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2009 Fiscal Year Annual Research Report

Fe系物質の超高圧下での挙動と最下部マントル~内核の物質科学

Research Project

Project/Area Number 20001005
Research InstitutionEhime University

Principal Investigator

入舩 徹男  Ehime University, 地球深部・ダイナミクス研究センター, 教授 (80193704)

Co-Investigator(Kenkyū-buntansha) 土屋 卓久  愛媛大学, 地球深部ダイナミクス研究センター, 教授 (70403863)
西山 宣正  愛媛大学, 地球深部ダイナミクス研究センター, 准教授 (10452682)
大藤 弘明  愛媛大学, 地球深部ダイナミクス研究センター, 助教 (80403864)
丹下 慶範  愛媛大学, 地球深部ダイナミクス研究センター, 助教 (70543164)
桑山 靖弘  愛媛大学, 地球深部ダイナミクス研究センター, 助教 (00554015)
Keywords固体地球物理学 / 超高圧実験 / 地球・惑星内部 / 第一原理計算 / マントル・核
Research Abstract

新たに導入された6000トン超高圧合成装置の立ち上げをおこなうとともに、超高硬度ナノ多結晶ダイヤモンド(ヒメダイヤ)の大型化をおこなった。この結果、6-7mmのヒメダイヤの合成に成功するとともに、そのルーチン化をおこなった。このようなヒメダイヤに、パルスレーザー等を用いて加工をおこない、様々な超高圧装置用アンビル材への加工をおこなった。ダイヤモンドアンビル装置への応用により、100GPa・5000K領域におけるヒメダイヤの単結晶に比べる優位性を示した。また、マルチアンビルへの応用により、6-8-2加圧方式を用いて125GPaというこれまでの限界を打破するとともに、ドリッカマー型装置への応用も開始した。
下部マントル領域におけるパイロライト組成の相転移、密度変化、元素分配に関するマルチアンビル装置を用いた実験により、Fe分配に対するスピン転移の影響を評価した。また、Fe_2O_3-Al_2O_3-MgSiO_3系、あるいはこの部分系の組成に対して、下部マントル領域までの実験をおこない、相関係や密度変化を明らかにするとともに、Fe_2O_3の新しい高圧相を見出した。また、超音波速度測定法の改良により、下部マントル上部領域における弾性波速度精密測定を可能にした。一方、核に関してはFe-Si系の相関係を核条件下で明らかにするとともに、第一原理計算により核条件下でのFeの安定構造探査をおこなった。後者の結果、Feの新しい乱層構造を発見し、内核中における弾性的異方性がこの相により説明できることを示した。
以上のように、ヒメダイヤの合成と超高圧装置への応用、下部マントル領域での弾性波測定技術の開発などの革新的実験技術開発に基づいて、下部マントルの物質科学に関連する重要な成果を得るとともに、内核におけるFeの結晶構造に関してもインパクトの高い研究成果があがりつつある。

  • Research Products

    (71 results)

All 2010 2009 Other

All Journal Article (31 results) (of which Peer Reviewed: 31 results) Presentation (39 results) Remarks (1 results)

  • [Journal Article] P-V-T relation of MgO derived by simultaneous elastic wave velocityand in situX-ray measurements : A new pressure scale for the mantle transition region2010

    • Author(s)
      Kono, Y.
    • Journal Title

      Phys.Earth Planet Inter. (in press)

    • Peer Reviewed
  • [Journal Article] Pressure generation to 125 GPa using a 6-8-2 type multianvil apparatus withnano-polycrystalline diamond anvils2010

    • Author(s)
      Kunimoto, T.
    • Journal Title

      Journal of Physics : Conference Series (in press)

    • Peer Reviewed
  • [Journal Article] Micro-/nanostructural investigation of laser-cut surfaces of single-and polycrystalline diamonds2010

    • Author(s)
      Ohfuji, H.
    • Journal Title

      Diamond and Related Materials (in press)

    • Peer Reviewed
  • [Journal Article] Review of High Pressure Phases of Calcium by First-principles Calculations2010

    • Author(s)
      Ishikawa, T.
    • Journal Title

      Journal of Physics : Conference Series (in press)

    • Peer Reviewed
  • [Journal Article] Development of elastic wave velocities measurement system under high pressure and high temperature using a combination of ultrasonic interferometry and multianvil apparatus at SPring-82010

