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2010 Fiscal Year Final Research Report

Peculiar electrode activity in localized electron system

Research Project

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Project/Area Number 19205027
Research Category

Grant-in-Aid for Scientific Research (A)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionTokyo Institute of Technology

Principal Investigator

YAMADA Atsuo  Tokyo Institute of Technology, 大学院・工学系研究科, 教授 (30359690)

Co-Investigator(Kenkyū-buntansha) NISHIMURA Shinichi  東京大学, 大学院・工学系研究科, 主任研究員 (00549264)
Co-Investigator(Renkei-kenkyūsha) SHIRO Seki  電力中央研究所, 材料化学研究所, 主任研究員 (70371325)
YASHIMA Masatomo  東京大学, 大学院・理工学研究科, 教授 (00239740)
KANNO Ryoji  東京工業大学, 大学院・総合理工学研究, 教授 (90135426)
Project Period (FY) 2007 – 2010
Keywordsリチウム電池 / 正極 / 拡散 / 相分離
Research Abstract

We have focused on the electrode function of insulating materials which had been believed inactive. Some compounds with high activity were discovered during the project, of which structure was also determined. Atomic-scale anisotropic lithium diffusion and subsequent clustering, together with their kinetics, were experimentally elucidated. Thermodynamic approach was made to understand the size-dependency of these phenomena.

  • Research Products

    (44 results)

All 2011 2010 2009 2008 2007 Other

All Journal Article (27 results) (of which Peer Reviewed: 27 results) Presentation (11 results) Book (3 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results) (of which Overseas: 2 results)

  • [Journal Article] More on the reactivity of olivine LiFePO4 nano-particles with atmosphere at moderate temperature2011

    • Author(s)
      Jean-Frederic Martin, Marine Cuisinier, Nicolas Dupre, Atsuo Yamada, Ryoji Kanno, Dominique Guyomard
    • Journal Title

      Journal of Power Sources 196

      Pages: 2155-2163

    • Peer Reviewed
  • [Journal Article] New three-dimensional electrode structure for the lithium battery : Nano-sized gamma-Fe2O3 in a mesoporous carbon matrix2011

    • Author(s)
      Miki Nagao, Michiko Otani, Hiroki Tomita, Sho Kanzaki, Atsuo Yamada, Ryoji Kanno
    • Journal Title

      Journal of Power Sources 196

      Pages: 4741-4746

    • Peer Reviewed
  • [Journal Article] Relationship between surface chemistry and electrochemical behavior of LiNi1/2Mn1/2O2 positive electrode in a lithium-ion battery2011

    • Author(s)
      Nicolas Dupre, Jean-Frederic Martin, Julie Oliveri, Patrick Soudan, Atsuo Yamada, Ryoji Kanno, Dominique Guyomard
    • Journal Title

      Journal of Power Sources 196

      Pages: 4791-4800

    • Peer Reviewed
  • [Journal Article] Lithium iron borates as high capacity battery electrodes2010

    • Author(s)
      Atsuo Yamada, Nobuyuki Iwane, Yu Harada, Shin-ichi Nishimura, Yukinori Koyama, Isao Tanaka
    • Journal Title

      Advanced Materials 22

      Pages: 3583-3587

    • Peer Reviewed
  • [Journal Article] Special issue to ICMAT 2009, Symposium F : nanostructured materials for electrochemical energy systems : lithium batteries, supercapacitors and fuel cells, June 28-July 3, 2009, Singapore2010

    • Author(s)
      Balaya Palani, Jiang San Ping, Yamada Atsuo, Chowdari B.V.R.
    • Journal Title

      Journal of Solid State Electrochemistry 14(10)

      Pages: 1741-1742

    • Peer Reviewed
  • [Journal Article] Moisture driven aging mechanism of LiFePO4 subjected to air exposure2010

    • Author(s)
      M.Cuisinier, J.F.Martin, N.Dupre, A.Yamada, R.Kanno, D.Guyomard
    • Journal Title

      Electrochemistry Communications 12

      Pages: 238-241

    • Peer Reviewed
  • [Journal Article] Tailoring the electrochemical properties of composite electrodes by introducing surface redox-active oxide film : VOx-impregnated LiFePO4 electrode2010

    • Author(s)
      Kyu-Sung Park, Anass Benayad, Min-Sik Park, Atsuo Yamada, Seok-Gwang Doo
    • Journal Title

