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2009 Fiscal Year Final Research Report

Realization of ferroelectric columnar liquid crystal phases

Research Project

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Project/Area Number 19350090
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials/Devices
Research InstitutionChiba University

Principal Investigator

KISHIKAWA Keiki  Chiba University, 大学院・工学研究科, 教授 (40241939)

Co-Investigator(Renkei-kenkyūsha) KOHMOTO Shigeo  千葉大学, 大学院・工学研究科, 究科 (90195686)
Project Period (FY) 2007 – 2009
Keywords液晶 / 強誘電性 / 記録素子 / 解析・評価 / マイクロ・ナノデバイス
Research Abstract

Realization of ferroelectric columnar liquid crystal phases were attempted by modification of the molecular structures of liquid crystalline urea compounds. The polar structure of the column was clarified by the effect of alkyl chain length of the urea compounds. Lowering of the liquid crystal temperature range and improvement of the response time on applying a triangular wave voltage were observed in the liquid crystal phases. Further, it was found that the oxygen atoms in the arms of the urea molecules are necessary for the polar switching.

  • Research Products

    (38 results)

All 2010 2009 2008 2007

All Journal Article (25 results) (of which Peer Reviewed: 24 results) Presentation (13 results)

  • [Journal Article] Hydrogen-bonded ionic liquid crystals : pyridinylmethylimidazolium as a versatile building block2010

    • Author(s)
      Shigeo Kohmoto, Yukiko Hara, Keiki Kishikawa
    • Journal Title

      Tetrahedron Letters 51(11)

      Pages: 1508-1511

    • Peer Reviewed
  • [Journal Article] Liquid crystalline molecules with hydrogen-bonding networks in the direction of molecular short axes2010

    • Author(s)
      Shigeo Kohmoto, Yasunobu Someya, Keiki Kishikawa
    • Journal Title

      Liquid Crystals 37(2)

      Pages: 209-216

    • Peer Reviewed
  • [Journal Article] Relation between the Spontaneous Polarization and Alkyl Chain Length in Ferroelectric Switching of Columnar Liquid-Crystalline Ureas2010

    • Author(s)
      Keiki Kishikawa, Shoichiro Nakahara, Masanori Natsukawa, Keiichi Suzuki, ; Shigeo Kohmoto
    • Journal Title

      Molecular Crystals and Liquid Crystals 516

      Pages: 107-113

    • Peer Reviewed
  • [Journal Article] Stabilization of γ-lactam and lactone ring-fused norcaradienes by protonation : DFT calculations of norcaradiene and the corresponding cycloheptatriene structures2010

    • Author(s)
      Shigeo Kohmoto, Tatsuya Motomura, Masahiro Takahashi, Kishikawa Keiki
    • Journal Title

      Journal of Molecular Structure 964(1-3)

      Pages: 47-51

    • Peer Reviewed
  • [Journal Article] Ferroelectrically switchable columnar liquid crystalline ureas2009

    • Author(s)
      Keiki Kishikawa, Shoichiro Nakahara, Yohei Nishikawa, Masanori Natsukawa, Shigeo Kohmoto
    • Journal Title

      Molecular Crystals and Liquid Crystals 498

      Pages: 11-18

    • Peer Reviewed
  • [Journal Article] Generation of Square-Shaped Cyclic Dimers vs Zigzag Hydrogen-Bonding Networks and Pseudo-conformational Polymorphism of Tethered Benzoic Acids2009

    • Author(s)
      Shigeo Kohmoto, Yu Kuroda, Keiki Kishikawa, Hyuma Masu, Isao Azumaya
    • Journal Title

      Crystal Growth & Design 9(12)

      Pages: 5017-5020

    • Peer Reviewed
  • [Journal Article] Hydrogen-Bonded Dimers of 3,5-Bis-(hydroxylmethyl) benzoic Acids : Novel Supramolecular Tectons2009

    • Author(s)
      Shigeo Kohmoto, Yu Kuroda, Yasunobu Someya ; Keiki Kishikawa, Hyuma Masu, Kentaro Yamaguchi, Isao Azumaya
    • Journal Title

      Crystal Growth & Design 9(8)

