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2021 Fiscal Year Annual Research Report

Speciation and isotope analyses of volatile elements in carbonates for the evolution of surface environment on Mars

Research Project

Project/Area Number 19H01960
Research InstitutionJapan Aerospace EXploration Agency

Principal Investigator

臼井 寛裕  国立研究開発法人宇宙航空研究開発機構, 宇宙科学研究所, 教授 (60636471)

Co-Investigator(Kenkyū-buntansha) 高橋 嘉夫  東京大学, 大学院理学系研究科(理学部), 教授 (10304396)
中田 亮一  国立研究開発法人海洋研究開発機構, 超先鋭研究開発部門(高知コア研究所), 主任研究員 (50726958)
黒川 宏之  東京工業大学, 地球生命研究所, 特任助教 (80713643)
上野 雄一郎  東京工業大学, 理学院, 教授 (90422542)
Project Period (FY) 2019-04-01 – 2022-03-31
Keywords火星隕石 / 硫黄化学種 / 鉄化学種 / XAFS分析
Outline of Annual Research Achievements

2021年度は、研究計画調書に記載の『研究計画1:局所XAFS(μ-XAFS)分析による火星表層成分のFeとSの化学種同定』および『研究計画3:水散逸モデルに基づく水の消失量および表層酸化との関係性の解明』の論文化を進めた。一方、『研究計画2:SIMS分析に基づく表層水のD/H・13C/12C・18O/16Oの決定』に関しては、海外出張を含む計画の為、コロナ下での実施は見送った。
実施した研究計画1および2では、火星隕石に含まれる炭酸塩および粘土鉱物の鉄・硫黄XAFS分析データの解析を実施した。また、火星アナログ物質としてカンブリア紀の炭酸塩の硫黄XAFS分析データの解釈を進めた。結果、硫黄が、有機硫黄および大部分が硫酸イオンとして炭酸塩の炭酸イオンを構造的に置換した形で存在していることが明らかとなった。また、炭酸塩中には微量成分として鉄を含む粘土鉱物が含まれることを明らかにした。本研究成果は、査読付き原著論文として国際専門誌に掲載された(Matsuura et al. 2021 GCA; Nakada et al. 2021 Minerals; Shidare et al. 2021 GCAなど)。
本研究成果の波及効果として、日本が進める火星衛星サンプルリターン計画(MMX:Martian Moons Exploration)への参画が挙げられる。代表者のみならず分担者もMMXの分析班および火星探査班に所属し、本研究成果の結果をもとに、MMX計画で実施する観測・分析内容に対するインプットを行った(Fujiya et al. 2021 EPS; Ogohara et al. 2022 EPS; Kuramoto et al. 2022 EPSなど)。

Research Progress Status

令和3年度が最終年度であるため、記入しない。

Strategy for Future Research Activity

令和3年度が最終年度であるため、記入しない。

  • Research Products

    (56 results)

All 2022 2021

All Journal Article (22 results) (of which Int'l Joint Research: 6 results,  Peer Reviewed: 21 results,  Open Access: 15 results) Presentation (34 results) (of which Int'l Joint Research: 18 results,  Invited: 7 results)

  • [Journal Article] Distant Formation and Differentiation of Outer Main Belt Asteroids and Carbonaceous Chondrite Parent Bodies2022

    • Author(s)
      Kurokawa H.、Shibuya T.、Sekine Y.、Ehlmann B. L.、Usui F.、Kikuchi S.、Yoda M.
    • Journal Title

      AGU Advances

      Volume: 3 Pages: -

    • DOI

      10.1029/2021AV000568

    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Can we constrain the origin of Mars' recurring slope lineae using atmospheric observations?2022

    • Author(s)
      Kurokawa Hiroyuki、Kuroda Takeshi、Aoki Shohei、Nakagawa Hiromu
    • Journal Title

      Icarus

      Volume: 371 Pages: -

    • DOI

      10.1016/j.icarus.2021.114688

    • Peer Reviewed / Open Access
  • [Journal Article] Photochemical Synthesis of Ammonia and Amino Acids from Nitrous Oxide2022

