
      裳華房
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] "n-Dimensional Periodic Tables of the Elements" "The Mathematics of the Periodic Table" (D. H. Rouvray, R. B. King ed)2005

    • Author(s)
      Haruo, Hosoya, Fuyuko Kido, Sumio Tokita
    • Total Pages
      59-74
    • Publisher
      NOVA Science Publisher
    • Description
      「研究成果報告書概要(和文)」より
  • [Book] 化学便覧 応用化学編 第6版 "染料・色素"2003

    • Author(s)
      時田澄男
    • Total Pages
      3
    • Publisher
      丸善
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 教育用模型2006

    • Inventor(s)
      時田那珂子, 時田澄男
    • Industrial Property Rights Holder
      埼玉大学
    • Industrial Property Number
      意匠登録1298427 意願2006-010175
    • Filing Date
      2006-03-24
    • Acquisition Date
      2007-03-16
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 教育用模型2006

    • Inventor(s)
      時田那珂子, 時田澄男
    • Industrial Property Rights Holder
      埼玉大学
    • Industrial Property Number
      意匠登録1298894 意願2006-010176
    • Filing Date
      2006-03-24
    • Acquisition Date
      2007-03-16
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 教育用模型2006

    • Inventor(s)
      時田那珂子, 時田澄男
    • Industrial Property Rights Holder
      埼玉大学
    • Industrial Property Number
      意匠登録1298428 意願2006-010177
    • Filing Date
      2006-03-24
    • Acquisition Date
      2007-03-16
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 教育用模型2006

    • Inventor(s)
      時田那珂子, 時田澄男
    • Industrial Property Rights Holder
      埼玉大学
    • Industrial Property Number
      意匠登録1298429 意願2006-010178
    • Filing Date
      2006-03-24
    • Acquisition Date
      2007-03-16
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 教育用模型2006

    • Inventor(s)
      時田那珂子, 時田澄男
    • Industrial Property Rights Holder
      埼玉大学
    • Industrial Property Number
      意匠登録1298430 意願2006-010179
    • Filing Date
      2006-03-24
    • Acquisition Date
      2007-03-16
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 教育用模型2006

    • Inventor(s)
      時田那珂子, 時田澄男
    • Industrial Property Rights Holder
      埼玉大学
    • Industrial Property Number
      意匠登録1298431 意願2006-0101810
    • Filing Date
      2006-03-24
    • Acquisition Date
      2007-03-16
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 教育用模型2006

    • Inventor(s)
      時田那珂子, 時田澄男
    • Industrial Property Rights Holder
      埼玉大学
    • Industrial Property Number
      意匠登録1298895 意願2006-010181
    • Filing Date
      2006-03-24
    • Acquisition Date
      2007-03-16
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 放射線検出用発色剤2005

    • Inventor(s)
      時田澄男, 太刀川達也
    • Industrial Property Rights Holder
      埼玉大学
    • Industrial Property Number
      新規特許 特願2005-169055
    • Filing Date
      2005-06-09
    • Description
      「研究成果報告書概要(和文)」より
  • [Patent(Industrial Property Rights)] 教育用模型2005

    • Inventor(s)
      時田那珂子, 時田澄男
    • Industrial Property Rights Holder
      埼玉大学
    • Industrial Property Number
      意匠登録 意願2005-38068
    • Filing Date
      2005-12-26
    • Description
      「研究成果報告書概要(和文)」より

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Published: 2008-05-27  

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