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2009 Fiscal Year Final Research Report

Examination of fast dynamics and hierarchical order in ionic liquids

Research Project

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Project/Area Number 17073003
Research Category

Grant-in-Aid for Scientific Research on Priority Areas

Allocation TypeSingle-year Grants
Review Section Science and Engineering
Research InstitutionThe University of Tokyo

Principal Investigator

IWATA Koichi  The University of Tokyo, 理学部, 教授 (90232678)

Project Period (FY) 2005 – 2009
Keywordsイオン液体 / 階層構造 / 局所構造 / 時間分解分光法 / 粘度 / 熱拡散定数 / 溶媒和電子
Research Abstract

Ionic liquids take a liquid form at room temperature although they are salts. They are used as solvents "green" to the environments, because most of them show a negligible vapor pressure. We have studied the correlation between the molecular scale solvation environments in ionic liquids and their macroscopic properties, by observing ultrafast events that proceed in the ionic liquids. It is possible that "local structure", whose presence is presumed in the ionic liquids, affects the macroscopic properties and chemical reactions in the ionic liquids to a large extent.

  • Research Products

    (28 results)

All 2010 2009 2008 2007 2006 2005 Other

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (15 results) Book (1 results) Remarks (1 results)

  • [Journal Article] Two different charge transfer states of photoexcited 9,9'-bianthryl in polar and nonpolar solvents characterized by nanosecond time-resolved near-IR spectroscopy in the 4500-10500cm^<-1> region2010

    • Author(s)
      N.Asami, T.Takaya, S.Yabumoto, S.Shigeto, H.Hamaguchi, K.Iwata
    • Journal Title

      J.Phys.Chem.A 114(22)

      Pages: 6351-6355

    • Peer Reviewed
  • [Journal Article] Effect of cluster formation of solvent molecules on the preferential solvatation of anthracene in binary alcoholic solutions2009

    • Author(s)
      S.Kunsagi-Mate, K.Iwata
    • Journal Title

      Chem.Phys.Lett. 473(4-6)

      Pages: 284-287

    • Peer Reviewed
  • [Journal Article] Intermolecular interaction between W(CO)_6 and alkane molecules probed by ultrafast vibrational energy relaxation : anomalously strong interaction between W(CO)_6 and decane2009

    • Author(s)
      M.Banno, K.Iwata, H.Hamaguchi
    • Journal Title

      J.Phys.Chem.A 113(6)

      Pages: 1007-1011

    • Peer Reviewed
  • [Journal Article] Femtosecond Time-Resolved Absorption Anisotropy Spectroscopy on 9,9'-Bianthryl : Detection of Partial Intramolecular Charge Transfer in Polar and Nonpolar Solvents2009

    • Author(s)
      T.Takaya, H.Hamaguchi, K.Iwata
    • Journal Title

      J.Chem.Phys. 130(1)

      Pages: 014501-1-014501-9

    • Peer Reviewed
  • [Journal Article] I Ultrafast bimolecular radical reaction between S_1 p-terphenyl and carbon tetrachloride. Mode-specific acceleration of vibrational dephasing in reactant molecule2008

    • Author(s)
      K.Iwata
    • Journal Title

      J.Raman.Spectrosc. 39(11)

      Pages: 1512-1517

    • Peer Reviewed
  • [Journal Article] Vibrational Cooling Process of S_1 trans-stilbene in Ionic Liquids Observed with Picosecond Time-Resolved Raman Spectroscopy2007

    • Author(s)
      K.Iwata, K.Yoshida, Y.Takada, H.Hamaguchi
    • Journal Title

      Chem.Lett. 36(4)

      Pages: 504-505

    • Peer Reviewed
  • [Journal Article] Picosecond time-resolved fluorescence study on solute-solvent interaction of 2-Aminoquinoline in room-temperature ionic liquids : π-π aromatic complex formation and unusually slow rotational diffusion2007

    • Author(s)
      K.Iwata, M.Kakita, H.Hamaguchi
    • Journal Title

      J.Phys.Chem.B 111(18)