    • Author(s)
      Higo, Y.
    • Journal Title

      Journal of Synchrotron radiation (in press)

    • Peer Reviewed
  • [Journal Article] Laser heating in nano-polycrystalline diamond anvil cell2010

    • Author(s)
      Ohfuji, H.
    • Journal Title

      Journal of Physics : Conference Series (in press)

    • Peer Reviewed
  • [Journal Article] Application of nano-polycrystalline diamond to laser-heated diamondanvil cell experiments2010

    • Author(s)
      Ohfuji, H.
    • Journal Title

      High Press.Res. (in press)

    • Peer Reviewed
  • [Journal Article] Elastic properties of sintered diamonds with and without Co binder2010

    • Author(s)
      Kono, Y.
    • Journal Title

      Journal of Physics : Conference Series (in press)

    • Peer Reviewed
  • [Journal Article] Lowering P, T boundary for synthesis of pure nano-polycrystalline diamond2010

    • Author(s)
      Isobe, F.
    • Journal Title

      Journal of Physics : Conference Series (in press)

    • Peer Reviewed
  • [Journal Article] Pressure-volume-temperature relationship of F_<e72>Pt_<28> alloy under high pressure and temperature2010

    • Author(s)
      Matsushita, M.
    • Journal Title

      Journal of Physics : Conference Series (in press)

    • Peer Reviewed
  • [Journal Article] High-pressure two-dimensional angle-dispersive x-ray diffraction measurement system using a Kawai-type multianvil press at SPring-82010

    • Author(s)
      Funakoshi, K.
    • Journal Title

      Journal of Physics : Conference Series (in press)

    • Peer Reviewed
  • [Journal Article] Analysis of the recrystallization of cold-rolled copper after isothermalannealing using electron backscattered diffraction patterns2010

    • Author(s)
      Matsusita, M.
    • Journal Title

      Defect and Diffusion Forum 297-301

      Pages: 359-364

    • Peer Reviewed
  • [Journal Article] Elastic, vibrational and thermodynamic properties of MgGeO_3 post-perovskite investigated by first principles simulation2010

    • Author(s)
      Usui, Y.
    • Journal Title

      J.Geophys.Res. 115

      Pages: B03201

    • Peer Reviewed
  • [Journal Article] Iron partitioning and density changes of pyrolite in Earth's lower mantle2010

    • Author(s)
      Irifune, T.
    • Journal Title

      Science 327

      Pages: 193-195

    • Peer Reviewed
  • [Journal Article] Confirmation of octahedrally coordinated phosphorus in AlPO_4-containing stishoviteby 31P NMR2009

    • Author(s)
      Stebbins, J.F. Kim
    • Journal Title

      Eur.Jour.Mineral. 21

      Pages: 667-671

    • Peer Reviewed
  • [Journal Article] Temperature profile in the lowermost mantle from seismological and mineral physics joint modeling2009

    • Author(s)
      Kawai, K.
    • Journal Title

      Proceedings of the National Academy of Sciences of the United States of America 106

      Pages: 22119-22123

    • Peer Reviewed
  • [Journal Article] Optical characterization of nano-polycrystalline diamond synthesized directly from graphite under high pressure and high temperature2009

    • Author(s)
      Sumiya, H.
    • Journal Title

      Jap.J.Appl.Phy. 48

      Pages: 20206

    • Peer Reviewed
  • [Journal Article] A system for measuring elastic wave velocity under high pressure and high temperature using a combination of ultrasonic measurement and the multi-anvil apparatus at SPrin-82009

    • Author(s)
      Higo, Y.
    • Journal Title

      J.Synchrotron Rad. 16

      Pages: 762-768

    • Peer Reviewed
  • [Journal Article] Stress measurement under high-pressure using Kawai-type multi-anvil apparatus combined with synchrotron radiation2009

    • Author(s)
      Nishihara, Y.
    • Journal Title

      J.Synchrotron Rad. 16

      Pages: 757-671

    • Peer Reviewed
  • [Journal Article] A combination of a Drickamer anvil apparatus and monochromatic X-rays for stress and strain measurements under high pressure2009

    • Author(s)
      Nishiyama, N.
    • Journal Title

      J.Synchrotron Rad. 16

      Pages: 742-747

    • Peer Reviewed
  • [Journal Article] Effects of Si on the elastic property of Fe at Earth's inner core pressures : First principles study2009

