2017 Fiscal Year Final Research Report
Development of three-dimensional spiro-aromatic systems
| Project/Area Number |
15K05419
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Multi-year Fund |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Shimane University |
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Principal Investigator |
Suzuki Masaaki 島根大学, 総合理工学研究科, 講師 (90506891)
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| Project Period (FY) |
2015-04-01 – 2018-03-31
|
| Keywords | ポルフィリノイド / ポルフィリン / テトラベンゾポルフィリン / 環拡張ポルフィリン / トリピリン / 芳香族性 / 三次元π共役 |
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| Outline of Final Research Achievements |
Spiro-aromatic systems are consisting of the three-dimensional combination of pi-planes in a perpendicular arrangement. This work was focused on the three-dimensional pi-plane systems including non-planarity of the frameworks and branching of the pi-conjugation. Syntheses of nonplanar meso-trifluoromethyl substituted tetrabenzoporphyrins, spiro-fused porphodimethanes, branched recombined N-fused pentaphyrins, and bromine-terminated tripyrrins were investigated.
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| Free Research Field |
有機化学
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