    • Author(s)
      Zang Xiaofeng、Ueno Yuichiro、Kitadai Norio
    • Journal Title

      Astrobiology

      Volume: 22 Pages: 387~398

    • DOI

      10.1089/ast.2021.0064

    • Peer Reviewed
  • [Journal Article] Absorption spectra measurements at ~1 cm-1 spectral resolution of 32S, 33S, 34S, and 36S sulfur dioxide for the 206-220 nm region and applications to modeling of the isotopic self-shielding2022

    • Author(s)
      Endo Yoshiaki、O. Danielache Sebastian、Ogawa Moeko、Ueno Yuichiro
    • Journal Title

      GEOCHEMICAL JOURNAL

      Volume: 56 Pages: 40~56

    • DOI

      10.2343/geochemj.GJ22004

    • Peer Reviewed
  • [Journal Article] Martian moons exploration MMX: sample return mission to Phobos elucidating formation processes of habitable planets2022

    • Author(s)
      Kuramoto Kiyoshi、Kawakatsu Yasuhiro、Fujimoto Masaki、Araya Akito、Barucci Maria Antonietta、Genda Hidenori、Hirata Naru、Ikeda Hitoshi、Imamura Takeshi、Helbert Jorn、Kameda Shingo、Kobayashi Masanori、Kusano Hiroki、Lawrence David J.、Matsumoto Koji、Michel Patrick、Miyamoto Hideaki、Usui Tomohiro et al.
    • Journal Title

      Earth, Planets and Space

      Volume: 74 Pages: -

    • DOI

      10.1186/s40623-021-01545-7

    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] The Mars system revealed by the Martian Moons eXploration mission2022

    • Author(s)
      Ogohara Kazunori、Nakagawa Hiromu、Aoki Shohei、Kouyama Toru、Usui Tomohiro、Terada Naoki、Imamura Takeshi、Montmessin Franck、Brain David、Doressoundiram Alain、Gautier Thomas、Hara Takuya、Harada Yuki、Ikeda Hitoshi、Koike Mizuho、Leblanc Fran?ois、Ramirez Ramses、Sawyer Eric、Seki Kanako、Spiga Aymeric、et al.
    • Journal Title

      Earth, Planets and Space

      Volume: 74 Pages: -

    • DOI

      10.1186/s40623-021-01417-0

    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] MIRS: an imaging spectrometer for the MMX mission2021

    • Author(s)
      Barucci Maria Antonietta、Reess Jean-Michel、Bernardi Pernelle、Doressoundiram Alain、Fornasier Sonia、Le Du Michel、Iwata Takahiro、Nakagawa Hiromu、Nakamura Tomoki、Aoki Shohei、Arai Takehiko、Baldit Elisa、Beck Pierre、Buey Jean-Tristan、Canalias Elisabet、Kurokawa Hiroyuki、et al.
    • Journal Title

      Earth, Planets and Space

      Volume: 73 Pages: -

    • DOI

      10.1186/s40623-021-01423-2

    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Numerous chondritic impactors and oxidized magma ocean set Earth’s volatile depletion2021

    • Author(s)
      Sakuraba Haruka、Kurokawa Hiroyuki、Genda Hidenori、Ohta Kenji
    • Journal Title

      Scientific Reports

      Volume: 11 Pages: -

    • DOI

      10.1038/s41598-021-99240-w

    • Peer Reviewed / Open Access
  • [Journal Article] Mars’ atmospheric neon suggests volatile-rich primitive mantle2021

    • Author(s)
      Kurokawa Hiroyuki、Miura Yayoi N.、Sugita Seiji、Cho Yuichiro、Leblanc Fran?ois、Terada Naoki、Nakagawa Hiromu
    • Journal Title

      Icarus

      Volume: 370 Pages: -

    • DOI

      10.1016/j.icarus.2021.114685

    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Journal Article] Hydrated crust stores Mars' missing water2021

    • Author(s)
      Kurokawa Hiroyuki
    • Journal Title

      Science

      Volume: 372 Pages: 27~28

    • DOI

      10.1126/science.abh4469

  • [Journal Article] Survey of impact glasses in shergottites searching for Martian sulfate using X-ray absorption near-edge structure2021

