2009 Fiscal Year Final Research Report
Development of Bio-inspired Catalytic Reactions in Water
| Project/Area Number |
18065017
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| Research Category |
Grant-in-Aid for Scientific Research on Priority Areas
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| Allocation Type | Single-year Grants |
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| Review Section |
Science and Engineering
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| Research Institution | Kyushu University |
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Principal Investigator |
SEIJI Ogo Kyushu University, 大学院・工学研究院, 教授 (60290904)
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| Project Period (FY) |
2006 – 2009
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| Keywords | 水中 / 水素 / 電子 / 錯体 / 触媒 |
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| Research Abstract |
The catalytic mimic of hydrogenase has been a long-standing challenge in the study of activation of hydrogen gas. The NiRu model complexes mimic the major features of hydrogenase, that is : heterolytic hydrogen activation, electron extraction, and simultaneous isotope exchange. The key mechanistic aspects are the proton-like character of the hydride intermediate, the activation of a second molecule of hydrogen gas during each cycle, and the possibility of positive ion exchange, which produces simultaneous, not sequential isotope exchange.
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[Journal Article] A Dinuclear Ni(μ-H)Ru Complex Derived from H2.2007
Author(s)
Ogo, Seiji;* Kabe, Ryota; Uehara, Keiji; Kure, Bunsho; Nishimura, Takashi; Menon, Saija C.; Harada, Ryosuke; Fukuzumi, Shunichi; Higuchi, Yoshiki; Ohhara, Takashi; Tamada, Taro; Kuroki, Ryota.
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Journal Title
Science 316(5824)
Pages: 585-587
Peer Reviewed
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