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2010 Fiscal Year Final Research Report

Studies on Diversity and Synergy of Elements Directed toward Organic Synthesis

Research Project

  • PDF
Project/Area Number 18105004
Research Category

Grant-in-Aid for Scientific Research (S)

Allocation TypeSingle-year Grants
Research Field Synthetic chemistry
Research InstitutionThe University of Tokyo

Principal Investigator

NAKAMURA Eiichi  The University of Tokyo, 大学院・理学系研究科, 教授 (00134809)

Co-Investigator(Kenkyū-buntansha) YOSHIKAI Naohiko  南洋理工大学(シンガポール), 助教授 (50401170)
Project Period (FY) 2006 – 2009
Keywords均一系触媒 / 炭素-炭素結合生成 / π電子系化合物 / 有機デバイス
Research Abstract

The present research aimed at mechanistic understanding-driven design of organic synthetic reactions. Thus, we developed highly efficient, stereoselective and functional group-tolerant carbon-carbon bond formation reactions, taking advantage of the reactivity of group 8-13 transition metals and the understanding of their multimetallic cooperation. Fully utilizing element diversity and multimetallic cooperation, we developed synthetic methods of high efficiency, high selectivity and sustainability, and applied these methods for the creation of novelπ-electronic materials for organoelectronic devices.

  • Research Products

    (15 results)

All 2010 2009 2008 2007 2006 Other

All Journal Article (6 results) Presentation (3 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (4 results)

  • [Journal Article] Bis(carbazolyl)benzodifuran : A High-mobility Ambipolar Material for Homojunction Organic Light-emitting Diode Devices2009

    • Author(s)
      H.Tsuji, C.Mitsui, Y.Sato, E.Nakamura
    • Journal Title

      Adv.Mater. 21

      Pages: 3776-3779

  • [Journal Article] Mechanistic Study of the Manganese-Catalyzed [2+2+2] Annulation of 1,3-Dicarbonyl Compound and Terminal Alkynes2009

    • Author(s)
      N.Yoshikai, S.-L.Zhang, K.-i.Yamagata, H.Tsuji, E.Nakamura
    • Journal Title

      J.Am.Chem.Soc. 131

      Pages: 4099-4109

  • [Journal Article] Ligand Exchange as the First Irreversible Step in the Nickel-Catalyzed Cross-Coupling Reaction of Grignard Reagents2008

    • Author(s)
      N.Yoshikai, H.Matsuda, E.Nakamura
    • Journal Title

      J.Am.Chem.Soc. 130

      Pages: 15258-15259

  • [Journal Article] Manganese-Catalyzed Benzene Synthesis by [2+2+2] Coupling of 1,3-Dicarbonyl Compound and Terminal Acetylene2008

    • Author(s)
      H.Tsuji, K.Yamagata, T.Fujimoto, E.Nakamura
    • Journal Title

      J.Am.Chem.Soc. 130

      Pages: 7792-7793

  • [Journal Article] Iron-Catalyzed Direct Arylation through Directed C-H Bond Activation2008

    • Author(s)
      J.Norinder, A.Matsumoto, N.Yoshikai, E.Nakamura
    • Journal Title

      J.Am.Chem.Soc. 130

      Pages: 5858-5859

  • [Journal Article] Synthesis and Properties of 2,3,6,7-Tetraarylbenzo[1,2-b:4,5-b']difuran s as Hole-Transporting Material2007

    • Author(s)
      H.Tsuji, C.Mitsui, L.Ilies, Y.Sato, E.Nakamura
    • Journal Title

      J.Am.Chem.Soc. 129

      Pages: 11902-11903

  • [Presentation] Organo electronics research guided by new reactions and new molecules2010

    • Author(s)
      Eiichi Nakamura
    • Organizer
      The International Chemical Congress of Pacific Basin Societies (Pacifichem 2010)
    • Place of Presentation
      Honolulu, Hawaii, USA
    • Year and Date
      2010-12-15
  • [Presentation] Activation of Unreactive Carbon-Halogen and Carbon-Hydrogen Bonds by2008

    • Author(s)
      N.Yoshikai
    • Organizer
      Transition Metal Catalysis of Nucleophilic Organometallics
    • Place of Presentation
      Columbia University, New York, USA
    • Year and Date
      2008-12-05
  • [Presentation] New Metallo Enamine Chemistry2007

    • Author(s)
      E.Nakamura
    • Place of Presentation
      Wyeth Lecture , University of Pennsylvania, Philadelphia, USA
    • Year and Date
      2007-05-02
  • [Book] Chemistry of Organocopper Compounds(Theory of Organocopper-Mediated Reactions)(Z.Rappoport, I.Marek Eds.)

    • Author(s)
      E.Nakamura, N.Yoshikai
    • Publisher
      John Wiley & Sons
  • [Remarks] ホームページ等

    • URL

      http://www.chem.s.u-tokyo.ac.jp/users/common/NakamuraLab.html

  • [Patent(Industrial Property Rights)] 芳香族アミン化合物を用いた有機電界発光素子2010

    • Inventor(s)
      中村栄一, 佐藤佳晴, 辻勇人, 三津井親彦
    • Industrial Property Rights Holder
      独立行政法人科学技術振興機構
    • Industrial Property Number
      特許,第4583470
    • Acquisition Date
      2010-11-17
  • [Patent(Industrial Property Rights)] インダセン誘導体及びその製造方法,並びに炭素架橋p-フェニレンビニレン誘導体及びその製造方法2009

    • Inventor(s)
      中村栄一, 辻勇人, 朱曉張
    • Industrial Property Rights Holder
      国立大学法人東京大学
    • Industrial Property Number
      特願,2009-178975
    • Filing Date
      2009-07-31
  • [Patent(Industrial Property Rights)] 芳香族アミン化合物を用いた有機電界発光素子2007

    • Inventor(s)
      中村栄一, 佐藤佳晴, 辻勇人, 三津井親彦
    • Industrial Property Rights Holder
      独立行政法人科学技術振興機構,佐藤佳晴
    • Industrial Property Number
      特願,2007-122892
    • Filing Date
      2007-05-07
  • [Patent(Industrial Property Rights)] 光学活性三級ホスフィン化合物,これを配位子とする金属錯体およびその用途2006

    • Inventor(s)
      中村栄一, アラカナンダハジュラ, 吉戒直彦
    • Industrial Property Rights Holder
      国立大学法人東京大学
    • Industrial Property Number
      特願,2006-142601
    • Filing Date
      2006-05-23

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Published: 2012-01-26   Modified: 2016-04-21  

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