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2020 Fiscal Year Annual Research Report

Speciation and isotope analyses of volatile elements in carbonates for the evolution of surface environment on Mars

Research Project

Project/Area Number 19H01960
Research InstitutionJapan Aerospace EXploration Agency

Principal Investigator

臼井 寛裕  国立研究開発法人宇宙航空研究開発機構, 宇宙科学研究所, 教授 (60636471)

Co-Investigator(Kenkyū-buntansha) 高橋 嘉夫  東京大学, 大学院理学系研究科(理学部), 教授 (10304396)
中田 亮一  国立研究開発法人海洋研究開発機構, 超先鋭研究開発部門(高知コア研究所), 副主任研究員 (50726958)
黒川 宏之  東京工業大学, 地球生命研究所, 特任助教 (80713643)
上野 雄一郎  東京工業大学, 理学院, 教授 (90422542)
Project Period (FY) 2019-04-01 – 2022-03-31
Keywords火星隕石 / XAFS / 硫黄化学種
Outline of Annual Research Achievements

2020年度は、研究計画調書に記載の『研究計画1:局所XAFS(μ-XAFS)分析による火星表層成分のFeとSの化学種同定』の論文化を中心に進めた。具体的には、2019年度に取得した火星隕石および火星アナログ物質に含まれる炭酸塩の局所XAFS分析データの解析を行い、火星の炭酸塩に微量元素として含まれる窒素や硫黄の化学種を同定した。結果、1)炭酸塩中の窒素は還元的な有機窒素として、2)硫黄は、一部が有機窒素、そして大部分が硫酸イオンとして炭酸塩の炭酸イオンを構造的に置換した形で存在していることが明らかとなった。本研究成果は、査読付き原著論文として国際専門誌に掲載された。

Current Status of Research Progress
Current Status of Research Progress

2: Research has progressed on the whole more than it was originally planned.

Reason

目標としていた2年目での論文化を達成したため。

Strategy for Future Research Activity

2021年度は、コロナウイルスの影響で、SPring-8における実験や、研究計画2で予定していた米国での局所同位体分析が十分に実施できないことが予想される。2020年度後半に取得できたSpring-8でのXAFSデータ解析や計画3の水散逸モデルへの展開を中心に、論文の執筆に集中する。

  • Research Products

    (54 results)

All 2021 2020

All Journal Article (25 results) (of which Int'l Joint Research: 17 results,  Peer Reviewed: 25 results,  Open Access: 4 results) Presentation (29 results) (of which Int'l Joint Research: 17 results,  Invited: 4 results)

  • [Journal Article] EXAFS Determination of Clay Minerals in Martian Meteorite Allan Hills 84001 and Its Implication for the Noachian Aqueous Environment2021

    • Author(s)
      Nakada Ryoichi、Tanabe Gaku、Kajitani Iori、Usui Tomohiro、Shidare Masashi、Yokoyama Tetsuya
    • Journal Title

      Minerals

      Volume: 11 Pages: -

    • DOI

      10.3390/min11020176

    • Peer Reviewed / Open Access
  • [Journal Article] Standardization for 13C‐13C clumped isotope analysis by fluorination method2021

    • Author(s)
      Taguchi Koudai、Gilbert Alexis、Ueno Yuichiro
    • Journal Title

      Rapid Communications in Mass Spectrometry

      Volume: - Pages: -

    • DOI

      10.1002/rcm.9109

    • Peer Reviewed
  • [Journal Article] Tracing sulfur sources in the crust via SIMS measurement of sulfur isotopes in apatite2021

    • Author(s)
      Hammerli Johannes、Greber Nicolas D.、Martin Laure、Bouvier Anne-Sophie、Kemp Anthony I.S.、Fiorentini Marco L.、Spangenberg Jorge E.、Ueno Yuichiro、Schaltegger Urs
    • Journal Title

      Chemical Geology

      Volume: - Pages: 120242~120242

    • DOI

      10.1016/j.chemgeo.2021.120242

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Scandium immobilization by goethite: Surface adsorption versus structural incorporation2021