    • Author(s)
      Shidare Masashi、Nakada Ryoichi、Usui Tomohiro、Tobita Minato、Shimizu Kenji、Takahashi Yoshio、Yokoyama Tetsuya
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 313 Pages: 85~98

    • DOI

      10.1016/j.gca.2021.08.026

    • Peer Reviewed / Open Access
  • [Journal Article] A New Constraint on the Physicochemical Condition of Mars Surface during the Amazonian Epoch Based on Chemical Speciation for Secondary Minerals in Martian Nakhlites2021

    • Author(s)
      Suga Hiroki、Suzuki Keika、Usui Tomohiro、Yamaguchi Akira、Sekizawa Oki、Nitta Kiyofumi、Takeichi Yasuo、Ohigashi Takuji、Takahashi Yoshio
    • Journal Title

      Minerals

      Volume: 11 Pages: -

    • DOI

      10.3390/min11050514

    • Peer Reviewed / Open Access
  • [Journal Article] Nearly Carbon‐Saturated Magma Oceans in Planetary Embryos During Core Formation2021

    • Author(s)
      Kuwahara Hideharu、Itoh Shoichi、Suzumura Akimasa、Nakada Ryoichi、Irifune Tetsuo
    • Journal Title

      Geophysical Research Letters

      Volume: 48 Pages: -

    • DOI

      10.1029/2021GL092389

    • Peer Reviewed
  • [Journal Article] High-throughput isotope analysis of sub-nanogram sized lead using MC-ICP-MS with on-line thallium doping technique and desolvating nebulizer system2021

    • Author(s)
      Nagaishi Kazuya、Nakada Ryoichi、Ishikawa Tsuyoshi
    • Journal Title

      GEOCHEMICAL JOURNAL

      Volume: 55 Pages: 1~9

    • DOI

      10.2343/geochemj.2.0612

    • Peer Reviewed / Open Access
  • [Journal Article] Pennsylvanian paleoclimatic record in rhythmites developed on an oceanic island of low-latitude Panthalassa2021

    • Author(s)
      Kakizkaki Yoshihiro、Kano Akihiro、Ota Yasuhiro、Nakada Ryoichi、Nagaishi Kazuya、Kashiwagi Kenji
    • Journal Title

      Sedimentary Geology

      Volume: 424 Pages: -

    • DOI

      10.1016/j.sedgeo.2021.105992

    • Peer Reviewed
  • [Journal Article] Tracing sulfur sources in the crust via SIMS measurements of sulfur isotopes in apatite2021

    • Author(s)
      Hammerli Johannes、Greber Nicolas D.、Martin Laure、Bouvier Anne-Sophie、Kemp Anthony I.S.、Fiorentini Marco L.、Spangenberg Jorge E.、Ueno Yuichiro、Schaltegger Urs
    • Journal Title

      Chemical Geology

      Volume: 579 Pages: -

    • DOI

      10.1016/j.chemgeo.2021.120242

    • Peer Reviewed / Open Access
  • [Journal Article] Spatial distribution and speciation of sulfur in Ediacaran limestones with μ-XRF imaging and XANES spectroscopy: Implications for diagenetic mobilization of sulfur species2021

    • Author(s)
      Matsu'ura Fumihiro、Nakada Ryoichi、Usui Tomohiro、Sawaki Yusuke、Ueno Yuichiro、Kajitani Iori、Saitoh Masafumi
    • Journal Title

      Geochimica et Cosmochimica Acta

      Volume: 306 Pages: 20~43

    • DOI

      10.1016/j.gca.2021.05.010

    • Peer Reviewed / Open Access
  • [Journal Article] Multiple sulfur isotope chemostratigraphy across the <scp>Permian?Triassic</scp> boundary at Chaotian, China: Implications for a shoaling model of toxic deep‐waters2021

    • Author(s)
      Saitoh Masafumi、Ueno Yuichiro、Isozaki Yukio、Yoshida Naohiro
    • Journal Title