      Pages: 3457-3462

    • Peer Reviewed
  • [Journal Article] Control of the molecular structure of liquid crystals by using intermolecular interactions in the direction of the minor axis2009

    • Author(s)
      Keiki Kishikawa
    • Journal Title

      TCIMeru 143

      Pages: 2-1

  • [Journal Article] Transformation of β-nitro alcohols to the corresponding nitro imines with lithium hexamethyldisilazide (LHMDS) via sequential retro nitro-aldol-nitro-Mannich reaction2009

    • Author(s)
      Seiji Tanaka, Kazuhiro Kochi, Hiroyuki Ito, Jun Mukawa, Keiki Kishikawa, Makoto Yamamoto, Shigeo Kohmoto
    • Journal Title

      Synthetic Communications 39(5)

      Pages: 868-874

    • Peer Reviewed
  • [Journal Article] Construction of super-structures in liquid crystalline molecular aggregates using lateral intermolecular interactions2008

    • Author(s)
      Keiki Kishikawa, Yuki Gosei
    • Journal Title

      Kagaku Kyokaishi 66(4)

      Pages: 368-376

    • Peer Reviewed
  • [Journal Article] Conformation of S-shaped aromatic imide foldamers and their induced circular dichroism2008

    • Author(s)
      Shigeo Kohmoto, Hiroshi Takeichi, Keiki Kishikawa, Hyuma Masu, Isao Azumaya
    • Journal Title

      Tetrahedron Letters 49(7)

      Pages: 1223-1227

    • Peer Reviewed
  • [Journal Article] Double nitro-Mannich reaction utilizing in situ generated Ntrimethylsilylaldimines : novel four-component one-pot synthesis of nitro imines2008

    • Author(s)
      Seiji Tanaka, Yukinari Oguma, Yusuke Tanaka, Hidenori Echizen, Hyuma Masu, Kentaro Yamaguchi, Keiki Kishikawa, Shigeo Kohmoto, Makoto Yamamoto
    • Journal Title

      Tetrahedron 64(7)

      Pages: 1388-1396

    • Peer Reviewed
  • [Journal Article] Fixation of Multilayered Structures of Liquid-Crystalline 2:1 Complexes of Benzoic Acid Derivatives and Dipyridyl Compounds and the Effect of Nanopillars on Removal of the Dipyridyl Molecules from the Polymers2008

    • Author(s)
      Keiki Kishikawa, Akina Hirai, Shigeo Kohmoto
    • Journal Title

      Chemistry of Materials 20(5)

      Pages: 1931-1935

    • Peer Reviewed
  • [Journal Article] Supramolecular polymerization and poly-morphs of oligo (p-phenylene vinylene)-functionalized bis-and monoureas2008

    • Author(s)
      Shiki Yagai, Shun Kubota, Tomoyuki Iwashima, Keiki Kishikawa, Takashi Nakanishi, Takashi Karatsu, Akihide Kitamura
    • Journal Title

      Chemistry-A European Journal 14(17)

      Pages: 5246-5257

    • Peer Reviewed
  • [Journal Article] Tailoring liquid-crystalline supramolecular structures by ionic interactions2008

    • Author(s)
      Takao Noguchi, Keiki Kishikawa, Shigeo Kohmoto
    • Journal Title

      Chemistry Letters 37(1)

      Pages: 12-13

    • Peer Reviewed
  • [Journal Article] Tailoring of ionic supramolecular assemblies based on ammonium carboxylates toward liquid-crystalline micellar cubic mesophases2008

    • Author(s)
      Takao Noguchi, ; Keiki Kishikawa, Shigeo Kohmoto
    • Journal Title

      Liquid Crystals 35(8)

      Pages: 1043-1050

    • Peer Reviewed
  • [Journal Article] Volume effect of alkyl chains on organization of ionic self-assemblies toward hexagonal columnar mesophases2008

    • Author(s)
      Takao Noguchi, Keiki Kishikawa Shigeo Kohmoto
    • Journal Title

      Bulletin of the Chemical Society of Japan 81(6)

      Pages: 778-783

    • Peer Reviewed
  • [Journal Article] Columnar superstructures of nondisc-shaped molecules generated by arene-perfluoroarene face-to-face interactions2007

