Curve effect on the pai-electron moiety

2017 Fiscal Year Final Research Report

• Project/Area Number: 16K13954
• Research Category: Grant-in-Aid for Challenging Exploratory Research
• Allocation Type: Multi-year Fund
• Research Field: Organic chemistry
• Research Institution: Hiroshima University
• Principal Investigator: Abe Manabu 広島大学, 理学研究科, 教授 (30273577)
• Project Period (FY): 2016-04-01 – 2018-03-31
• Keywords: curved molecule / pai electron

Outline of Final Research Achievements

Alkenes usually have a planar structure, π orbitals are extended in the direction perpendicular to the molecular plane, which are involved in absorption and emission of light energy, electron transfer. In recent years, a carbon material having a π-conjugated electron system as represented by fullerenes and carbon nanotubes has drawn attention as a next-generation functional material. The reason is the unique electron transfer ability and low excitation energy generated from the π electron system. However, the understanding of the electronic properties generated by the π-electron system is inexperienced, and the effects of the π-electron system are not clearly understood. In this research, the electronic property of bicyclo [1.1.0] but- -1 (3) -ene was examined as an example of the distorted π-electron compound.

Free Research Field

反応性中間体の化学