    • Author(s)
      Qin Hai-Bo、Yang Shitong、Tanaka Masato、Sanematsu Kenzo、Arcilla Carlo、Takahashi Yoshio
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 294 Pages: 255~272

    • DOI

      10.1016/j.gca.2020.11.020

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] The role of hydrothermal sulfate reduction in the sulfur cycles within Europa: Laboratory experiments on sulfate reduction at 100?MPa2021

    • Author(s)
      Tan Shuya、Sekine Yasuhito、Shibuya Takazo、Miyamoto Chihiro、Takahashi Yoshio
    • Journal Title

      Icarus

      Volume: 357 Pages: 114222~114222

    • DOI

      10.1016/j.icarus.2020.114222

    • Peer Reviewed
  • [Journal Article] Broadband high-energy resolution hard x-ray spectroscopy using transition edge sensors at SPring-82021

    • Author(s)
      Yamada S, Ichinohe Y, Tatsuno H, Hayakawa R, Suda H, Ohashi T, Ishisaki Y, Uruga T, Sekizawa O, Nitta K, Takahashi Y.
    • Journal Title

      Review of Scientific Instruments

      Volume: 92 Pages: 013103~013103

    • DOI

      10.1063/5.0020642

    • Peer Reviewed
  • [Journal Article] Multiple sulfur isotope chemostratigraphy across the Permian?Triassic boundary at Chaotian, China: Implications for a shoaling model of toxic deep‐waters2021

    • Author(s)
      Saitoh Masafumi、Ueno Yuichiro、Isozaki Yukio、Yoshida Naohiro
    • Journal Title

      Island Arc

      Volume: 30 Pages: -

    • DOI

      10.1111/iar.12398

    • Peer Reviewed
  • [Journal Article] A fluorination method for measuring the 13C‐13C isotopologue of C2 molecules2020

    • Author(s)
      Taguchi Koudai、Yamamoto Tomonari、Nakagawa Mayuko、Gilbert Alexis、Ueno Yuichiro
    • Journal Title

      Rapid Communications in Mass Spectrometry

      Volume: 34 Pages: -

    • DOI

      10.1002/rcm.8761

    • Peer Reviewed
  • [Journal Article] Mission to Planet Earth: The First Two Billion Years2020

    • Author(s)
      Steken E. E.、Som S. M.、Claire M.、Rugheimer S.、Scherf M.、Sprob L.、Tosi N.、Ueno Y.、Lammer H.
    • Journal Title

      Space Science Reviews

      Volume: 216 Pages: -

    • DOI

      10.1007/s11214-020-00652-3

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] The Importance of Phobos Sample Return for Understanding the Mars-Moon System2020

    • Author(s)
      Usui Tomohiro、Bajo Ken-ichi、Fujiya Wataru、Furukawa Yoshihiro、Koike Mizuho、Miura Yayoi N.、Sugahara Haruna、Tachibana Shogo、Takano Yoshinori、Kuramoto Kiyoshi
    • Journal Title

      Space Science Reviews

      Volume: 216 Pages: -

    • DOI

      10.1007/s11214-020-00668-9

    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Loss and Fractionation of Noble Gas Isotopes and Moderately Volatile Elements from Planetary Embryos and Early Venus, Earth and Mars2020

    • Author(s)
      Lammer Helmut、Scherf Manuel、Kurokawa Hiroyuki、Ueno Yuichiro、Burger Christoph、Maindl Thomas、Johnstone Colin P.、Leizinger Martin、Benedikt Markus、Fossati Luca、Kislyakova Kristina G.、Marty Bernard、Avice Guillaume、Fegley Bruce、Odert Petra
    • Journal Title

      Space Science Reviews

      Volume: 216 Pages: -

    • DOI

      10.1007/s11214-020-00701-x

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Chemical speciation of scandium and yttrium in laterites: New insights into the control of their partitioning behaviors2020

    • Author(s)
      Qin Hai-Bo、Yang Shitong、Tanaka Masato、Sanematsu Kenzo、Arcilla Carlo、Takahashi Yoshio
    • Journal Title

