2009 Fiscal Year Final Research Report
Fine Control of Metal Arrangement in Transition Metal Clusters
| Project/Area Number |
18064011
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Osaka University |
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Principal Investigator |
MURAHASHI Tetsuro Osaka University, 工学研究科, 准教授 (40314380)
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| Project Period (FY) |
2006 – 2009
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| Keywords | 金属クラスター / 構造制御 / 金属-金属間結合 / 金属錯体 |
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| Research Abstract |
The one-dimensional metal wires or two-dimensional metal sheets are the attractive class of metal assemblies for catalysis and materials science. However, it has been difficult to construct such low-dimensional metal frameworks in a discrete molecule, because the synthetic method to build-up the low-dimensional metal assembly in a size- and shape-selective manner has not developed. In this project, we successfully developed an efficient method to construct low-dimensional metal assemblies by means of an organometallic approach.
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