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2016 Fiscal Year Annual Research Report

Development of intramolecular isotope analysis for understanding the origin of natural gas hydrocarbons

Research Project

Project/Area Number 15K17774
Research InstitutionTokyo Institute of Technology

Principal Investigator

ジルベルト アレキシー  東京工業大学, 理学院, 特任助教 (20726955)

Project Period (FY) 2015-04-01 – 2017-03-31
KeywordsIsotope / Natural gas / Hydrocarbons
Outline of Annual Research Achievements

Our goal was to refine our understanding of natural gas sources ans sinks in natural geological settings.
We developed a method for position-specific 13C isotope analysis of propane and butane from natural gas. The first part of the project consisted in developing the method and calibrating it with labelled 13C compounds (Gilbert et al 2016).
We then applied the method to natural gas of various origins: we synthesized natural gas in the lab by thermal cracking of oil components; we sampled natural gas from a continental hydrothermal system and several gases of thermogenic origin.
We showed that our method is able to distinguish different processes such as biological vs non-biological production, thermal vs biological degradation (Suda, Gilbert et al, 2017).

  • Research Products

    (9 results)

All 2017 2016

All Journal Article (5 results) (of which Int'l Joint Research: 5 results,  Peer Reviewed: 5 results,  Open Access: 1 results,  Acknowledgement Compliant: 3 results) Presentation (4 results) (of which Invited: 2 results)

  • [Journal Article] Compound- and position-specific carbon isotopic signatures of abiogenic hydrocarbons from on-land serpentinite-hosted Hakuba Happo hot spring in Japan2017

    • Author(s)
      Konomi Suda, Alexis Gilbert, Keita Yamada, Naohiro Yoshida, Yuichiro Ueno
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 206 Pages: 201-215

    • DOI

      10.1016/j.gca.2017.03.008

    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] The Abiotic Chemistry of Thiolated Acetate Derivatives and the Origin of Life2016

    • Author(s)
      Kuhan Chandru, Alexis Gilbert, Christopher Butch, Masashi Aono, H James Cleaves
    • Journal Title

      Scientific Reports

      Volume: 6 Pages: 1-11

    • DOI

      doi:10.1038/srep29883

    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Measurement of natural carbon isotopic composition of acetone in human urine2016

    • Author(s)
      Keita Yamada, Kazuki Ohishi, Alexis Gilbert, Mai Akasaka, Naohiro Yoshida, Ryoko Yoshimura
    • Journal Title

      Analytical and bioanalytical chemistry

      Volume: 408 Pages: 1597-1607

    • DOI

      10.1007/s00216-015-9268-z

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Measurement of position-specific 13 C isotopic composition of propane at the nanomole level2016

    • Author(s)
      Alexis Gilbert, Keita Yamada, Konomi Suda, Yuichiro Ueno, Naohiro Yoshida
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 177 Pages: 201-216

    • DOI

      10.1016/j.gca.2016.01.017

    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Journal Article] Evaluation of on-line pyrolysis coupled to isotope ratio mass spectrometry for the determination of position-specific 13 C isotope composition of short chain n-alkanes (C6-C 12)2016

    • Author(s)
      Alexis Gilbert, Keita Yamada, Naohiro Yoshida
    • Journal Title

      Talanta

      Volume: 153 Pages: 158-162

    • DOI

      10.1016/j.talanta.2016.03.014

    • Peer Reviewed / Int'l Joint Research / Acknowledgement Compliant
  • [Presentation] Recent insights into intramolecular 13C isotope composition of biomolecules2016

    • Author(s)
      Alexis Gilbert, Gerald Remaud, Keita Yamada, Yuichiro Ueno, Richard Robins, Naohiro Yoshida
    • Organizer
      AGU 2016
    • Place of Presentation
      San Francisco (USA)
    • Year and Date
      2016-12-12 – 2016-12-16
    • Invited
  • [Presentation] Position-specific isotope analysis by on-line pyrolysis coupled to IRMS2016

    • Author(s)
      Alexis Gilbert, Keita Yamada, Yuichiro Ueno, Naohiro Yoshida
    • Organizer
      AGU 2016
    • Place of Presentation
      San Francisco (USA)
    • Year and Date
      2016-12-12 – 2016-12-16
  • [Presentation] Stable isotopes in Biogeosciences2016

    • Author(s)
      Alexis Gilbert
    • Organizer
      International Symposium on Isotopomer 2016
    • Place of Presentation
      Nantes (France)
    • Year and Date
      2016-10-03 – 2016-10-06
    • Invited
  • [Presentation] On-line pyrolysis combined with IRMS for 13C intramolecular isotope determination2016

    • Author(s)
      Alexis Gilbert, Keita Yamada, Yuichiro Ueno, Naohiro Yoshida
    • Organizer
      Workshop on isotopologues (Goldschmidt Conference 2016)
    • Place of Presentation
      Tokyo (Japan)
    • Year and Date
      2016-06-25 – 2016-06-25

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Published: 2018-01-16  

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