      Chemical Geology

      Volume: 552 Pages: 119771~119771

    • DOI

      10.1016/j.chemgeo.2020.119771

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Geochemically heterogeneous Martian mantle inferred from Pb isotope systematics of depleted shergottites2020

    • Author(s)
      Moriwaki Ryota、Usui Tomohiro、Tobita Minato、Yokoyama Tetsuya
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 274 Pages: 157~171

    • DOI

      10.1016/j.gca.2020.01.014

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Major/trace elements and Sr?Nd?Pb isotope systematics of lavas from lakes Barombi Mbo and Barombi Koto in the Kumba graben, Cameroon volcanic line: Constraints on petrogenesis2020

    • Author(s)
      Asaah A.N.E.、Yokoyama T.、Aka F.T.、Iwamori H.、Kuritani T.、Usui T.、Gountie Dedzo M.、Tamen J.、Hasegawa T.、Fozing E.M.、Wirmvem M.J.、Nche A.L.
    • Journal Title

      Journal of African Earth Sciences

      Volume: 161 Pages: 103675~103675

    • DOI

      10.1016/j.jafrearsci.2019.103675

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Interaction between Cerium and H2O in Hydrous Rhyolitic Melts2020

    • Author(s)
      Kondo Nozomi M.、Kono Yoshio、Ohara Koji、Nakada Ryoichi、Ina Toshiaki、Skrzypek Etienne、Yamada Akihiro、Saito Satoshi
    • Journal Title

      ACS Earth and Space Chemistry

      Volume: 4 Pages: 2281~2288

    • DOI

      10.1021/acsearthspacechem.0c00206

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Climate Simulations of Early Mars With Estimated Precipitation, Runoff, and Erosion Rates2020

    • Author(s)
      Ramirez Ramses M.、Craddock Robert A.、Usui Tomohiro
    • Journal Title

      Journal of Geophysical Research: Planets

      Volume: 125 Pages: -

    • DOI

      10.1029/2019JE006160

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Radar Sounding of Subsurface Structure in Eastern Coprates and Capri Chasmata, Mars2020

    • Author(s)
      Noguchi Rina、Ishiyama Ken、Kumamoto Atsushi、Uemura Chihiro、Kasaba Yasumasa、Usui Tomohiro、Oura Aina、Shoji Daigo
    • Journal Title

      Geophysical Research Letters

      Volume: 47 Pages: -

    • DOI

      10.1029/2020GL088556

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] A Probabilistic Approach to Determination of Ceres' Average Surface Composition From Dawn Visible‐Infrared Mapping Spectrometer and Gamma Ray and Neutron Detector Data2020

    • Author(s)
      Kurokawa H.、Ehlmann B. L.、De Sanctis M. C.、Lap?tre M. G. A.、Usui T.、Stein N. T.、Prettyman T. H.、Raponi A.、Ciarniello M.
    • Journal Title

      Journal of Geophysical Research: Planets

      Volume: 125 Pages: -

    • DOI

      10.1029/2020JE006606

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] In-situ preservation of nitrogen-bearing organics in Noachian Martian carbonates2020

    • Author(s)
      Koike Mizuho、Nakada Ryoichi、Kajitani Iori、Usui Tomohiro、Tamenori Yusuke、Sugahara Haruna、Kobayashi Atsuko
    • Journal Title

      Nature Communications

      Volume: 11 Pages: -

    • DOI

      10.1038/s41467-020-15931-4

    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Characterization of two types of cesium-bearing microparticles emitted from the Fukushima accident via multiple synchrotron radiation analyses2020

    • Author(s)
      Miura Hikaru、Kurihara Yuichi、Yamamoto Masayoshi、Sakaguchi Aya、Yamaguchi Noriko、Sekizawa Oki、Nitta Kiyofumi、Higaki Shogo、Tsumune Daisuke、Itai Takaaki、Takahashi Yoshio
    • Journal Title

