2010 Fiscal Year Final Research Report
Synthesis and Regulated Functions of Multinuclear Transition Metal Complexes Based on Tetranuclear Palladium and Platinum Complexes
| Project/Area Number |
19205008
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Tokyo Institute of Technology |
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Principal Investigator |
OSAKADA Kohtaro Tokyo Institute of Technology, 資源化学研究所, 教授 (00152455)
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| Project Period (FY) |
2007 – 2010
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| Keywords | パラジウム / 白金 / 多核錯体 / ケイ素配位子 / 平面構造 |
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| Research Abstract |
A number of tetranuclear complexes of Pd and Pt containing the bridging Si and Ge ligands were prepared. The synthetic reactions proceeds smoothly and recversibly, and are revealed to show high generality. The tetranucelar complexes react with CuI and AgI to afford hetero-pentanuclear complexes and with thiol to produce the linear tetrapalladium complexes or hexanuclear palladium complexes.
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