      Pages: 4914-4919

    • Peer Reviewed
  • [Journal Article] Intra- and inter-molecular vibrational energy transfer in tungsten carbonyl complexes W(CO)_5(X) (X=CO, CS, CH_3CN, and CD_3CN)2007

    • Author(s)
      M.Banno, K.Iwata, H.Hamaguchi
    • Journal Title

      J.Chem.Phys. 126(20)

      Pages: 204501-1-204501-9

    • Peer Reviewed
  • [Journal Article] Local structure formation in alkyl-imidazolium based ionic liquids as revealed by linear and non-linear Raman spectroscopy2007

    • Author(s)
      K.Iwata, H.Okajima, S.Saha, H.Hamaguchi
    • Journal Title

      Acc.Chem.Res. 40(11)

      Pages: 1174-1181

    • Peer Reviewed
  • [Journal Article] Charge Resonance Character in Charge Transfer State of Bianthryls : Effect of Symmetry Breaking on Time-Resolved Near-IR Absorption Spectra2006

    • Author(s)
      T.Takaya, S.Saha, H.Hamaguchi, M.Sarkar, A.Samanta, K.Iwata
    • Journal Title

      J.Phys.Chem.A(letter) 110(13)

      Pages: 4291-4295

    • Peer Reviewed
  • [Journal Article] Solvent-dependent intra- and intermolecular vibrational energy transfer of W(CO)_6 probed with sub-picosecond time-resolved infrared spectroscopy2005

    • Author(s)
      Motohiro Banno, Shin Sato, Koichi Iwata, Hiro-o Hamaguchi
    • Journal Title

      Chem.Phys.Lett. 412(4-6)

      Pages: 464-169

    • Peer Reviewed
  • [Presentation] New Attempts with Raman Spectroscopy for Examining Macromolecules and Lipid Bilayer Membranes2010

    • Author(s)
      Koichi Iwata
    • Organizer
      XXIIth International Conference on Raman Spectroscopy (ICORS2010)(Invited)
    • Place of Presentation
      Boston, MA, USA
    • Year and Date
      2010-08-09
  • [Presentation] How Electron Relaxes in Micellar Solution, Ionic Liquid, and TiO_2 Photocatalyst : Femtosecond Time-resolved Near-infrared Study2010

    • Author(s)
      Koichi Iwata
    • Organizer
      Advanced Spectroscopy and Imaging in Molecular Science(Invited)
    • Place of Presentation
      Hsinchu, Taiwan
    • Year and Date
      2010-07-13
  • [Presentation] Loose electrons in micellar solution and TiO_2 photocatalysts examined with femtosecond time-resolved near-IR spectroscopy2009

    • Author(s)
      Koichi Iwata
    • Organizer
      The Second Asian Spectroscopy Conference (ASC09)(Invited)
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      20091130-20091202
  • [Presentation] Disagreement between Microscopic Solvation Environments and Macroscopic Properties in Ionic Liquids2009

    • Author(s)
      Koichi Iwata
    • Organizer
      3rd Congress on Ionic Liquids (COIL-3)
    • Place of Presentation
      Cairns, Australia
    • Year and Date
      20090531-20090604
  • [Presentation] Microscopic Solvation Environments and Macroscopic Properties : Loss of Correlation in Ionic Liquid2009

    • Author(s)
      Koichi Iwata
    • Organizer
      COIL-3 Pre-Symposium "Science of Ionic Liquids"
    • Place of Presentation
      Cairns, Australia
    • Year and Date
      20090529-20090530
  • [Presentation] Loss of correlation between microscopic solvation environments and macroscopic properties : Partially ordered structure in ionic liquids2009

    • Author(s)
      Koichi Iwata
    • Organizer
      5th International Conference on Advanced Vibrational Spectroscopy (ICAVS-5)(Invited)
    • Place of Presentation
      Melbourne, Australia
    • Year and Date
      2009-07-16
  • [Presentation] Layers of intermolecular interaction specified with picosecond time-resolved Raman spectroscopy2008