      Scientific Reports

      Volume: 10 Pages: -

    • DOI

      10.1038/s41598-020-68318-2

    • Peer Reviewed / Open Access
  • [Journal Article] The Great Oxidation Event preceded a Paleoproterozoic “snowball Earth”2020

    • Author(s)
      Warke Matthew R.、Di Rocco Tommaso、Zerkle Aubrey L.、Lepland Aivo、Prave Anthony R.、Martin Adam P.、Ueno Yuichiro、Condon Daniel J.、Claire Mark W.
    • Journal Title

      Proceedings of the National Academy of Sciences

      Volume: 117 Pages: 13314~13320

    • DOI

      10.1073/pnas.2003090117

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Local Structure of Rare Earth Elements (REE) in Marine Ferromanganese Oxides by Extended X-ray Absorption Fine Structure and Its Comparison with REE in Ion-adsorption Type Deposits2020

    • Author(s)
      Nagasawa Makoto、Qin Hai-Bo、Yamaguchi Akiko、Takahashi Yoshio
    • Journal Title

      Chemistry Letters

      Volume: 49 Pages: 909~911

    • DOI

      10.1246/cl.200257

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Hydrogenation reactions of carbon on Earth: Linking methane, margarine, and life2020

    • Author(s)
      McGlynn Shawn E.、Glass Jennifer B.、Johnson-Finn Kristin、Klein Frieder、Sanden Sebastian A.、Schrenk Matthew O.、Ueno Yuichiro、Vitale-Brovarone Alberto
    • Journal Title

      American Mineralogist

      Volume: 105 Pages: 599~608

    • DOI

      10.2138/am-2020-6928CCBYNCND

    • Peer Reviewed / Int'l Joint Research
  • [Journal Article] Vanadium micro-XANES determination of oxygen fugacity in olivine-hosted glass inclusion and groundmass glasses of martian primitive shergottite Yamato 9804592020

    • Author(s)
      Nakada Ryoichi、Usui Tomohiro、Ushioda Masashi、Takahashi Yoshio
    • Journal Title

      American Mineralogist

      Volume: 105 Pages: 1695~1703

    • DOI

      10.2138/am-2020-7321

    • Peer Reviewed
  • [Journal Article] Multiple Sulfur Isotope Records of the 3.22 Ga Moodies Group, Barberton Greenstone Belt2020

    • Author(s)
      Saitoh Masafumi、Nabhan Sami、Thomazo Christophe、Olivier Nicolas、Moyen Jean-Fran?ois、Ueno Yuichiro、Marin-Carbonne Johanna
    • Journal Title

      Geosciences

      Volume: 10 Pages: 145~145

    • DOI

      10.3390/geosciences10040145

    • Peer Reviewed / Int'l Joint Research
  • [Presentation] A Development of SO2F2 Method to Measure Sulfate Isotopologues2020

    • Author(s)
      Katsuta T, Ueno Y, Nakagawa M, Aoki R, Yoshida N
    • Organizer
      Goldschmidt Conference
    • Int'l Joint Research
  • [Presentation] A possibility of rubidium isotope as a prosy of water-rock interaction at surface of aqua planets2020

    • Author(s)
      Yoshio Takahashi, Rimi Konagaya, Hiroyuki Tsuboi, and Takaaki Itai
    • Organizer
      JpGU-AGU Joint Meeting 2020
    • Int'l Joint Research
  • [Presentation] Abundance of 13C-13C Bonding in Biotic and Abiotic Ethane Measured by a New C2F6 Method2020

    • Author(s)
      Taguchi K, Yamamoto T, Nakagawa M, Gilbert A, Ueno Y
    • Organizer
      Goldschmidt Conference
    • Int'l Joint Research
  • [Presentation] Analysis of 13C-13C isotopologue of ethane and ethanol by a fluorination method2020

    • Author(s)
      Koudai Taguchi, Tomonari Yamamoto, Mayuko Nakagawa, Yuichiro Ueno
    • Organizer
      JpGU-AGU Joint Meeting
    • Int'l Joint Research
  • [Presentation] Constraints on the Source of the Martian Magnetic Anomalies Inferred From Relaxation Time of Remanent Magnetization2020

