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2004 Fiscal Year Final Research Report Summary

Isolation of lignin-carbohydrate bonds in wood

Research Project

Project/Area Number 15380124
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field 林産科学・木質工学
Research InstitutionForestry and Forest Products Research Institute

Principal Investigator

HOSOYA Shuji  Forestry and Forest Products Research Institute, Department of Chemical Utilization, Chief, 成分利用研究領域, 領域長 (70012002)

Co-Investigator(Kenkyū-buntansha) MAGARA Kengo  Forestry and Forest Products Research Institute, Wood chemistry laboratory, Laboratory head, 室長 (10353848)
TANAKA Ryohei  Forestry and Forest Products Research Institute, Wood chemistry laboratory, Senior Researcher, 主任研究官 (50343778)
IKEDA Tsutomu  Forestry and Forest Products Research Institute, Wood chemistry laboratory, Researcher, 研究員 (90334036)
SUGIMOTO Tomoko  Forestry and Forest Products Research Institute, Wood chemistry laboratory, Researcher, 研究員 (20353732)
Project Period (FY) 2003 – 2004
Keywordslignin / hexose / lignin-carbohydrate complexes / benzyl ether / ozone / acid / LCC / LCCモデル化合物
Research Abstract

Mostly lignin, it is about 96% lignin in wood meal, was degraded to very low molecular weight structures which could not give acid insoluble lignin after ozonation for 16 hours with 20 times molar ozone. On the other hand, LCC products which contain a benzyl ether type LCC bond in a molecular were isolated from red pine wood after ozonation followed by acid hydrolysis. LCC products were included in the Acidic fraction after anion exchange chromatography, the Acidic fraction was mixture of many products such as organic acids from lignin and acidic sugars from polysaccharides. Many products gave similar retention time compare with that of LCC products on GC chromatogram after trimethylsilylation, identification of LCC products was very difficult. However, it was improved after acetylation instead of trimethylsilylation. LCC products were isolated from both glucose and mannose bonded LCC model compounds and some products which give same retention time on GC chromatogram with these LCC products were also isolated from red pine wood. These products isolated from red pine wood gave same retention time on total ion chromatogram and showed similar mass fragment pattern, compared with LCC products isolated from LCC model compounds. Therefore, these results suggested that benzyl ether type LCC bonds between lignin and hexoses, such as glucose and mannose, were isolated from red pine wood by ozonation followed acid hydrolysis without LCC bond cleavage.

  • Research Products

    (3 results)

All 2004

All Journal Article (3 results)

  • [Journal Article] Isolation of lignin-carbohydrate bonds in wood. Model experiments and preliminary application to pine wood.2004

    • Author(s)
      Olov Karlsson
    • Journal Title

      Journal of wood science 50

      Pages: 142-150

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Chlorine-Free bleaching of kraft pulp from oil palm empty fruit bunches.2004

    • Author(s)
      Pyohei Tanaka
    • Journal Title

      Japan agricultural research quarterly 38

      Pages: 275-279

    • Description
      「研究成果報告書概要(和文)」より
  • [Journal Article] Chlorine-Free bleaching of kraft pulp from oil parm empty fruit bunches.2004

    • Author(s)
      Ryohei Tanaka
    • Journal Title

      Japan agricultural research quarterly 38

      Pages: 275-279

    • Description
      「研究成果報告書概要(欧文)」より

URL: 

Published: 2006-07-11  

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