      Island Arc

      Volume: 30 Pages: -

    • DOI

      10.1111/iar.12398

    • Peer Reviewed / Open Access
  • [Journal Article] Standardization for 13C-13C clumped isotope analysis by fluorination method2021

    • Author(s)
      Taguchi Koudai、Gilbert Alexis、Ueno Yuichiro
    • Journal Title

      Rapid Communications in Mass Spectrometry

      Volume: 35 Pages: -

    • DOI

      10.1002/rcm.9109

    • Peer Reviewed
  • [Journal Article] EXAFS Determination of Clay Minerals in Martian Meteorite Allan Hills 84001 and Its Implication for the Noachian Aqueous Environment2021

    • Author(s)
      Nakada Ryoichi、Tanabe Gaku、Kajitani Iori、Usui Tomohiro、Shidare Masashi、Yokoyama Tetsuya
    • Journal Title

      Minerals

      Volume: 11 Pages: -

    • DOI

      10.3390/min11020176

    • Peer Reviewed / Open Access
  • [Journal Article] Searching for life on Mars and its moons2021

    • Author(s)
      Hyodo Ryuki、Usui Tomohiro
    • Journal Title

      Science

      Volume: 373 Pages: 742~742

    • DOI

      10.1126/science.abj1512

    • Peer Reviewed
  • [Journal Article] Analytical protocols for Phobos regolith samples returned by the Martian Moons eXploration (MMX) mission2021

    • Author(s)
      Fujiya Wataru、Furukawa Yoshihiro、Sugahara Haruna、Koike Mizuho、Bajo Ken-ichi、Chabot Nancy L.、Miura Yayoi N.、Moynier Frederic、Russell Sara S.、Tachibana Shogo、Takano Yoshinori、Usui Tomohiro、Zolensky Michael E.
    • Journal Title

      Earth, Planets and Space

      Volume: 73 Pages: -

    • DOI

      10.1186/s40623-021-01438-9

    • Peer Reviewed / Open Access / Int'l Joint Research
  • [Presentation] 揮発性元素同位体組成から探る火星の形成と表層環境進化2022

    • Author(s)
      黒川宏之
    • Organizer
      CPS & ABC ワークショップ『火星から諸惑星: 表層環境の多様性』
    • Invited
  • [Presentation] GREX-PLUSて?期待される惑星サイエンス:理論・太陽系探査とのシナシ?ー2022

    • Author(s)
      黒川宏之
    • Organizer
      GREX-PLUS サイエンス検討会 FY2021
    • Invited
  • [Presentation] Distant formation and water-rock differentiation of large C-complex asteroids2022

    • Author(s)
      Kurokawa, H.
    • Organizer
      53rd Lunar and Planetary Science Conference
    • Int'l Joint Research
  • [Presentation] Mars atmospheric neon probes mantle volatile content and early surface environment2022

    • Author(s)
      Kurokawa, H.
    • Organizer
      53rd Lunar and Planetary Science Conference
    • Int'l Joint Research
  • [Presentation] C型小惑星の起源・進化と水惑星形成2022

    • Author(s)
      黒川宏之
    • Organizer
      第5回水惑星学全体会議
  • [Presentation] The origin of Earth's mantle N: The implications for planetary accretion and Earth-life co-evolution2022

    • Author(s)
      黒川宏之
    • Organizer
      惑星圏研究会
  • [Presentation] Mars Ice Mapper EDL による火星大気ネオンその場測定:科学検討と機器開発状況2022

    • Author(s)
      黒川宏之
    • Organizer
      第22回宇宙科学シンポジウム
  • [Presentation] Earth-Life co-evolution: A perspective from volatile accretion and cycling2022

    • Author(s)
      Kurokawa, H.
    • Organizer
      10th ELSI International Symposium
    • Int'l Joint Research
  • [Presentation] MINERALOGY AND SULFUR X-RAY ABSORPTION NEAR-EDGE STRUCTURE (S-XANES) ANALYSIS OF BOCKFJORD VOLCANIC COMPLEX CARBONATES, A POTENTIAL MARTIAN ANALOG2022