      Chemical Communications 46

      Pages: 2572-2574

    • Peer Reviewed
  • [Journal Article] Synthesis of LixMnO2 by chemical lithiation in an aqueous media2010

    • Author(s)
      Won Il Jung, Miki Nagao, Cedric Pitteloud, Atsuo Yamada, Ryoji Kanno
    • Journal Title

      Journal of Power Sources 195

      Pages: 3328-3332

    • Peer Reviewed
  • [Journal Article] Structure and electrode properties of new polyanion-based cathodes2010

    • Author(s)
      Atsuo Yamada
    • Journal Title

      Battery Technology 22

      Pages: 37-47

    • Peer Reviewed
  • [Journal Article] All solid-state sheet battery using lithium inorganic solid electrolyte, thio-LISICON2009

    • Author(s)
      Taro Inada, Takeshi Kobayashi, Noriyuki Sonoyama, Atsuo Yamada, Shigeo Kondo, Miki Nagao, Ryoji Kanno
    • Journal Title

      Journal of Power Sources 194(2)

      Pages: 1085-1088

    • Peer Reviewed
  • [Journal Article] Surface Structure of LiNi0.8Co0.2O2 : a New Experimental Technique Using in Situ X-ray Diffraction and Two-Dimensional Epitaxial Film Electrodes2009

    • Author(s)
      K.Sakamoto, M.Hirayama, N.Sonoyama, D.Mori, A.Yamada, K.Tamura, J.Mizuki, R.Kanno
    • Journal Title

      Chemistry of Materials 21(13)

      Pages: 2632-2640

    • Peer Reviewed
  • [Journal Article] Shift of Redox Potential and Kinetics in Lix(MnyFe1-y)PO42009

    • Author(s)
      Genki Kobayashi, Atsuo Yamada, Shin-ichi Nishimura, Ryoji Kanno, Yo Kobayashi, Shiro Seki, Yasutaka Ohno, Hajime Miyashiro
    • Journal Title

      Journal of Power Sources 189

      Pages: 397-401

    • Peer Reviewed
  • [Journal Article] Isolation of Solid Solution Phses in Size-Controlled LixFePO4 at Room Temperature2009

    • Author(s)
      Genki Kobayashi, Shin-ichi Nishimura, Ryoji Kanno, Masatomo Yamashita, Takashi Ida, Atsuo Yamada
    • Journal Title

      Advanced Functional Materials 18(3)

      Pages: 395-403

    • Peer Reviewed
  • [Journal Article] Aging of the LiNi1/2Mn1/2O2 Positive Electrode Interface in Electrolyte2009

    • Author(s)
      Nicolas Dupre, Jean-Frederic Martin, Julie Oliveri, Patrick Soudan, Dominique Guyomard, Atsuo Yamada, Ryoji Kanno
    • Journal Title

      Journal of The Electrochemical Society 156(5)

      Pages: C180-C185

    • Peer Reviewed
  • [Journal Article] Structural investigation of Eu2+ emissions from alkaline earth zirconium phosphate2009

    • Author(s)
      Masaaki Hirayama, Noriyuki Sonoyama, Atsuo Yamada, Ryoji Kanno
    • Journal Title

      Journal of Power Sources 189(2)

      Pages: 1154-1163

    • Peer Reviewed
  • [Journal Article] Structural and magnetic properties of Lix(MnyFe1-y)PO4 electrode materials for Li-ion batteries2009

    • Author(s)
      M.Kopec, A.Yamada, G.Kobayashi, S.Nishimura, R.Kanno, A.Mauger, F.Gendron, C.M.Julien
    • Journal Title

      Journal of Power Sources 189(2)

      Pages: 1154-1163

    • Peer Reviewed
  • [Journal Article] Characterization of interphases appearing on LiNi0.5Mn0.5O2 using 7Li MAS NMR2009

    • Author(s)
      Nicolas Dupre, Jean-Frederic Martin, Dominique Guyomard, Atsuo Yamada, Ryoji Kanno
    • Journal Title

      Journal of Power Sources 189(1)

      Pages: 557-560

    • Peer Reviewed
  • [Journal Article] Chemically oxidized γ-MnO2 for lithium secondary batteries : structure and intercalation/deintercalation properties2009

    • Author(s)
      Won Il Jung, Miki Nagao, Cedric Pitteloud, Keiji Itoh, Atsuo Yamada, Ryoji Kanno
    • Journal Title