    • Author(s)
      Keiki Kishikawa, Katsuyuki Oda, Sumihiro Aikyo, Shigeo Kohmoto, Angewandte Chemie
    • Journal Title

      International Edition 46(5)

      Pages: 764-768, S764/1-S764/3

    • Peer Reviewed
  • [Journal Article] Diversification of Self-Organized Architectures in Supramolecular Dye Assemblies2007

    • Author(s)
      Shiki Yagai, Tetsuro Kinoshita, Masatsugu Higashi, Keiki Kishikawa, Takashi Nakanishi, Takashi Karatsu, Akihide Kitamura
    • Journal Title

      Journal of the American Chemical Society 129(43)

      Pages: 13277-13287

    • Peer Reviewed
  • [Journal Article] Electro-optic Kerr effect in the isotropic phase above the columnar phase of a urea derivative2007

    • Author(s)
      Yoshinori Okada, Fumito Araoka, Yoichi Takanishi, Ken Ishikawa, Shoichiro Nakahara, Keiki Kishikawa, Hyunhee Choi, Jeong Weon Wu, Hideo Takezoe
    • Journal Title

      Physical Review E : Statistical, Nonlinear, and Soft Matter Physics 75(5-1)

      Pages: 050701/1-050701/4

    • Peer Reviewed
  • [Journal Article] Micro-segregated layer structures generated by liquid crystalline dimers possessing an oligo (ethylene glycol) spacer and two terminal alkyl chains2007

    • Author(s)
      Masaki Katoh, Shigeo Kohmoto, Keiki Kishikawa
    • Journal Title

      Materials Letters 61(14-15)

      Pages: 2915-2918

    • Peer Reviewed
  • [Journal Article] Polymorphism-dependent fluorescence of 9,10-bis (pentafluorobenzoyloxy)-anthracene2007

    • Author(s)
      Shigeo Kohmoto, Ryota Tsuyuki, Hyuma Masu, Isao Azumaya, Keiki Kishikawa
    • Journal Title

      Tetrahedron Letters 49(1)

      Pages: 39-43

    • Peer Reviewed
  • [Journal Article] Room-Temperature Discotic Nematic Liquid Crystals over a Wide Temperature Range : Alkali-Metal-Ion-Induced Phase Transition from Discotic Nematic to Columnar Phases2007

    • Author(s)
      Shigeo Kohmoto, Emiko Mori, Keiki Kishikawa
    • Journal Title

      Journal of the American Chemical Society 129(44)

      Pages: 13364-13365

    • Peer Reviewed
  • [Journal Article] Three relaxation processes from an electric-field-induced polar structure in a columnar liquid crystalline urea derivative2007

    • Author(s)
      Yoshinori Okada, Shohei Matsumoto, Fumito Araoka, Masanao Goto, Yoichi Takanishi, Ken Ishikawa, Shoichiro Nakahara, Keiki Kishikawa, Hideo Takezoe, Physical Review E
    • Journal Title

      Statistical, Nonlinear, and Soft Matter Physics 76(4-1)

      Pages: 041701/1-041701/6

    • Peer Reviewed
  • [Journal Article] Why achiral rod-like compound with ester group amplifies chiral power in chiral mesophase2007

    • Author(s)
      Susumu Kawauchi, Suk-Won Choi, Kaoru Fukuda, Keiki Kishikawa Junji Watanabe, Hideo Takezoe
    • Journal Title

      Chemistry Letters 36(6)

      Pages: 750-751

    • Peer Reviewed
  • [Presentation] Self-organization of liquid crystalline molecules by introduction of lateral intermolecular interactions2009

    • Author(s)
      Keiki Kishiakwa
    • Organizer
      2009 Annual Meeting of ROC Taiwan Liquid Crystal Society (Hsinchu), Abstract KA-01
    • Year and Date
      2009-12-18
  • [Presentation] Ferroelectric Switchable Columnar Liquid Crystalline Ureas2009

    • Author(s)
      Keiki Kishikawa
    • Organizer
      2009 Liquid Crystal Application Workshop : National Chiao Tung University
    • Place of Presentation
      Taiwan
    • Year and Date
      2009-12-17
  • [Presentation] 様々なリンカーの導入による強誘電性柱状液晶の実現2009

