2010 Fiscal Year Final Research Report
Syntheses of noble signal transduction molecules possessing two orthogonally oriented redox moieties and their application to logical gates
| Project/Area Number |
19550138
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Functional materials chemistry
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| Research Institution | Shizuoka University |
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Principal Investigator |
UEDA Kazumasa Shizuoka University, 工学部, 教授 (10275290)
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| Co-Investigator(Kenkyū-buntansha) |
KOKADO Satoshi 静岡大学, 工学部, 准教授 (50377719)
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| Project Period (FY) |
2007 – 2010
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| Keywords | 直交配向分子 / 情報伝達素子 / 論理回路 / レドックス中心 / ヨウ素置換 / テトラチアフルバレノチオキノン-1,3-ジチオールメチド / Halogen bonding |
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| Research Abstract |
Constructing of noble signal transduction molecules without the use of electrical conduction is one of the current issues for power saving function in logical gates. Our approach to overcome this issue is employing charge propagation for signal transduction system. One of the candidates for such system is a molecule possessing two orthogonally oriented redox moieties. We have succeeded in the syntheses of the iodine group substituted tetrathiafulvalenothioquinone-1,3-dithiolemthide derivatives and arranging them orthogonally by halogen bonding in the solid state.
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[Journal Article] Syntheses, crystal structures and DFT calculations of 2-[4, 5-bis(ethylsulfanyl)-1, 3-dithiol-2-ylidene]-5-(4, 5-diiodo-1, 3-dithiol-2-ylidene)-1, 3-dithiolan-4-thione and-one2010
Author(s)
K.Ueda, K.Suzuki, K.Suzuki, K.Yoza, T.Ishida
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Journal Title
Physica B : Physics of Condensed Matter. 405(11)
Pages: S69-S74
Peer Reviewed
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[Presentation] Syntheses, and crystal structures of 5-[4-(4, 5-diiodo-1, 3-dithiol-2-ylidene)-5-thioxo-1, 3-dithiolan-2-ylidene][1, 3]dithiolo[4, 5-d][1, 3]dithiol-2-one and 5-[4-(4, 5-diiodo-1, 3-dithiol-2-ylidene)-5-oxo-1, 3-dithiolan-2-ylidene][1, 3]dithiolo[4, 5-d][1,3]dithiol-2-one2010
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