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2009 Fiscal Year Final Research Report

Creation of Metal-mediated Nanolink Supramolecules

Research Project

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Project/Area Number 17069010
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionThe University of Tokyo

Principal Investigator

SHIONOYA Mitsuhiko  The University of Tokyo, 大学院・理学系研究科, 教授 (60187333)

Co-Investigator(Renkei-kenkyūsha) TANAKA Kentaro  名古屋大学, 大学院・理学研究科, 教授 (40281589)
HIRAOKA Shuichi  東京大学, 大学院・総合文化研究科, 教授 (10322538)
TASHIRO Shohei  東京大学, 大学院・理学系研究科, 助教 (80420230)
UBE Hitoshi  東京大学, 大学院・理学系研究科, 助教 (00512138)
TAKEZAWA Yusuke  東京大学, 大学院・理学系研究科, 特任助教 (70508598)
Project Period (FY) 2005 – 2009
Keywords化学工学 / 化学物理 / 表面・界面物性 / 複合材料・特性 / 合成化学
Research Abstract

This study aimed at creation of metal-mediated nanolink supramolecules that shows specific chemical and physical properties and dynamic functions on the surface of a solid. As the As the result, a method of conduction measurement in artificial metallo-DNA linking carbon nanotube electrodes, an arrangement of Magnus'-type metal stacks in a molecular cage, a synthetic method of metal wire using an oxime-type macrocycle have been established. These findings show that such supramolecular metal complexes are useful for nanolink molecules as key materials.

  • Research Products

    (28 results)

All 2011 2010 2009 2008 2007 2006 2005 Other

All Journal Article (12 results) (of which Peer Reviewed: 12 results) Presentation (14 results) Book (1 results) Remarks (1 results)

  • [Journal Article] A pH Switchable Rotaxane based on a Metal Cage and Bis-Anionic Thread2010

    • Author(s)
      G.H.Clever, M.Shionoya
    • Journal Title

      Chem.Eur.J. 16

      Pages: 11784-11790

    • Peer Reviewed
  • [Journal Article] Light-Triggered Crystallization of a Molecular Host-Guest Complex2010

    • Author(s)
      G.H.Clever, S.Tashiro, M.Shionoya
    • Journal Title

      J.Am.Chem.Soc. 132

      Pages: 9973-9975

    • Peer Reviewed
  • [Journal Article] Metal-Base Pairing in DNA2010

    • Author(s)
      G.H.Clever, M.Shionoya
    • Journal Title

      Coord.Chem.Rev. 254

      Pages: 2391-2402

    • Peer Reviewed
  • [Journal Article] One-Pot, Template Syntheses of a New Class of Metallomacrocycles with a Tetraoxime Cyclic Skeleton2009

    • Author(s)
      S.Tashiro, A.Minoda, M.Yamada, M.Shionoya
    • Journal Title

      Inorg.Chem. 48

      Pages: 11093-10101

    • Peer Reviewed
  • [Journal Article] Inclusion of Anionic Guests in a Molecular Cage with Pd-Centers as Electrostatic Anchors2009

    • Author(s)
      G.H.Clever, S.Tashiro, M.Shionoya
    • Journal Title

      Angew.Chem.Int.Ed. 48

      Pages: 7010-7012

    • Peer Reviewed
  • [Journal Article] Discrete Self-Assembly of Iron Ions inside Triple-Stranded Artificial DNA2009

    • Author(s)
      Y.Takezawa, W.Maeda, K.Tanaka, M.Shionoya
    • Journal Title

      Angew.Chem.Int.Ed. 48

      Pages: 1081-1084

    • Peer Reviewed
  • [Journal Article] A Close-Packed, Highly- Insulating Organic Thin Monolayer on Si(111)2008

    • Author(s)
      K.Tanaka, T.Tanaka, T.Hasegawa, M.Shionoya
    • Journal Title

      Chem.Lett. 37

      Pages: 440-441

    • Peer Reviewed
  • [Journal Article] Programmable Metal Assembly on Bio-Inspired Templates2007

    • Author(s)
      K.Tanaka, M.Shionoya
    • Journal Title

      Coord.Chem.Rev. 251

      Pages: 2732-2742

    • Peer Reviewed
  • [Journal Article] Isostructural Coordination Capsules for a Series of 10 Different d^5 to d^<10> Transition Metal Ions2006

    • Author(s)
      S.Hiraoka, K.Harano, M.Shiro, Y.Ozawa, N.Yasuda, K.Toriumi, M.Shionoya
    • Journal Title

      Angew.Chem.Int.Ed. 45

      Pages: 6488-6491

    • Peer Reviewed
  • [Journal Article] Electrostatically Controlled Hierarchical Arrangement of Monocationic Silver(I) and Dicationic Mercury(II) Ions between Disk-Shaped Template Ligands2006

    • Author(s)
      S.Hiraoka, T.Tanaka, M.Shionoya
    • Journal Title

      J.Am.Chem.Soc. 128

      Pages: 13038-10339

    • Peer Reviewed
  • [Journal Article] Bio-Inspired Programmable Self-Assembly on DNA Templates2006

    • Author(s)
      K.Tanaka, M.Shionoya
    • Journal Title

      Chem.Lett. 35

      Pages: 694-699

    • Peer Reviewed
  • [Journal Article] Programmable Self-Assembly of Metal Ions in Artificial DNA2006