    • Author(s)
      佐藤雅彦, 山本裕二, 西岡孝, 小玉一人, 望月伸竜, 潮田雅司, 中田亮一, 綱川秀夫
    • Organizer
      JpGU-AGU Joint Meeting 2020
  • [Presentation] Determination on iron species in plagioclase crystals toward the understanding on the magnetite exsolution2020

    • Author(s)
      R. Nakada, M. Sato, M. Ushioda, Y. Tamura, and S. Yamamoto
    • Organizer
      EGU General Assembly 2020
    • Int'l Joint Research
  • [Presentation] Equilibrium and Kinetic Fractionation on S-O Clumping of Sulfate2020

    • Author(s)
      Ueno Y, Nakagawa M, Katsuta T, Aoki R, Yoshida N
    • Organizer
      Goldschmidt Conference
    • Int'l Joint Research
  • [Presentation] In situ Hydrogen Isotope Analysis of Pyroxenes in Precambrian Gabbro2020

    • Author(s)
      Yagi H, Itoh S, Ishikawa A, Shibuya T, Ueno Y
    • Organizer
      Goldschmidt Conference
    • Int'l Joint Research
  • [Presentation] In-situ detection of early Noachian nitrogen-bearing organics from Martian carbonates2020

    • Author(s)
      小池みずほ, 中田亮一, 梶谷伊織, 臼井寛裕, 為則雄祐, 菅原春菜, 小林厚子
    • Organizer
      JpGU-AGU Joint Meeting 2020
  • [Presentation] In-Situ detection of nitrogen-bearing organics in Noachian Martian carbonates: Implication for nitrogen-cycle on early Mars2020

    • Author(s)
      M. Koike, R. Nakada, I. Kajitani, T. Usui, Y.Tamenori, H. Sugahara, and A. Kobayashi
    • Organizer
      Goldschmidt Conference 2020
    • Int'l Joint Research
  • [Presentation] Iron Limitation Enhance Organic Matter Sulfurization within the Limestones of the Ediacaran Dengying Formation2020

    • Author(s)
      MATSU’URA F, Nakada R, Ueno Y, Sawaki Y, Saitoh M, Kajitani I, Usui T
    • Organizer
      Goldschmidt Conference
    • Int'l Joint Research
  • [Presentation] Iron-Rich Hot Springs in Japan, a Microbiogeochemical Guided Tour2020

    • Author(s)
      Li-Hau F, Nakagawa M, Ward L, Ueno Y, McGlynn S
    • Organizer
      Goldschmidt Conference
    • Int'l Joint Research
  • [Presentation] Jinata Hot Spring as an Analogue to Early Proterozoic Oceans2020

    • Author(s)
      Fatima Li Hau, Mayuko Nakagawa, Lewis Ward, Yuichiro Ueno, Shawn E McGlynn
    • Organizer
      JpGU-AGU Joint Meeting
    • Int'l Joint Research
  • [Presentation] New constraints on atmospheric oxygenation2020

    • Author(s)
      Warke M. R., Di Rocco T., Zerkle A. L., Lepland A., Prave A. R., Martin A. P., Ueno Y., Condon D. J., Claire M. W.
    • Organizer
      GSA Annual Meeting
    • Int'l Joint Research / Invited
  • [Presentation] Photochemical flux of ammonia and glycine from N2O and its implication for origin of life2020

    • Author(s)
      Zang, X., Ueno Y.
    • Organizer
      AGU Fall meeting
    • Int'l Joint Research
  • [Presentation] Reactive iron supply control dominant sulfur species in the limestones of Ediacaran Doushantuo and Dengying Formations2020

    • Author(s)
      松浦史宏, 中田亮一, 上野雄一郎, 澤木佑介, 斎藤誠史, 梶谷伊織, 臼井寛裕
    • Organizer
      JpGU-AGU Joint Meeting 2020
    • Int'l Joint Research
  • [Presentation] Reduction of U(VI) to U(IV) by Fe(II)-bearing smectite2020

