2009 Fiscal Year Final Research Report
Construction of Bio-inorganic Devices Having Chemical/Energy Conversion Functions
| Project/Area Number |
19350083
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Chemistry related to living body
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| Research Institution | Nagoya Institute of Technology |
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Principal Investigator |
MASUDA Hideki Nagoya Institute of Technology, 大学院・工学研究科, 教授 (50209441)
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| Co-Investigator(Kenkyū-buntansha) |
OZAWA Tomohiro 名古屋工業大学, 大学院・工学研究科, 准教授 (70270999)
FUNAHASHI Yasuhiro 名古屋工業大学, 大学院・工学研究科, 准教授 (00321604)
INOMATA Tomohiko 名古屋工業大学, 大学院・工学研究科, 助教 (40397493)
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| Project Period (FY) |
2007 – 2009
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| Keywords | 酸化触媒 / センサー / デバイス化 / ナノ細孔 / ナノ触媒 / エネルギー変換 / 物質変換 / 高選択的酸化反応 |
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| Research Abstract |
In biological systems, metallo-enzymes play catalytic functions under ambient conditions, so the biological reaction systems composed by such enzymes are environment-friendly catalytic reaction ones. Our aim is to develop the devices having such functions. We designed and prepared some bio-inorganic devices composed of metal complexes having chemical/energy conversion functions such as dioxygen activation, dinitrogen activation, hydrogen activation, nitrile activation, and so on.
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[Journal Article] The effect of the side chain length of Asp and Glu on coordination structure of Cu^<2+> in a de novo designed protein2009
Author(s)
Daigo Shiga, Daisuke Nakane, Tomohiko Inomata, Hideki Masuda, Masayuki Oda, Masanori Noda, Susumu Uchiyama, Kiichi Fukui, Yu Takano, Haruki Nakamura, Toshihisa Mizuno, Toshiki Tanaka
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Journal Title
Biopolymers 91(11)
Pages: 907-916
Peer Reviewed
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[Journal Article] Synthesis, Characterization, and Reactivities of (m-h2:h2-Disulfido)dicopper(II) Complexes with N-Alkylated cis, cis1, 3, 5-Triaminocyclohexane Derivatives2008
Author(s)
Yuji Kajita, Jun Matsumoto, Isao Takahashi, Shun Hirota, Yasuhiro Funahashi, Tomohiro Ozawa, Hideki Masuda
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Journal Title
Eur. J. Inorg. Chem.
Pages: 3977-3986
Peer Reviewed
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[Journal Article] Formation of a Bridged Butterfly-Typeμ-η^2:η^2-Peroxo Dicopper Core Structure with a Carboxylate Group2008
Author(s)
Yasuhiro Funahashi, Tomohide Nishikawa, Yuko Wasada-Tsutsui, Yuji Kajita, Syuhei Yamaguchi, Hidekazu Arii, Tomohiro Ozawa, Koichiro Jitsukawa, Takehiko Tosha, Shun Hirota, Teizo Kitagawa, Hideki Masuda
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Journal Title
J. Am. Chem. Soc. 130(49)
Pages: 16444-16445
Peer Reviewed
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[Journal Article] Probing Electron Transfer Reactions between Two Azurins from Alcaligenes xylosoxidans GIFU 1051 with Optically Active Ru Complexes as Molecular Recognition Probes: Importance of the 43rd Residue2007
Author(s)
Takashi Kato, Hideyuki Kumita, Isao Takahashi, Aki Murakami, Kunue Yoshimoto, Yasunori Ikeue, Kunishige Kataoka, Shinnichiro Suzuki, Takeshi Sakurai, Tomohiro Ozawa, Yasuhiro Funahashi, Koichiro Jitsukawa, Hideki Masuda
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Journal Title
Inorg. Chim. Acta 360
Pages: 1555-1567
Peer Reviewed
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[Journal Article] Syntheses, Characterization, and Dioxygen Reactivities of Cu(I) Complexes with cis, cis-1, 3, 5-Triamino-cyclohezane Derivatives: A Cu(III)_2O_2 Intermediate Exhibiting Higher C-H activation2007
Author(s)
Yuji Kajita, Hidekikazu Arii, Takahiro Saito, Yamato Saito, Shigenori Nagatomo, Teizo Kitagawa, Yasuhiro Funahashi, Tomohiro Ozawa, Hideki Masuda
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Journal Title
Inorg. Chem. 46(8)
Pages: 3322-3335
Peer Reviewed
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