    • Author(s)
      Chang-Chin Wang, Haruna Sugahara, Tomohiro Usui, Ryoichi Nakada, Mizuho Koike, Hans Amundsen
    • Organizer
      LPSC2022
    • Int'l Joint Research
  • [Presentation] SPECIATION OF SULFUR IN CARBONATES IN A 4.1-BILLION-YEAR-OLD MARTIAN METEORITE2022

    • Author(s)
      Iori Kajitani, Ryoichi Nakada, Mizuho Koike, Gaku Tanabe, Tomohiro Usui, Fumihiro Matsu’ura, Keisuke Fukushi, Hiroyuki Kurokawa, Tetsuya Yokoyama
    • Organizer
      LPSC2022
    • Int'l Joint Research
  • [Presentation] JAXA's planetary exploration marching with the community2022

    • Author(s)
      Tomohiro Usui
    • Organizer
      10th ELSI Symposium
    • Int'l Joint Research / Invited
  • [Presentation] Future in situ measurements of atmospheric neon to unveil the origin and early surface environment of Mars2021

    • Author(s)
      Kurokawa, H.
    • Organizer
      ISAS Planetary Exploration Workshop 2021
    • Int'l Joint Research
  • [Presentation] 火星大気ネオンの示唆する揮発性元素に富んだマントルとその起源2021

    • Author(s)
      黒川宏之
    • Organizer
      日本惑星科学会 2021年秋季講演会
  • [Presentation] 初期火星における強酸性表層水による表層のAl に富む粘土鉱物形成の可能性2021

    • Author(s)
      杉内光輝・関根康人・丹 秀也・野田夏実・高橋嘉夫
    • Organizer
      日本地球化学会 第68回オンライン年会
  • [Presentation] 初期火星における二価鉄サポナイトの有機硫黄化合物生成、炭素循環、気候に対する役割2021

    • Author(s)
      野田夏実・関根康人・高橋嘉夫・佐久間 博・河合敬宏・中川 麻悠子・北台紀夫・Kristin Johnson-Finn・Shawn McGlynn
    • Organizer
      日本地球惑星科学連合2021年大会
  • [Presentation] The role of ferrous saponite in the formation of sulfur-bearing organic matter on early Earth and early Mars2021

    • Author(s)
      Natsumi Noda, Yasuhito Sekine, Yoshio Takahashi, Hiroshi Sakuma, Takahiro Kawai, Mayuko Nakagawa, Norio Kitadai, Kristin Johnson-Finn, Shawn E McGlynn
    • Organizer
      2021 Goldschmidt Virtual
    • Int'l Joint Research
  • [Presentation] Rock-magnetic and mineralogical properties of the exsolved magnetite in plagioclase crystal2021

    • Author(s)
      Masahiko Sato, Masashi Ushioda, Ryoichi Nakada, Yujiro Tamura, Shinji Yamamoto
    • Organizer
      JpGU2021
  • [Presentation] Redox change by coseismic water-rock reactions in the interior of planets2021

    • Author(s)
      Takehiro Hirose, Ryoichi Nakada, Keishi Okazaki, Takazo Shibuya
    • Organizer
      JpGU2021
  • [Presentation] The micro-scale speciation analyses of sulfur in the Ediacaran limestones: Implications for diagenetic mobilization of sulfur species2021

    • Author(s)
      Fumihiro Matsuura, Ryoichi Nakada, Yusuke Sawaki, Yuichiro Ueno, Masafumi Saitoh, Iori Kajitani, Tomohiro Usui
    • Organizer
      JpGU2021
  • [Presentation] Relationship between the abundance of the exsolved magnetite and the valence state of iron in single plagioclase crystal separated from Doshi gabbro2021

    • Author(s)
      Yujiro Tamura, Masahiko Sato, Ryoichi Nakada, Chie Kato, Shinji Yamamoto
    • Organizer
      JpGU2021
  • [Presentation] Investigation of “Martian nitrogen cycle” and its evolution based on in-situ analyses of meteorites2021

    • Author(s)
      Mizuho Koike, Ryoichi Nakada, Kajitani Iori, Haruna Sugahara, Tomohiro Usui
    • Organizer
      JpGU2021
  • [Presentation] Interaction between Cerium and H2O in Hydrous Rhyolitic Melts2021

