2010 Fiscal Year Final Research Report
Structural control of peroxoheteropolytungstates :the role ofthe solvent and counter cations
| Project/Area Number |
19550065
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Inorganic chemistry
|
|---|
| Research Institution | Wakayama University |
|---|
Principal Investigator |
HASHIMOTO Masato Wakayama University, システム工学部, 教授 (50237947)
|
|---|
| Project Period (FY) |
2007 – 2010
|
| Keywords | ポリオキソメタレート / 金属過酸化物 / タングステン / 溶液内錯形成反応 / 結晶構造 / 構造制御 / 多核NMR / 自己集積化 |
|---|
| Research Abstract |
A peroxopolytungstate is an anionic aggregate of tungsten peroxides. Effe cts of solvent compositions and coexisting canons to build up peroxopolytungstateswere examined. Solvents did not affect so much in the range of the present work. On the other hand coexisting cations showed significant effects on the composition, structure and amount of the anion.
|