    • Author(s)
      K.Tanaka, G.H.Clever, Y.Takezawa, Y.Yamada, C.Kaul, M.Shionoya, T.Carell
    • Journal Title

      Nat.Nanotechnol. 1

      Pages: 190-194

    • Peer Reviewed
  • [Presentation] Design-based Nano- to Submicron-sized Supramolecular Assemblies2011

    • Author(s)
      M.Shionoya
    • Organizer
      CSI meeting(Invited)
    • Place of Presentation
      Berlin, Germany.
    • Year and Date
      20110310-20110311
  • [Presentation] Supramolecular Design toward Dynamic Molecular Functions2010

    • Author(s)
      M.Shionoya
    • Organizer
      5^<th> International Symposium on Macrocyclic & Supramolecuar Chemistry 2010(Plenary)
    • Place of Presentation
      Nara.
    • Year and Date
      20100606-20100609
  • [Presentation] A New Trend in Supramolecular Chemistry -Control of Array, Space, and Motion-2010

    • Author(s)
      M.Shionoya
    • Organizer
      SFB 749 : Symposium Kloster Irsee(Plenary)
    • Place of Presentation
      Irsee, Germany.
    • Year and Date
      20100321-20100324
  • [Presentation] A New Trend in Supramolecular Synthesis : Dynamic Control of Array, Space, and Motion2010

    • Author(s)
      M.Shionoya
    • Organizer
      The International Symposium on Nano-Bio Molecular Assembly 2010(Invited)
    • Place of Presentation
      Seoul, South Korea.
    • Year and Date
      2010-06-16
  • [Presentation] Metal Strings in Artificial DNA, International Workshop on DNA-based Nanotechnology : Construction2009

    • Author(s)
      M.Shionoya
    • Organizer
      Mechanics and Electronics(Plenary)
    • Place of Presentation
      Dresden, Germany.
    • Year and Date
      2009-05-15
  • [Presentation] Supramolecular Nanoarchitecture for Array, Space, and Motion2008

    • Author(s)
      M.Shionoya
    • Organizer
      4^<th> EuCheMS Conference on NITROGEN LIGANDS in Coordination Chemistry, Metal-Organic Chemistry, Bioinorganic Chemistry & Homogeneous Catalysis(Plenary)
    • Place of Presentation
      G.-P.Germany.
    • Year and Date
      20080824-20080828
  • [Presentation] Noncovalent Assemblies for Metal Array, Space, and Motion2007

    • Author(s)
      M.Shionoya
    • Organizer
      International Symposium on Catalysis & Fine Chemicals 2007(Plenary)
    • Place of Presentation
      Singapore.
    • Year and Date
      20071216-20071221
  • [Presentation] Molecular Machines based on Non-Interlocking Molecules2007

    • Author(s)
      M.Shionoya
    • Organizer
      21^<st> Solvay Conference on Chemistry "From Noncovalent Assemblies to Molecular Machines"(Invited)
    • Place of Presentation
      Brussels, Belgium.
    • Year and Date
      20071128-20071201
  • [Presentation] Nanoscopic Self-Assembled Architecture : Programmable Metal Arrays and Molecular Motions2007

    • Author(s)
      M.Shionoya
    • Organizer
      Japan-USA Joint Symposium(Invited)
    • Place of Presentation
      Evanston, USA.
    • Year and Date
      20070625-20070626
  • [Presentation] Noncovalent Assemblies : Nanoscopic Metal Array, Space, and Motion2007

    • Author(s)
      M.Shionoya
    • Organizer
      CIPSM Lecture(Invited)
    • Place of Presentation
      Munich, Germany.
    • Year and Date
      2007-07-30
  • [Presentation] Artificial Metallo-DNA for Metal Array Programming2006

    • Author(s)
      M.Shionoya
    • Organizer
      The ESF Research Conference Inorganic Chemistry(Plenary)
    • Place of Presentation
      Athens, Greece.
    • Year and Date
      20061112-20061117
  • [Presentation] Artificial Metallo-DNA towards Metal Array Programming, XVII International Roundtable on Nucleosides2006

    • Author(s)
      M.Shionoya
    • Organizer
      Nucleotides and Nucleic Acids(Plenary)
    • Place of Presentation
      Bern, Switzerland.
    • Year and Date
      20060903-20060907
  • [Presentation] A Supramolecular Approach to Metal Array Programming using Artificial DNA2006

    • Author(s)
      M.Shionoya
    • Organizer
      The Second Nanoday(Plenary)
    • Place of Presentation
      Seoul, South Korea.
    • Year and Date
      2006-06-09
  • [Presentation] Supramolecular Metal-Arrays and Metal-Mediated Motions -Artificial Metallo-DNA and Peptides, Molecular Ball Bearings and Containers-2005

    • Author(s)
      M.Shionoya
    • Organizer
      The 9^<th> International Conference on Miniatuarized Systems for Chemistry and Life Sciences(Plenary)
    • Place of Presentation
      Boston, USA.
    • Year and Date
      20051009-20051013
  • [Book] 超分子金属錯体2009

    • Author(s)
      共編:藤田誠, 塩谷光彦
    • Publisher
      三共出版
  • [Remarks] ホームページ

    • URL

      http://www.chem.s.u-tokyo.ac.jp/users/bioinorg/index.html

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Published: 2012-02-13   Modified: 2012-11-16  

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