    • Author(s)
      Koichi Iwata
    • Organizer
      80 Years of Raman Effect, "Reflection and the Future"(Invited)
    • Place of Presentation
      Bangalore, India
    • Year and Date
      20081208-20081210
  • [Presentation] Using Ultrafast Time-resolved Near IR Spectroscopy to Probe Photocatalytic Reactions on TiO_22008

    • Author(s)
      Koichi Iwata
    • Organizer
      35th FACSS (Federation of Analytical Chemistry and Spectroscopy Societies)(Invited)
    • Place of Presentation
      Reno, Nevada, USA
    • Year and Date
      20080928-20081002
  • [Presentation] International Symposium on Structure and Reaction Dynamics of Ionic Liquids in Kanazawa2008

    • Author(s)
      Koichi Iwata
    • Organizer
      International Symposium on Structure and Reaction Dynamics of Ionic Liquids in Kanazawa(Invited)
    • Place of Presentation
      Kanazawa, Japan
    • Year and Date
      20080902-20080903
  • [Presentation] Photoinduced bimolecular radical reaction between p-terphenyl and carbon tetrachloride studied by picosecond time-resolved Raman spectroscopy - mode-selective acceleration of vibrational dephasing2008

    • Author(s)
      Koichi Iwata, K. Yoshida, H. Hamaguchi
    • Organizer
      20th International Conference on Raman Spectroscopy (ICORS2008)(Invited)
    • Place of Presentation
      London, UK
    • Year and Date
      20080817-20080822
  • [Presentation] Photochemical and Photophysical Processes in Room-temperature Ionic Liquids Studied by Ultrafast Time-resolved Spectroscopy2008

    • Author(s)
      Koichi Iwata
    • Organizer
      Trombay Symposium on Radiation and Photochemistry (TSRP2008)(Invited)
    • Place of Presentation
      Pune, India
    • Year and Date
      20080107-20080111
  • [Presentation] Picosecond Time-resolved Raman and Fluorescence Studies of Ionic Liquids : Disagreement between Macroscopic and Microscopic Properties2007

    • Author(s)
      Koichi Iwata
    • Organizer
      2nd International Congress on Ionic Liquids (COIL-2)
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      20070805-20070810
  • [Presentation] Chemical reactions in ionic liquids studied by picosecond time-resolved Raman spectroscopy and femtosecond time-resolved near-infrared spectroscopy2007

    • Author(s)
      Koichi Iwata
    • Organizer
      Structure and Dynamics of Ionic Liquids
    • Place of Presentation
      Kazusa, Japan
    • Year and Date
      20070802-20070804
  • [Presentation] Fast dynamics in ionic liquids probed with time-resolved spectroscopy : Raman, fluorescence, and near-infrared2007

    • Author(s)
      Koichi Iwata
    • Organizer
      The First Asian Spectroscopy Conference (ASC'07)(Invited)
    • Place of Presentation
      Bangalore, India
    • Year and Date
      20070128-20070202
  • [Presentation] Vibrational Dynamics in Ionic Liquids Observed with Picosecond Time-Resolved Raman Spectroscopy2006

    • Author(s)
      Koichi Iwata, Yuta Takada, Kyousuke Yoshida, Hiro-o Hamaguchi
    • Organizer
      20th International Conference on Raman Spectroscopy (ICORS2006)(Invited)
    • Place of Presentation
      Yokohama, Japan
    • Year and Date
      20060820-20060825
  • [Book] 第5版実験化学講座9『物質の構造I分光上』(第8.2.1節ラマン散乱の測定装置" 第8.2.2節測定上の注意" 第8.3.4節時間分解ラマン")2005

    • Author(s)
      岩田耕一
    • Total Pages
      506-513(513-526,560-567)
    • Publisher
      丸善
  • [Remarks] ホームページ等

    • URL

      http://www-cc.gakushuin.ac.jp/~20040130/index.htm

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Published: 2012-02-13   Modified: 2016-04-21  

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