      J.Mater.Chem. 19

      Pages: 800-806

    • Peer Reviewed
  • [Journal Article] Structure of Li2FeSiO42008

    • Author(s)
      Shin-ichi Nishimura, Shogo Hayase, Ryoji Kanno, Masatomo Yashima, Noriaki Nakayama, Atsuo Yamada
    • Journal Title

      Journal of the American Chemical Society 130(40)

      Pages: 13212-13213

    • Peer Reviewed
  • [Journal Article] Experimental visualization of lithium diffusion in LixFePO42008

    • Author(s)
      Shin-ichi Nishimura, Genki Kobayashi, Kenji Ohoyama, Ryoji Kanno, Masatomo Yashima, Astuo Yamada
    • Journal Title

      Nature Materials 7

      Pages: 707-711

    • Peer Reviewed
  • [Journal Article] Relationship between structural characteristics and photoluminescent properties of (La1-xEux)2M2O7 (M=Zr,Hf,Sn) pyrochlores2008

    • Author(s)
      Masaaki Hirayama, Noriyuki Sonoyama, Astuo Yamada, Ryoji Kanno
    • Journal Title

      Journal of luminescence 128(11)

      Pages: 1819-1825

    • Peer Reviewed
  • [Journal Article] Electrochemical luminescence of Mg1-xCaxIn2O4:Er3+ electrodes2008

    • Author(s)
      Noriyuki Sonoyama, ken Kawamura, Atsuo Yamada, Ryoji Kanno
    • Journal Title

      Journal of Luminescence 128(10)

      Pages: 1679-1683

    • Peer Reviewed
  • [Journal Article] Interfacial reactions at electrode/electrolyte boundary in all solid-state lithium battery using inorganic solid electrolyte, thio-LISICON2008

    • Author(s)
      Takeshi Kobayashi, Atsuo Yamada, Ryoji Kanno
    • Journal Title

      Electrochimica Acta 53(15)

      Pages: 5045-5050

    • Peer Reviewed
  • [Journal Article] Air Exposure Effect on LiFePO42008

    • Author(s)
      Jean Frederic Martin, Atsuo Yamada, Genki Kobayashi, Shin-ichi Nishimura, Ryoji Kanno, Dominique Guyomard, Nicolas Dupre
    • Journal Title

      Electrochemical and Solid-State Letters 11(1)

      Pages: A12-A16

    • Peer Reviewed
  • [Journal Article] Detection of surface layers using 7Li MAS NMR2008

    • Author(s)
      N.Dupre, J-F.Martin, J.Oliveri, P.Soudan, D.Guyomard, A.Yamada, R.Kanno
    • Journal Title

      J.Mater.Chem. 18

      Pages: 4266-4273

    • Peer Reviewed
  • [Journal Article] Unique control of bulk reactivity by surface phenomena in a positive electrode of lithium battery2008

    • Author(s)
      N.Dupre, J-F.Martin, J.Oliveri, D.Guyomard, A.Yamada, R.Kanno
    • Journal Title

      Electrochem.Comm. 10(12)

      Pages: 1897-1900

    • Peer Reviewed
  • [Journal Article] Characterization of Interfaces Appearing on LiNi0.5Mn0.5O2 Using 7Li MAS NMR2008

    • Author(s)
      N.Dupre, J-F.Martin, J.Oliveri, D.Guyomard, A.Yamada, R.Kanno
    • Journal Title

      J.Power Sources. 189(1)

      Pages: 557-560

    • Peer Reviewed
  • [Presentation] LixFePO4における相図の指標としての着色現象2011

    • Author(s)
      古月翔, 夏井竜一, 西村真一, 工藤友佑, 山下晃一, 山田淳夫
    • Organizer
      電気化学会第78回大会,2L07
    • Year and Date
      2011-03-30
  • [Presentation] Cathode Materials for Large-Scale Lithium-Ion Batteries2010

    • Author(s)
      山田淳夫
    • Organizer
      International Congress on Materials and Technologies, 12th International Ceramics Congress, Montecattini Terme, Italy
    • Year and Date
      20100000
  • [Presentation] Borates as High-Capacity Cathodes2010

    • Author(s)
      N.Iwane, Y.Harada, S.Nishimura, Y.Koyama, I.Tanaka, A.Yamada,
    • Organizer
      International Meeting on Lithium Batteries (IMLB 2010), Abs. 650
    • Year and Date
      2010-07-01
  • [Presentation] Polymorphism and Structural Defect in Lithium Transition Metal Silicate Li2FeSiO4 and Li2MnSiO42010