    • Author(s)
      Yoshio Takahashi, Jing Sun, Takafumi Hamamoto, and Takayuki Sasaki
    • Organizer
      JpGU-AGU Joint Meeting 2020
    • Int'l Joint Research
  • [Presentation] Revised kinetic parameters of the APS reductase enzyme: effect on microbial sulfur isotope fractionation.2020

    • Author(s)
      Shawn E McGlynn, Tommy Po-Hsiang Wang, Mayuko Nakagawa, Yuichiro Ueno
    • Organizer
      JpGU-AGU Joint Meeting
    • Int'l Joint Research
  • [Presentation] Sulfur species in carbonates of a 4.1-billion-year old Martian meteorite constraining conditions of water on ancient Mars2020

    • Author(s)
      梶谷伊織, 中田亮一, 小池みずほ, 田辺学, 臼井寛裕, 横山哲也, 福士圭介
    • Organizer
      JpGU-AGU Joint Meeting 2020
  • [Presentation] The effects of carbon concentration and silicate melt structure on the metal-silicate partitioning of carbon in a shallow magma ocean2020

    • Author(s)
      桑原秀治, 鈴村明政, 伊藤正一, 中田亮一, 入舩徹男
    • Organizer
      JpGU-AGU Joint Meeting 2020
  • [Presentation] The Great Oxidation Event Preceded a Paleoproterozoic ‘snowball Earth’2020

    • Author(s)
      Warke M, Di Rocco T, Zerkle A, Lepland A, Prave A, Martin A, Ueno Y, Claire M
    • Organizer
      Goldschmidt Conference
    • Int'l Joint Research
  • [Presentation] コマチアイトの強親鉄性元素地球化学?マントル進化史の解明に向けて?2020

    • Author(s)
      中野 隼, 石川 晃, 上野 雄一郎, 横山 哲也
    • Organizer
      JpGU-AGU Joint Meeting
  • [Presentation] フッ化型同位体分子計測:エタン、エタノールの13C-13C二重置換同位体分子計測法の開発2020

    • Author(s)
      田口宏大, Alexis Gilbert, 中川麻悠子, 上野雄一郎
    • Organizer
      日本地球化学会年会
  • [Presentation] 火星隕石ALH 84001の炭酸塩中の硫黄化学種解析に基づく初期火星表層環境の推定2020

    • Author(s)
      梶谷伊織, 中田亮一, 小池みずほ, 田辺学, 臼井寛裕, 松浦史宏, 福士圭 介, 黒川宏之, 横山哲也
    • Organizer
      日本惑星科学会2020年秋季講演会
  • [Presentation] 火星隕石Yamato 980459の局所XANES分析に基づく火成玄武岩マグマの酸素分圧進化2020

    • Author(s)
      中田亮一, 臼井寛裕, 潮田雅司, 高橋嘉夫
    • Organizer
      日本地球化学会第67回オンライン年会
  • [Presentation] 好熱性硫黄不均化菌の四種硫黄同位体指標2020

    • Author(s)
      中川麻悠子, 梅澤和寛, 小島久弥, 福井学, 吉田尚弘, 上野雄一郎
    • Organizer
      日本地球化学会年会
  • [Presentation] 丹沢道志斑れい岩から分離された斜長石中での離溶磁鉄鉱存在量と鉄価数の評価2020

    • Author(s)
      田村裕二郎, 佐藤雅彦, 中田亮一, 加藤千恵, 山本伸次
    • Organizer
      JpGU-AGU Joint Meeting 2020
    • Invited
  • [Presentation] 分子レベルでの粘土鉱物と金属イオンの相互作用解析とその地球化学的意義: 吸着反応と酸化還元反応2020

    • Author(s)
      高橋嘉夫
    • Organizer
      日本地球化学会
    • Invited
  • [Presentation] 分子地球化学:46億年の元素の輪廻と私たちの将来研究者2020

    • Author(s)
      高橋嘉夫
    • Organizer
      SEEDS Conference 2020
    • Invited

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Published: 2021-12-27  

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