    • Author(s)
      近藤 望、河野 義生、尾原 幸治、中田 亮一、伊奈 稔哲、Skrzypek Etienne、山田 明寛、齊藤 哲
    • Organizer
      JpGU2021
  • [Presentation] Sulfur mass-independent fractionation patterns during SO2 photolysis under low temperature and low pressure atmosphere: implication for Archean atmospheric composition2021

    • Author(s)
      Yoshiaki Endo, Yasuhito Sekine, Yuichiro Ueno
    • Organizer
      JpGU
  • [Presentation] Geochemical drivers of microbial mediated iron reduction/oxidation in Proterozoic analogue environments2021

    • Author(s)
      Fatima Li-Hau, Mayuko Nakagawa, Lewis M. Ward, Takeshi Kakegawa, Yuichiro Ueno, Shawn McGlynn
    • Organizer
      JpGU
  • [Presentation] Application of fluorination method to isotopologue biogeochemistry2021

    • Author(s)
      Yuichiro Ueno, Koudai Taguchi, Toshiki Katsuta, Mayuko Nakagawa, Naohiro Yoshida, Alexis Gilbert
    • Organizer
      Goldschmidt Conference
    • Int'l Joint Research
  • [Presentation] Low 13C-13C clumping on abiotic hydrocarbons2021

    • Author(s)
      Koudai Taguchi, Alexis Gilbert, Yuichiro Ueno
    • Organizer
      Goldschmidt Conference
    • Int'l Joint Research
  • [Presentation] Δ34S18O systematics of modern sulfate2021

    • Author(s)
      Toshiki Katsuta, Yuichiro Ueno, Mayuko Nakagawa, Riho Aoki, Naohiro Yoshida
    • Organizer
      Goldschmidt Conference
    • Int'l Joint Research
  • [Presentation] Speciation and quantification of sulfur distributed in the Ediacaran limestones: Implications for diagenetic mobilization of sulfur species2021

    • Author(s)
      Fumihiro Matsuura, Ryoichi Nakada, Yusuke Sawaki, Yuichiro Ueno, Masafumi Saitoh, Kajitani Iori, Tomohiro Usui
    • Organizer
      Goldschmidt Conference
    • Int'l Joint Research
  • [Presentation] Missing negative Δ33S reservoir in mantle inferred from 2.7 Ga komatiite2021

    • Author(s)
      Shun Nakano, Akira Ishikawa, Yuichiro Ueno, Tetsuya Yokoyama
    • Organizer
      Goldschmidt Conference
    • Int'l Joint Research
  • [Presentation] Highly siderophile elements behavior in the Paleoarchean Camel Creek komatiites from East Pilbara Terrane, Western Australia2021

    • Author(s)
      Yusuke Kubota, Fumihiro Matsu'ura, Kenji Shimizu, Akira Ishikawa, Yuichiro Ueno
    • Organizer
      Goldschmidt Conference
    • Int'l Joint Research
  • [Presentation] Ancient Organic Material and Improving Detection Confidence Using Stable Isotopes2021

    • Author(s)
      Yuichiro Ueno
    • Organizer
      NAS Committee on Astrobiology and Planetary Sciences 2021 Fall Meeting
    • Int'l Joint Research / Invited
  • [Presentation] Atmospheric CO in prebiotic Earth-like planet2021

    • Author(s)
      Yuichiro Ueno
    • Organizer
      AGU Fall Meeting
    • Int'l Joint Research / Invited
  • [Presentation] JAXA's Strategic Mars Exploration Program (JSMEP) for Understanding the Origin, Evolution, Inventory of Water on Mars2021

    • Author(s)
      Tomohiro Usui
    • Organizer
      JpGU
    • Int'l Joint Research / Invited
  • [Presentation] Martian Moon eXploration (MMX) Mission Update2021

    • Author(s)
      Tomohiro Usui
    • Organizer
      ExMAG
    • Int'l Joint Research / Invited

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Published: 2022-12-28  

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