    • Author(s)
      西村真一, 早瀬章吾, 菅野了次, 中山則昭, 山田淳夫
    • Organizer
      International Meeting on Lithium Batteries (IMLB 2010), Abs. 500
    • Year and Date
      2010-06-29
  • [Presentation] Li2MSiO4(M=Fe,Mn)の結晶構造2009

    • Author(s)
      西村真一, 早瀬章吾, 菅野了次, 八島正知, 中山則昭, 山田淳夫
    • Organizer
      電気化学会第76回大会, 1M24
    • Year and Date
      2009-03-29
  • [Presentation] Avramiモデルに基づく粒径制御されたLixFePO4における相境界移動現象の解析2009

    • Author(s)
      夏井竜一, 小林玄器, 西村真一, 山田淳夫, 菅野了次
    • Organizer
      電気化学会第76回大会,1O26
    • Year and Date
      2009-03-29
  • [Presentation] Three Experimental Verifications on LixFePO4 : (i) Bulk Miscibility Gap, (ii) Air Exposure Effect, and (iii) Lithium Diffusion2008

    • Author(s)
      山田淳夫
    • Organizer
      1st International Conference on Advanced Lithium Batteries for Automobile Applications
    • Place of Presentation
      Argonne, USA
    • Year and Date
      20080000
  • [Presentation] Li2FeSiO4の結晶構造決定2008

    • Author(s)
      西村真一, 早瀬章吾, 山田淳夫, 菅野了次, 八島正知, 中山則昭
    • Organizer
      第49回電池討論会,1F14
    • Year and Date
      2008-11-05
  • [Presentation] 室温でのLixFePO4固溶相(0.9<x<1)の単離2008

    • Author(s)
      小林玄器, 西村真一, 山田淳夫, 菅野了次, 八島正知, 井田隆
    • Organizer
      電気化学第75回大会,1A35
    • Year and Date
      2008-03-29
  • [Presentation] Combined Structural, Electrochemical, and Thermodynamic Studies on Various LixMPO4 Olivine Compounds2007

    • Author(s)
      山田淳夫
    • Organizer
      International Symposium on Novel Materials and Synthesis
    • Place of Presentation
      Shanghai, China
    • Year and Date
      20070000
  • [Presentation] Synthesis and Electrochemistry of Monoclinic Li(MnxFe1-x)BO3 : A Combined Experimental and Computational Study

    • Author(s)
      A.Yamada, N.Iwane, Y.Harada, 西村真一, Y.Koyama, I.Tanaka
    • Organizer
      2011 MRS Spring Meeting, L4.3
    • Place of Presentation
      20110427
  • [Book] 電池ハンドブック-3編(15章回折法)(山木準一監修)2010

    • Author(s)
      山田淳夫
    • Total Pages
      126-131
    • Publisher
      オーム社
  • [Book] 電池ハンドブック-8編(3章11節オリビン型LiFePO4正極)(山木準一監修)2010

    • Author(s)
      山田淳夫
    • Total Pages
      480-484
    • Publisher
      オーム社
  • [Book] 電池ハンドブック-8編(3章12節LiFePO4類縁化合物正極)(山木準一監修)2010

    • Author(s)
      山田淳夫
    • Total Pages
      485-490
  • [Remarks] ホームページ等

    • URL

      http://www.yamada-lab.t.u-tokyo.ac.jp/index.html

  • [Patent(Industrial Property Rights)] ピロリン酸塩化合物およびその製造方法2010

    • Inventor(s)
      山田淳夫、西村真一、夏井竜一
    • Industrial Property Rights Holder
      山田淳夫、西村真一、夏井竜一
    • Industrial Property Number
      特願,2009-276513
    • Filing Date
      2010-12-03
    • Overseas
  • [Patent(Industrial Property Rights)] 2次電池正極材料の製造方法2008

    • Inventor(s)
      山田淳夫、早瀬章吾、藤田善岐、西村真一、立川守、日野賢一
    • Industrial Property Rights Holder
      山田淳夫、早瀬章吾、藤田善岐、西村真一、立川守、日野賢一
    • Industrial Property Number
      特願,2007-315091
    • Filing Date
      2008-03-26
    • Overseas

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Published: 2012-01-26   Modified: 2013-05-07  

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