    • Author(s)
      岸川圭希, 森保慎吾, 幸本重男
    • Organizer
      日本液晶学会討論会
    • Place of Presentation
      東京農工大学小金井キャンパス
    • Year and Date
      2009-09-13
  • [Presentation] 電圧印加による柱状分子集合体の超構造制御2009

    • Author(s)
      岸川圭希, 五郡維甫, 幸本重男
    • Organizer
      日本液晶学会討論会
    • Place of Presentation
      東京農工大学小金井キャンパス
    • Year and Date
      2009-09-13
  • [Presentation] Superstructures of Liquid Crystalline Ureas and Their Ferroelectric Behaviors2008

    • Author(s)
      Keiki Kishikawa, Masanori Natsukawa, Keiichi Suzuki, Shigeo Kohmoto
    • Organizer
      The International Union of Materials Research Societies International Conference in Asia 2008, Nagoya, Japan Symposium of Liquid Crystals and Ordered Soft Materials, Program book
    • Place of Presentation
      Nagoya, Japan
    • Year and Date
      2008-12-12
  • [Presentation] Superstructures of liquid crystalline ureas and their ferroelectric switching behaviors2008

    • Author(s)
      Keiki Kishikawa, Masanori Natsukawa, Shoichiro Nakahara, Yoshinori Okada, Yoichi Takanishi, Ken Ishikawa, Hideo Takezoe, Shigeo Kohmoto
    • Organizer
      3rd International Conference on Cutting-Edge Organic Chemistry in Asia
    • Place of Presentation
      Hangzhou, China
    • Year and Date
      2008-10-20
  • [Presentation] 強誘電的挙動を示す柱状液晶相の合成と特性2008

    • Author(s)
      岸川圭希, 鈴木敬一, 幸本重男
    • Organizer
      日本液晶学会討論会
    • Place of Presentation
      キャンパスプラザ京都
    • Year and Date
      2008-09-17
  • [Presentation] Superstructures and ferroelectric behaviors of liquid crystalline ureas possessing two long cores2008

    • Author(s)
      Keiki Kishikawa, Masanori Natsukawa, Keiichi Suzuki, Shigeo Kohmoto
    • Organizer
      The 4th Japanese-Italian Workshop on Liquid Crystals (JILC'08)
    • Place of Presentation
      Nara, Japan
    • Year and Date
      2008-07-09
  • [Presentation] Ferroelectrically Switchable Columnar Liquid-Crystalline Ureas2008

    • Author(s)
      Keiki Kishikawa, Masanori Natsukawa, Shigeo Kohmoto
    • Organizer
      International Liquid Crystal Conference 2008
    • Place of Presentation
      Jedu, Korea
    • Year and Date
      2008-06-16
  • [Presentation] 液晶性ウレアの分子構造とスイッチング挙動2007

    • Author(s)
      岸川圭希, 夏川昌典, 田中誠次, 幸本重男
    • Organizer
      2007年日本液晶学会討論会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2007-09-12
  • [Presentation] Ferroelectrically switchable columnar liquid-crystalline ureas2007

    • Author(s)
      Keiki Kishikawa, Shoichiro Nakahara, Shigeo Kohmoto, Yoshinori Okada, Yoichi Takanishi, Ken Ishikawa, Hideo Takezoe
    • Organizer
      The 11th international conference on ferroelectric liquid crystals
    • Place of Presentation
      Sapporo, Japan
    • Year and Date
      2007-09-07
  • [Presentation] Ferroelectrically switchable columnar liquid-crystalline ureas2007

    • Author(s)
      Keiki Kishikawa
    • Organizer
      2007 the 11th International Symposium On Advanced Display Materials and Devices (ADMD 2007)
    • Place of Presentation
      Daegu, Korea
    • Year and Date
      2007-06-22
  • [Presentation] 分子短軸方向の分子間水素結合を利用した直線的分子集合体の構築と性質2007

    • Author(s)
      岸川圭希
    • Organizer
      第11回日本化学会液晶化学研究会シンポジウム
    • Place of Presentation
      大分県別府市ビーコンプラザ
    • Year and Date
      2007-05-18

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Published: 2011-06-18   Modified: 2016-04-21  

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