    • Author(s)
      Tsuchiya, T.
    • Journal Title

      Phys.Earth Planet.Inter. 174

      Pages: 212-219

    • Peer Reviewed
  • [Journal Article] Analysis of the texture of superplastic carburized duplex stainless alloy2009

    • Author(s)
      Matsushita, M.
    • Journal Title

      Mat.Chem.Phys. 114

      Pages: 522-524

    • Peer Reviewed
  • [Journal Article] Non-cubic symmetry of CaSiO_3 perovskite up to 18 GPa 1600K2009

    • Author(s)
      Uchida, T.
    • Journal Title

      Earth Planet.Sci.Lett. 282

      Pages: 268-274

    • Peer Reviewed
  • [Journal Article] Elasticity of (Mg_<0.87>Fe_<0.13>)_2SiO_4 wadsleyite to 12 GPa 1073 K2009

    • Author(s)
      Liu, W.
    • Journal Title

      Phys.Earth Planet.Inter. 174

      Pages: 98-104

    • Peer Reviewed
  • [Journal Article] Thermal equation of state of CaFe_2O_4-type MgAl_2O_42009

    • Author(s)
      Sueda, Y.
    • Journal Title

      Phys.Earth Planet.Inter. 174

      Pages: 78-85

    • Peer Reviewed
  • [Journal Article] In situ measurement of interfacial tension of Fe-Sand Fe-P liquids under high pressure using X-ray radiography and tomography techniques2009

    • Author(s)
      Terasaki, H.
    • Journal Title

      Phys.Earth Planet Inter. 174

      Pages: 220-226

    • Peer Reviewed
  • [Journal Article] The large-volume high-pressure facility at GSECARS : A "Swiss-army-knife" approach to synchrotron-based experimental studies2009

    • Author(s)
      Wang, Y
    • Journal Title

      Phys.Earth Planet Inter. 174

      Pages: 270-281

    • Peer Reviewed
  • [Journal Article] Micromachining and surface processing of the super-hard nano-polycrystalline diamond by three types of pulsed lasers2009

    • Author(s)
      Okuchi, T.
    • Journal Title

      Appl.Phys.A : Mater.Sci.Process. 96

      Pages: 833-842

    • Peer Reviewed
  • [Journal Article] Pulsed laser processing of nano-polycrystalline diamonds : a comparative study with single crystal diamond2009

    • Author(s)
      Odake, S.
    • Journal Title

      Diamond and Related Materials 18

      Pages: 877-880

    • Peer Reviewed
  • [Journal Article] Phase relations of iron-silicon alloys at high pressure and high temperature2009

    • Author(s)
      Kuwayama, Y.
    • Journal Title

      Phys.Chem.Minerals 36

      Pages: 511-518

    • Peer Reviewed
  • [Journal Article] Origin of the unique microstructures in nano-polycrystalline diamond synthesized by direct conversion of graphite at static high pressure2009

    • Author(s)
      Ohfuji, H.
    • Journal Title

      J.Mineral.and Pet.Sci 104

      Pages: 307-312

    • Peer Reviewed
  • [Presentation] New High-Pressure Phase in Fe_2O_32009

    • Author(s)
      Tsuchiya, T.
    • Organizer
      American Geophysical Union Fall Meeting 2009
    • Place of Presentation
      San Francisco, CA, USA
    • Year and Date
      2009-12-17
  • [Presentation] Phase relations of iron alloys at high pressure2009

    • Author(s)
      Kuwayama, Y.
    • Organizer
      American Geophysical Union Fall Meeting 2009
    • Place of Presentation
      San Francisco, CA, USA
    • Year and Date
      2009-12-17
  • [Presentation] First-principles Exploration of Crystal Structures of Pure Iron at Earth's Inner Core Conditions2009

    • Author(s)
      Ishikawa, T.
    • Organizer
      American Geophysical Union Fall Meeting 2009
    • Place of Presentation
      San Francisco, CA, USA
    • Year and Date
      2009-12-16
  • [Presentation] Deformation experiment at P-T conditions of the mantle transition zone using D-DIA apparatus2009

