2009 Fiscal Year Final Research Report
Controlled Dynamic Behavior of Interlocked Molecules with Metal Template Motifs
| Project/Area Number |
18064008
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
TAKATA Toshikazu Tokyo Institute of Technology, 大学院・理工学研究科, 教授 (40179445)
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| Co-Investigator(Kenkyū-buntansha) |
KOYAMA Yasuhito 東京工業大学, 大学院・理工学研究科, 助教 (10456262)
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| Project Period (FY) |
2006 – 2009
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| Keywords | ロタキサン / パラジウム / 触媒 / 相互作用 / 空間結合 |
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| Research Abstract |
Rotaxanes possessing catalytic functions have attracted much attention due to their unique structures consisting of mechanically linked components and their properties. The use of the rotaxane-based molecules as a reaction template enables the amplification of weak interactions by a proximity effect between the components, providing an ideal scaffold to evaluate the inherence of interaction between the elements. This study is focused on an evaluation of synergy effect generated between a transition metal and typical elements. On the basis of these results, we developed a new rotaxane catalyst and linear molecular motor including the rotaxane skeleton as a key unit.
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[Presentation] Synthesis2008
Author(s)
Toshikazu Takata
Organizer
Properties and Application of Rotaxanes Formed by Utilizing Dynamic Covalent Bond
Place of Presentation
Universidad Autonoma de Madrid, Madrid.
Year and Date
2008-07-10
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