2009 Fiscal Year Final Research Report
Development of novel molecular films based on self-assembly of coordination compounds
| Project/Area Number |
19205030
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| Research Category |
Grant-in-Aid for Scientific Research (A)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer/Textile materials
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| Research Institution | Kyushu University |
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Principal Investigator |
KIMIZUKA Nobuo Kyushu University, 大学院・工学研究院, 教授 (90186304)
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| Co-Investigator(Renkei-kenkyūsha) |
KUROIWA Keita 九州大学, 大学院・工学研究院, 助教 (70336006)
MORIKAWA Masa-aki 九州大学, 大学院・工学研究院, 助教 (10363384)
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| Project Period (FY) |
2007 – 2009
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| Keywords | ナノ金属錯体 / トリアゾール / 自己組織化 |
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| Research Abstract |
We developed the lipid packageing technique to 1D Fe^<11> 1,2,4-triazole complexes. Surprisingly, the complex leads to the stabilization of low spin (LS) complexes in organic media and consequent control of spin conversion via dynamic self-assembly of linear coordination chain. Therefore, supramolercular control of coordination polymer or introduction of dynamic self-assembly are of great value to optimize the spin state in organic media.
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[Journal Article] Nanoparticles of Adaptive Supramolecular Networks Self-Assembled from Nucleotides and Lanthanide Ions2009
Author(s)
Ryuhei Nishiyabu, Nozomi Hashimoto, Ten Cho, Kazuto Watanabe, Takefumi Yasunaga, Ayataka Endo, Kenji Kaneko, Takuro Niidome, Masaharu Murata, Chihaya Adachi, Yoshiki Katayama, Makoto Hashizume, Nobuo Kimizuka
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Journal Title
J. Am. Chem. Soc 131
Pages: 2151-2158
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