    • Author(s)
      Kawazoe, T.
    • Organizer
      American Geophysical Union Fall Meeting 2009
    • Place of Presentation
      San Francisco, CA, USA
    • Year and Date
      2009-12-15
  • [Presentation] Spin state of ferric iron in Mg-perovskite up to 200 Gpa by X-ray emission spectroscopy and its implication to the lower mantle2009

    • Author(s)
      Fujino, K.
    • Organizer
      American Geophysical Union Fall Meeting 2009
    • Place of Presentation
      San Francisco, CA, USA
    • Year and Date
      2009-12-15
  • [Presentation] Phase relations in harzburgite : stagnation of harzburgite at the lower part of the mantle transition zone and interpretation of seismic discontinuity at 600 km depth2009

    • Author(s)
      Nishiyama, N.
    • Organizer
      American Geophysical Union Fall Meeting 2009
    • Place of Presentation
      San Francisco, CA, USA
    • Year and Date
      2009-12-14
  • [Presentation] 超高硬度ナノ多結晶ダイヤモンドの合成と応用2009

    • Author(s)
      入舩徹男
    • Organizer
      日本化学会西日本大会2009
    • Place of Presentation
      愛媛大学,愛媛県
    • Year and Date
      2009-11-08
  • [Presentation] 高硬度ナノ多結晶ダイヤモンドの合成とその超高圧化学研究への応用2009

    • Author(s)
      入舩徹男
    • Organizer
      第43回日本芳香族工業会大会(松山大会)
    • Place of Presentation
      松山市総合コミュニティセンター,愛媛県
    • Year and Date
      2009-10-15
  • [Presentation] 高圧直接変換ナノ多結晶ダイヤモンドの微細構造・物性・応用2009

    • Author(s)
      入舩徹男
    • Organizer
      日本セラミックス協会第22回秋季シンポジウム
    • Place of Presentation
      愛媛大学,愛媛県
    • Year and Date
      2009-09-16
  • [Presentation] Laser-Heated Diamond-Anvil Cell Experiments at Multimegabar Pressure2009

    • Author(s)
      桑山靖弘
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-30
  • [Presentation] Multiple Shock Compression of Diamond Foils with Shaped Laser Pulse2009

    • Author(s)
      Shigemori, K
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-30
  • [Presentation] Stress relaxation test of olivine under Earth's deep upper mantle conditions2009

    • Author(s)
      Nishihara, Y
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-30
  • [Presentation] Review of High Pressure Phases of Calcium by the First-principles Calculation2009

    • Author(s)
      Ishikawa, T.
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-29
  • [Presentation] Pressure-volume-temperature relations of Fe_<72>Pt_<28> alloy under high pressures and temperatures2009

    • Author(s)
      Matsushita, M.
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-29
  • [Presentation] Development of a 6-8-2 type multi-anvil apparatus and its application : pressure-induced phase transitions in GeO_22009

    • Author(s)
      Kunimoto, T.
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-29
  • [Presentation] Unified analyses for P-V-T equation of state of MgO : A solution for pressure-scale problems in high P-T experiments2009

    • Author(s)
      Tange, Y.
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-29
  • [Presentation] Unified analyses for P-V-T EOS of MgO : A solution for P-scale problems in high P-T experiments2009

    • Author(s)
      Tange, Y.
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-29
  • [Presentation] Laser heating in "nano-polycrystalline" diamond anvil cell-Application for melting experiments of iron2009

    • Author(s)
      Ohfuji, H.
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-29
  • [Presentation] Ab initio assessment of high-P, T phase equilibria in multi-component mineral systems : Application to postperovskite phase equilibria in the MgSiO_3Al_2O_3 system2009

    • Author(s)
      Tsuchiya, T.
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-28
  • [Presentation] Elastic properties of sintered diamonds with and without Co binders2009

    • Author(s)
      Kono, Y.
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-28
  • [Presentation] Plastic deformation of polycrystalline sintered diamond materials in the DDIA with HIMEDIA pistons2009

    • Author(s)
      Nishiyama, N.
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-28
  • [Presentation] Properties and applications of ultra-hard nano-polycrystalline diamond synthesized by direct conversion from graphite under HPHT2009

    • Author(s)
      Sumiya, H
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-28
  • [Presentation] Measurements on the elasticity of nano-polycrystalline diamond by both pulse and resonance methods2009

