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2010 Fiscal Year Final Research Report

Development of Fluorous and Magnetic Catalytic Reactions for Green Chemistry

Research Project

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Project/Area Number 19750128
Research Category

Grant-in-Aid for Young Scientists (B)

Allocation TypeSingle-year Grants
Research Field Environmental chemistry
Research InstitutionThe Noguchi Institute

Principal Investigator

YOSHIDA Akihiro  The Noguchi Institute, 研究部, 研究員 (10292301)

Project Period (FY) 2007 – 2010
Keywordsフルオラス化学 / ルイス酸触媒 / 多相系反応 / スルホンイミド / 磁性触媒 / グリーンケミストリー / PFOS問題 / イオン液体
Research Abstract

Several fluorous catalysts and media were developed for green chemistry. That is to say, development of fluorous Lewis acid of late transition metal with fluorous sulfonimide ligands, ethereal oxygen-containing fluorous Lewis acid for the counter-measure against the problem of PFOS, fluorous ionic liquid and fluorous mesoporous silica gel was accomplished. Development of the reactions using iron oxide nanoparticle was performed as a magnetic catalytic reactions.

  • Research Products

    (9 results)

All 2011 2010 2009 2008 2007 Other

All Journal Article (2 results) (of which Peer Reviewed: 1 results) Presentation (3 results) Book (1 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] フルオラスLewis酸触媒反応の開発2011

    • Author(s)
      吉田彰宏
    • Journal Title

      Fluorine 3巻

      Pages: 10-16

  • [Journal Article] Recyclable Hafnium(IV) Bis(perfluorooctanesulfonyl) amide Complex for Catalytic Friedel-Crafts acylation and Prins Reaction in Fluorous Biphase System2007

    • Author(s)
      X.Hao, A.Yoshida, N.Hoshi
    • Journal Title

      J.Fluorine Chem. 128巻

      Pages: 1396-1401

    • Peer Reviewed
  • [Presentation] フルオラスLewis酸触媒反応の開発2010

    • Author(s)
      吉田彰宏
    • Organizer
      第17回有機フッ素化学セミナー(岡山)その2
    • Place of Presentation
      岡山
    • Year and Date
      2010-09-25
  • [Presentation] Environmental Aspect in Fluorous Biphasic System (Our Approach)2009

    • Author(s)
      N.Hoshi, A.Yoshida
    • Organizer
      The 19th International Symposium on Fluorine Chemistry including ISoFT'09 (19thISFC-ISoFT'09)
    • Place of Presentation
      Jackson Hole.
    • Year and Date
      20090823-20090828
  • [Presentation] Low-leaching Fluorous Biphasic Solvent System for Fluorous Lewis Acid Catalysis2007

    • Author(s)
      A.Yoshida, N.Hoshi
    • Organizer
      The 2nd International Symposium on Fluorous Technologies (ISoFT'07)
    • Place of Presentation
      横浜
    • Year and Date
      20070729-20070801
  • [Book] 「フルオラスLewis酸触媒」,「固定化触媒のルネッサンス」内(小林修, 小山田秀和監修)2007

    • Author(s)
      吉田彰宏, 錦戸條二
    • Total Pages
      192-206
    • Publisher
      シーエムシー出版
  • [Remarks] ホームページ等

    • URL

      http://www.noguchi.or.jp/

  • [Patent(Industrial Property Rights)] 低リーチング性のフルオラス多相系反応方法2009

    • Inventor(s)
      星信人, 吉田彰宏
    • Industrial Property Rights Holder
      公益財団法人野口研究所, 旭化成株式会社
    • Industrial Property Number
      特許,特願2009-190116
    • Filing Date
      2009-08-19
  • [Patent(Industrial Property Rights)] ルイス酸触媒含有組成物2008

    • Inventor(s)
      錦戸條二, 吉田彰宏, 池田正紀
    • Industrial Property Rights Holder
      公益財団法人野口研究所, 旭化成株式会社
    • Industrial Property Number
      特許,4119371
    • Acquisition Date
      2008-05-02

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Published: 2012-02-13   Modified: 2016-04-21  

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