2016 Fiscal Year Final Research Report
New route of anion exchange reactions and physical properties of mixed anion compounds
| Project/Area Number |
15K17695
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| Research Category |
Grant-in-Aid for Young Scientists (B)
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| Allocation Type | Multi-year Fund |
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| Research Field |
Condensed matter physics II
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| Research Institution | The University of Tokyo |
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Principal Investigator |
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| Project Period (FY) |
2015-04-01 – 2017-03-31
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| Keywords | 複合アニオン化合物 / 陰イオン置換反応 / 酸フッ化物 / 酸窒化物 / カルボジイミド / 多色性 |
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| Outline of Final Research Achievements |
We aimed at establishing a new route of anion exchange reactions for controlling physical properties of transition metal oxides and exploring novel properties of mixed-anion compounds. By using tetrafluoroethlene (teflon)/melamine as anion sources, we succeeded in performing anion exchange reactions. This method enabled us to synthesize various mixed-anion compounds including a new compound Lu2O2NCN. In addition, we investigated unique properties of mixed anion compounds and discovered a very strong pleochroism in a new mixed anion compound Ca3ReO5Cl2.
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| Free Research Field |
固体化学
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