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2010 Fiscal Year Final Research Report

Searches for clay minerals with asymmetric structures and their identification

Research Project

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Project/Area Number 19340159
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Petrology/Mineralogy/Science of ore deposit
Research InstitutionOchanomizu University

Principal Investigator

YAMAGISHI Akihiko  Ochanomizu University, 理学部, 訪問教授 (70001865)

Co-Investigator(Kenkyū-buntansha) KOGURE Toshihiro  東京大学, 理学研究科, 准教授 (50282728)
INOUE Atsuyuki  千葉大学, 理学部, 教授 (30150270)
Project Period (FY) 2007 – 2010
Keywords不斉構造 / 粘土鉱物
Research Abstract

This project aimed at searching clay minerals with asymmetric structures and identifying their chiral structures. As a result, the presence of single crystals of chiral kaolinite was confirmed by scanning electron microscopy. By applying the method of liquid column chromatography, a racemic mixture of kaolinite particles was attempted to be resolved into a pair of opposite enantiomers. The ultra-thin film of clay single layers was prepared by applying the Langmuir-Blodgett method.

  • Research Products

    (18 results)

All 2011 2010 2009

All Journal Article (9 results) (of which Peer Reviewed: 9 results) Presentation (8 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Hybridization of Clay Minerals with the Floating Film of a Cationic Ir(III) Complex at an Air-water Interface2011

    • Author(s)
      Hisako Sato, Kenji Tamura, Keishi Ohara, Shin-ichi Nagaoka, Akihiko Yamagishi
    • Journal Title

      New Journal of Chemistry 35

      Pages: 394-399

    • Peer Reviewed
  • [Journal Article] Enantioselective Sensing by Luminescence from Cyclometalated Iridium (III) Complexes Adsorbed on a Colloidal Saponite2011

    • Author(s)
      Hisako Sato, Kenji Tamura, R ie Aoki, Masako Kato, Akihiko Yamagishi
    • Journal Title

      Chem.Lett. 40

      Pages: 65-67

    • Peer Reviewed
  • [Journal Article] Effect of Coccolith Polysaccharides Isolated from the occolithophorid, Emiliania huxleyi, on Calcite Crystal Formation in In Vitro CaCO3 Crystallization2011

    • Author(s)
      Kayano K., K. Saruwatari, T. Kogure, Yoshihiro Shiraiwa
    • Journal Title

      Marine Biotechnology 13

      Pages: 83-92

    • Peer Reviewed
  • [Journal Article] Fabrication of Anatase Thin Film with Perfect c-Axis Orientation on Glass Substrate Promoted by a Two-Dimensional Perovskite Nanosheet Seed Layer2010

    • Author(s)
      Shibata T., Y. Ebina, T. Ohnishi, K. Takada, T. Kogure, T. Sasaki
    • Journal Title

      Cryst. Growth Des. 10

      Pages: 3787-3793

    • Peer Reviewed
  • [Journal Article] Application of Chlorite Geothermometry to Hydrothermal Alteration in Toyoha Geothermal System, Southwestern Hokkaido, Japan2010

    • Author(s)
      A. Inoue, K. Kurokawa, T. Hatta
    • Journal Title

      Resource Geeology 60

      Pages: 52-70

    • Peer Reviewed
  • [Journal Article] Highly Luminescent Langmuir-Blodgett Films of Amphiphilic Ir(III) Complexes for an Application of Gas Sensing2010

    • Author(s)
      Hisako Sato, Kenji Tamura, Masahiro Taniguchi, Akihiko Yamagishi
    • Journal Title

      New Journal of Chemistry(2010) 34

      Pages: 617-622

    • Peer Reviewed
  • [Journal Article] Molecular Recognition of Star-burst Tetranuclear Ru(III) Complexes on a Chirally Modified Clay Surface2010

    • Author(s)
      Noriko Fujimoto, Yukie Mori, Akihiko Yamagishi, Hisako Sato
    • Journal Title

      J.Chem.Soc., Chem., Comm. 46

      Pages: 5473-5475

    • Peer Reviewed
  • [Journal Article] Non-centrosymmetric behavior of a clay film ion-exchanged with chiral metal complexes2009

    • Author(s)
      Suzuki Y., R. Matsunaga, H. Sato, T. Kogure, A. Yamagishi, J. Kawamata
    • Journal Title

      Chem.Commun. 45

      Pages: 6964-6966

    • Peer Reviewed
  • [Journal Article] Well-controlled crystal growth of zinc oxide films on plastics at room temperature using 2D nanosheet seed layer2009

    • Author(s)
      Shibata, T., T. Ohnishi, I. Sakaguchi, M. Osada, K. Takada, T. Kogure, T. Sasaki
    • Journal Title

      J.Phys.Chem.C 113

      Pages: 19096-19101

    • Peer Reviewed
  • [Presentation] イリジウム金属錯体とモンモリロナイトハイブリッドLB膜の発光挙動2010

    • Author(s)
      佐藤久子、中江隆博、田村堅志、山岸晧彦
    • Organizer
      第29回 無機高分子研究討論会
    • Place of Presentation
      東京
    • Year and Date
      20101112-20101113
  • [Presentation] アミノ基含有ラダー型ポリシルセスキオキサンへのキラル基の導入とナノ構造制御2010

    • Author(s)
      金子芳郎、豊留寿也、佐藤久子、山岸晧彦
    • Organizer
      第29回 無機高分子研究討論会
    • Place of Presentation
      東京
    • Year and Date
      20101111-20101112
  • [Presentation] 混合配位子錯体の幾何異性に対する振動円二色性分光法による研究2010

    • Author(s)
      佐藤久子、宇野英満、中野晴之、山岸晧彦
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      20100927-20100930
  • [Presentation] 配位性Ru(III)錯体を用いたキラルテクトニクスの構築2010

    • Author(s)
      山岸晧彦、藤本慎子、森幸恵、佐藤久子
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Year and Date
      20100927-20100930
  • [Presentation] キラル基含有ラダー型ポリシルセスキオキサンの創製とナノ構造制御2010

    • Author(s)
      金子芳郎、豊留寿也、佐藤久子、山岸晧彦
    • Organizer
      第59回 高分子討論会
    • Place of Presentation
      北海道(依頼講演)
    • Year and Date
      20100915-20100917
  • [Presentation] 一次元無機高分子へのキラル基の導入とナノ構造制御2010

    • Author(s)
      金子芳郎、豊留寿也、佐藤久子、山岸晧彦
    • Organizer
      第54回粘土科学討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      20100907-20100908
  • [Presentation] 粘土鉱物と発光性イリジウム錯体とのハイブリッドLB膜による発光挙動2010

    • Author(s)
      堤響子、中江隆博、田村堅志、山岸晧彦、佐藤久子
    • Organizer
      第54回粘土科学討論会
    • Place of Presentation
      名古屋大学
    • Year and Date
      20100907-20100908
  • [Presentation] 振動円二色性分光法の混合配位子錯体への応用2010

    • Author(s)
      佐藤久子、宇野英満、山岸晧彦
    • Organizer
      MC2010(モレキュラーキラリティ)
    • Place of Presentation
      北海道
    • Year and Date
      20100612-20100615
  • [Patent(Industrial Property Rights)] ハイブリッド膜およびガスセンサ2011

    • Inventor(s)
      佐藤、田村、山岸
    • Industrial Property Rights Holder
      愛媛大学
    • Industrial Property Number
      特許,特願2011-97322
    • Filing Date
      2011-04-25

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Published: 2012-01-26   Modified: 2015-07-14  

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