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2009 Fiscal Year Final Research Report

Supramolecular self-supporting membrane having chiral nano-channel from supramolecular ladder chiral double helical polymer

Research Project

  • PDF
Project/Area Number 19350054
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer chemistry
Research InstitutionNiigata University

Principal Investigator

AOKI Toshiki  Niigata University, 自然科学系, 教授 (80212372)

Co-Investigator(Kenkyū-buntansha) KANEKO Takashi  新潟大学, 超域研究機構, 教授 (90272856)
TERAGUCHI Masahiro  新潟大学, 自然科学系, 助教 (30334650)
NAMIKOSHI Takeshi  新潟大学, ベンチャー・ビジネス・ラボラトリー, VBL研究機関研究員 (30452072)
HADANO Shingo  京都大学, 工学研究科, 産学官連携研究員 (70397157)
Project Period (FY) 2007 – 2009
Keywordsらせん選択重合 / ラダー高分子 / キラルらせん高分子 / 膜 / 高分子反応 / 分解反応 / 自立膜 / 超分子膜
Research Abstract

独創的な構造を持つ「超分子ラダーキラル二重らせん高分子」を申請者らの見出した手法で数種類合成することに成功した。この高分子のみよりなる自立膜が、光により定量的な選択芳香族環化分解を行い、しかも自立膜性を保つことを見出した。これにより『超分子ポリマー膜』の新しい調製法、超高分子量ポリマーのミクロ構造分析法、キラルナノチャンネル超分子ポリマー自立膜の調製法を見出した。

  • Research Products

    (8 results)

All 2010 2009 2008 2007

All Journal Article (5 results) (of which Peer Reviewed: 3 results) Presentation (2 results) Patent(Industrial Property Rights) (1 results)

  • [Journal Article] Synthesis and helix-sense-selective polymerization of a novel phenylacetylene having a trisiloxanyl group and two hydroxyl groups and enantioselective permeability of the resulting chiral polymeric membrane2010

    • Author(s)
      Lijia Liu, Yoshiyuki Oniyama, Yu Zang, Shingo Hadano, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Takeshi Namikoshi
    • Journal Title

      Edy Marwanta, Polymer 51(in press)

    • Peer Reviewed
  • [Journal Article] Helix-Sense-Selective Polymerization of Achiral Bis(hydroxymethyl)phenylacetylenes Having an Alkyl Group of Different Lengths2009

    • Author(s)
      Shingo Hadano, Takuya Kishimoto, Tomonori Hattori, Daisuke Tanioka, Masahiro Teraguchi, Toshiki Aoki, Takashi Kaneko, Takeshi Namikoshi
    • Journal Title

      Edy Marwanta, Macromol. Chem. Phys 210(9)

      Pages: 717-727

    • Peer Reviewed
  • [Journal Article] Two Modes of Asymmetric Polymerization of Phenylacetylene Having a L-Valinol Residue and Two Hydroxy Groups2009

    • Author(s)
      Hongge Jia, Masahiro Teraguchi, Toshiki Aoki, Yunosuke Abe, Takashi Kaneko, Shingo Hadano, Takeshi Namikoshi
    • Journal Title

      Edy Marwanta, Macromolecules 42(1)

      Pages: 17-19

  • [Journal Article] Copper(I) Iodide Accelerates Catalytic Activation in Rhodium Complex-catalyzed Helix-sense-selective Polymerization of Achiral Phenylacetylene Monomers2008

    • Author(s)
      Hiroo Katagiri, Takashi Kaneko, Masahiro Teraguchi, Toshiki Aoki
    • Journal Title

      Chem. Lett 37(4)

      Pages: 390-391

    • Peer Reviewed
  • [Journal Article] Helix-Sense Tunability Induced by Achiral Diene Ligands in the Chiral Catalytic System for the Helix-Sense-Selective Polymerization of Achiral and Bulky Phenylacetylene Monomers2007

    • Author(s)
      Takashi Kaneko, Yasuhiro Umeda, Honge Jia, Shingo Hadano, Masahiro Teraguchi, Toshiki Aoki
    • Journal Title

      Macromolecules 40(20)

      Pages: 7098-7102

  • [Presentation] Function of one-handed helical backbone of polyphenylacetylenes2008

    • Author(s)
      Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
    • Organizer
      The 5th International Symposium on Advanced Materials in Asia-Pacific Rim (5th ISAMAP)
    • Place of Presentation
      Zhengzhou, China
    • Year and Date
      20080800
  • [Presentation] Synthesis and Properties of Chiral Polyphenylacetylenes Having their Chiral Structures Only in the Backbone2008

    • Author(s)
      Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko
    • Organizer
      International Symposium on Polymer Chemistry (PC'2008, Hefei)
    • Place of Presentation
      Hefei, China
    • Year and Date
      20080615-20080619
  • [Patent(Industrial Property Rights)] ポリフェニルアセチレン膜の芳香環形成による超分子自立膜の製造方法2009

    • Inventor(s)
      青木俊樹、金子隆司、浪越毅、寺口昌宏、鬼山祥幸、波多野慎悟、エディマルワンタ
    • Industrial Property Rights Holder
      新潟大学
    • Industrial Property Number
      特許権特願第2009-038313号
    • Filing Date
      20090000

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Published: 2011-06-18   Modified: 2016-04-21  

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