    • Author(s)
      Kimura, M.
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-28
  • [Presentation] Phase relation of FeAlO_3 at high pressure and high temperature2009

    • Author(s)
      Wada, K.
    • Organizer
      AIRAPT-22 & HIPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-28
  • [Presentation] Elastic wave velocity measurements under the condition of lower most mantle transition region2009

    • Author(s)
      Higo, Y.
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-28
  • [Presentation] High-pressure two-dimensional x-ray diffraction measurement system using a Kawai-type multianvil apparatus at SPring-82009

    • Author(s)
      Funakoshi, K
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-28
  • [Presentation] T boundaries for synthesis of nano-polycrystalline diamond2009

    • Author(s)
      Isobe, F.
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-28
  • [Presentation] Elastic, thermodynamic and vibrational properties of MgGeO_3 post perovskite by first principles calculations2009

    • Author(s)
      Usui, Y.
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-28
  • [Presentation] Laser micromachining of the super-hard nano-polycrystalline diamond2009

    • Author(s)
      Okuchi, T
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-28
  • [Presentation] Development of multianvil technology and its application to deep Earth mineralogy and novel materials synthesis2009

    • Author(s)
      入舩徹男
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-27
  • [Presentation] Synthesis of nano-polycrystalline diamond in large-volume multianvil apparatus and its application to various types of high-pressure apparatus2009

    • Author(s)
      Irifune, T
    • Organizer
      AIRAPT-22 & HPCJ-50
    • Place of Presentation
      Odaiba, Tokyo, Japan
    • Year and Date
      2009-07-27
  • [Presentation] High-pressure techniques using sintered diamond anvils in multianvil apparatus and its applications2009

    • Author(s)
      Tange, Y.
    • Organizer
      IUCr workshop on Advanced Crystallography at High Pressure
    • Place of Presentation
      Harbin, China
    • Year and Date
      2009-07-19
  • [Presentation] Development of the elastic wave velocity measurement technique under the condition of lower mantle2009

    • Author(s)
      Higo, Y.
    • Organizer
      IUCr workshop on Advanced Crystallography at High Pressure
    • Place of Presentation
      Harbin, China
    • Year and Date
      2009-07-19
  • [Presentation] The orthoenstatite/clinoenstatite phase transition under the upper mantle conditions determined by in situ X-ray diffraction : Implications for nature of the X-discontinuity2009

    • Author(s)
      Ishikawa, T.
    • Organizer
      Goldschmidt Conference 2009
    • Place of Presentation
      Davos, Switzerland
    • Year and Date
      2009-06-25
  • [Presentation] Ab initio assessment of high-P,T thermodynamics in multi-component mineral systems : Application to postperovskite phase equilibria in the MgSiO_3-Al_2O_3 system2009

    • Author(s)
      Tsuchiya, T.
    • Organizer
      Goldschmidt Conference 2009
    • Place of Presentation
      Davos, Switzerland
    • Year and Date
      2009-06-24
  • [Presentation] Phase relations in harzburgite under lower part of the mantle transition zone and the uppermost lower mantle2009

    • Author(s)
      Nishiyama, N
    • Organizer
      Japan Geoscience Union Meeting 2009
    • Place of Presentation
      Makuhari, Japan
    • Year and Date
      2009-05-20
  • [Presentation] Stress relaxation test of olivine under Earth's deep upper mantle conditions2009

    • Author(s)
      Nishihara, Y
    • Organizer
      Japan Geoscience Union Meeting 2009
    • Place of Presentation
      幕張,千葉県
    • Year and Date
      2009-05-20
  • [Presentation] Spin state of ferric iron in Mg-perovskite up to 160GPa by X-ray emission spectroscopy2009

    • Author(s)
      Fujino, K
    • Organizer
      Japan Geoscience Union Meeting 2009
    • Place of Presentation
      幕張,千葉県
    • Year and Date
      2009-05-19
  • [Presentation] Unified analyses for P-V-T EOS of MgO : A solution for P-scale problems in high P-T experiments2009

    • Author(s)
      Tange, Y.
    • Organizer
      Japan Geoscience Union Meeting 2009
    • Place of Presentation
      幕張,千葉県
    • Year and Date
      2009-05-19
  • [Remarks]

    • URL

      http://www.ehime-u.ac.jp/~grc/

URL: 

Published: 2011-06-16   Modified: 2016-04-21  

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